• Title/Summary/Keyword: resistance change

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Autohesion Behavior of Brominated-Isobutylene-Isoprene Gum Nanocomposites with Layered Clay (층상점토 충전 브롬화 이소부틸-이소프렌 검 나노복합체의 점착거동)

  • Mensah, Bismark;Kim, Sungjin;Lee, Dae Hak;Kim, Han Gil;Oh, Jong Gab;Nah, Changwoon
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.43-52
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    • 2014
  • The effect of nanoclay (Cloisite 20A) on the self-adhesion behavior of uncured brominated-isobutylene-isoprene rubber (BIIR) has been studied. The dispersion state of nanoclay into the rubber matrix was examined by SEM, TEM and XRD analysis. The thermal degradation behavior of the filled and unfilled samples was examined by TGA and improvement in the thermal stability of the nanocomposites occurred based on the weight loss (%) measurements. Also, addition of nanoclay enhanced the cohesive strength of the material by reinforcement action thereby reducing the degree of molecular diffusion across the interface of butyl rubber. However, the average depth of penetration of the inter-diffused chains was still adequate to form entanglement on either side of the interface, and thus offered greater resistance to peeling, resulting in high tack strength measurements. The improvement in tack strength was only achieved at critical nanoclay loading above 8 phr. Contact angle measurement was also made to examine the surface characteristics. There was no significant interfacial property change by employing the nanoclay.

Downregulation of $\textrm{NF}_{-{\kappa}}\textrm{B}$ activation in human keratinocytes by melanogenic inhibitors

  • Ahn, Kwang-Seok;Lee, Jinseon;Kim, Yeong-Shik
    • Proceedings of the SCSK Conference
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    • 2003.09a
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    • pp.780-803
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    • 2003
  • Exposure of skin cells, particularly keratinocytes to various nuclear factor-kappaB ($\textrm{NF}_{-{\kappa}}\textrm{B}$) activators [e.g. tumor necrosis factor-$\alpha$, interleukin-1, lipopolysaccharides, and ultraviolet light] leads to phosphorylation and degradation of the inhibitory protein, $\textrm{I}_{{\kappa}}\textrm{B}$. Liberated $\textrm{NF}_{-{\kappa}}\textrm{B}$ is translocated into the nucleus where it can change or alter expression of target genes, resulting in the secretion of extracellular signaling molecules including melanotrophic factors affecting melanocyte. In order to demonstrate the possible role of $\textrm{NF}_{-{\kappa}}\textrm{B}$ activation on the synthesis of melanotrophic factors from the keratinocytes, the activities of $\textrm{NF}_{-{\kappa}}\textrm{B}$ induced by melanogenic inhibitors (MIs) were determined in human HaCaT keratinocytes transfected with $\textrm{pNF}_{-{\kappa}}\textrm{B}$-SEAP-NPT plasmid. Transfectant cells released the secretory alkaline phosphatase (SEAP) as a transcription reporter in response to the $\textrm{NF}_{-{\kappa}}\textrm{B}$ activity and contain the neomycin phosphotransferase (NPT) gene for the dominant selection marker for geneticin resistance. MIs such as niacinamide, kojic acid, hydroquinone, resorcinol, arbutin, and glycolic acid were preincubated with transfectant HaCaT cells for 3 h and then ultraviolet B (UVB) was irradiated. $\textrm{NF}_{-{\kappa}}\textrm{B}$ activation was measured with the SEAP reporter gene assay using a fluorescence detection method. Of the Mis tested, kojic acid ($IC_{50}$/ = 60 $\mu$M) was found to be the most potent inhibitor of UVB-upregulating $\textrm{NF}_{-{\kappa}}\textrm{B}$ activation in transfectant HaCaT cells, which is followed by niacinamide ($IC_{50}$/= 540 $\mu$M). Pretreatment of the transfectant HaCaT cells with the Mis, especially kojic acid and niacinamide, effectively lowered $\textrm{NF}_{-{\kappa}}\textrm{B}$ binding measured by electrophoretic mobility shift assay. Furthermore, these two inhibitors remarkably reduced the secretion level of IL-6, one of melanotrophic factors, triggered by UV-radiation of the HaCaT cells. These observations suggest that Mis working at the in vivo level might act partially through the modulation of the synthesis of melanotrophic factors in keratinocyte.

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Changes in the Soil Physical Properties of Vineyard Converted from Paddy Field (논에서 전환한 포도원의 토양물리적 특성변화)

  • Yun, Eul-Soo;Jung, Ki-Youl;Park, Ki-Do;Ko, Jee-Yeon;Lee, Jae-Saeng;Park, Sung-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.3
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    • pp.145-151
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    • 2009
  • This study was conducted to develop rational soil management and enhance the productivity of lands converted from paddy soils. Specifically, the changes in the soil physical properties brought about by the change in land usage from paddy soil were evaluated. This was carried out from 1999 to 2001 at 50 site in large-scale converted paddy fields of Kimcheon, Youngcheon, Gyeongsan and Milyang in the Youngnam region, categorized according to soil texture and drainage class. The ridge height of converted paddy soils was higher in coarse-textured and poorly-drained soils than in fine-textured and well-drained soils. The gray color of the surface soil was of lesser degree in converted soils than paddy soils and more notable in welldrained soils. The porosity ratio and the formation of aggregate structure were higher, and the appearance of soil mottling was deeper in converted paddy fields than in paddy soils. The glaying layer "g" of surface soil degraded with time. The porosity and amount of water stable aggregate was found to increase with time after conversion. The penetration resistance of the converted paddy soil was lower and deeper with time after conversion. The soil aeration of the converted paddy soil was lower in sandy loam than in loamy soil. Furthermore, soil aeration was influenced by ridge height and drainage class in poorly-drained soils.

Static Behavior of Steel-Concrete Composite Beam with Perfobond Rib Shear Connector (Perfobond rib 전단연결재가 설치된 강.콘크리트 합성보의 정적거동)

  • Ahn, Jin Hee;Chung, Hamin;Kim, Sang Hyo
    • Journal of Korean Society of Steel Construction
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    • v.21 no.4
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    • pp.421-432
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    • 2009
  • In this study, push-out and static loading tests were conducted to evaluate the behavioral characteristics of composite beams with a perfobond rib shear connector. The shear capacity of the perfobond rib was found to be proportional to its concrete strength, which is in turn affected by the increase in the concrete end-bearing strength and concrete dowel action to resist the shear force. The relative slips of the push-out specimen, however, which was used to assess the ductility of the shear connector, increased to some extent, but it no longer increased when it reached the critical concrete strength because of the flexibility of the transverse rebar in the rib hole. The static-loading-test results revealed a crack on the concrete slab in the composite beam with a perfobond rib on the side of the rib hole and transverse rebar for the applied moment and shear force to the rib hole, depending on the static loading. The shear resistance characteristics of the perfobond rib shear connector were found to resist the shear force from the relative slip on the interface of the composite beam. Thus, the sectional effect of the shear connector to the composite beam with a perfobond rib should be considered when designing the composite beam because the behavior of the composite beam can change owing to the shear connector.

Input Balun Design Method for CMOS Differential LNA (차동 저 잡음 증폭기의 입력 발룬 설계 최적화 기법)

  • Yoon, Jae-Hyuk
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.5
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    • pp.366-372
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    • 2017
  • In this paper, the analysis of baluns that are inevitably required to design a differential low noise amplifier, The balun converts a single signal input from the antenna into a differential signal, which serves as an input to the differential amplifier. In addition, it protects the circuit from ESD(Electrostatic Discharge) coming through the antenna and helps with input matching. However, in the case of a passive balun used in general, since the AC signal is transmitted through electromagnetic coupling formed between two metal lines, it not only has loss without gain but also has the greatest influence on the total noise figure of the receiving end. Therefore, the design of a balun in a low-noise amplifier is very important, and it is important to design a balun in consideration of line width, line spacing, winding, radius, and layout symmetry that are necessary. In this paper, the factors to be considered for improving the quality factor of balun are summarized, and the tendency of variation of resistance, inductance, and capacitance of the balun according to design element change is analyzed. Based on the analysis results, it is proved that the design of input balun allows the design of low noise, high gain differential amplifier with gain of 24 dB and noise figure of 2.51 dB.

A Study on 5.18 Discourse in Korean Newspaper: An Analysis of the $Dong-A$ $Ilbo$ (한국 언론과 5.18 광주민주화운동 담론: "동아일보"의 보도 기사와 사설을 중심으로)

  • Heo, Yun-Cheol;Kang, Seung-Hwa;Park, Hyo-Ju;Chae, Baek
    • Korean journal of communication and information
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    • v.58
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    • pp.130-153
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    • 2012
  • The purpose of this study is to examine how the $Dong-A$ $Ilbo$, a prevailing newspaper in Korea, has constructed 5.18 discourse. In the last thirty years or so in Korea, '5.18(the Gwangju Democratization Movement)', in both academic and social realm, has been one of the most disputed issues in the process of political change. However, little attention has been given to this topic in the field of communication study. Thus, we attempted to illuminate the construction of 5.18 dicourse by using terms analysis and discourse analysis of editorials during the period of May 18, 1980-December 31, 2010. From the study, it is found that the use of terms has changed from 'crisis' through 'resistance', 'slaughter', 'revolt' to 'democratization movement' in the $Dong-A$ $Ilbo$. And it is also found that 5.18 discourse has been developed in the order of 'tragic incident discourse', 'truth investigation discourse', 'rehabilitation discourse', 'deferment discourse', 'punishment discourse', 'political strife discourse' in the editorials of the $Dong-A$ $Ilbo$. These shifts of terms and discourse have been mostly led by socio-political changes. Based on the research results, the central characteristics of 5.18 discourse of the Korean mainstream press were elaborated and the implications of the results were discussed.

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Electrical Properties of $Ba_{1-x}(Bi_{0.5}K_{0.5})TiO_3$ according to $(Bi_{0.5}K_{0.5})TiO_3$ for Pb-free PTC (Pb-free PTC에 있어서 $(Bi_{0.5}K_{0.5})TiO_3$ 첨가에 따른 $Ba_{1-x}(Bi_{0.5}K_{0.5})TiO_3$의 전기적특성)

  • Lee, Mi-Jai;Choi, Byung-Hyun;Paik, Jong-Hoo;Kim, Bip-Nam;Lee, Woo-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.35-36
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    • 2008
  • PTC thermistor are characterized by an increase in the electrical resistance with temperature. The PTC materials of middle Curie point were produced or that of high Curie point (above $200^{\circ}C$), it was determined that compositional modifications of $Pb^{2+}$ for $Ba^{2+}$ produce change sin the Curie point to higher temperature. PTC ceramic materials with the Curie point above $120^{\circ}C$ were prepared by adding $PbTiO_3$, PbO or $Pb_3O_4$ into $BaTiO_3$. Thereby, adding $Pb^{2+}$ into $BaTiO_3$-based PTC material to improve Tc was studied broadly, however, weal know that PbO was poisonous and prone to volatilize, then to pollute the circumstance and hurt to people, so we should dope other innocuous additives instead of lead to increase Tc of composite PTC material. In order to prepare lead-free $BaTiO_3$-based PTC with middle Curie point, the incorporation on $Bi_{1/2}K_{1/2}TiO_3$ into $BaTiO_3$-based ceramics was investigated on samples containing 0, 1, 2, 3, 4, and 50mol% of $Bi_{1/2}K_{1/2}TiO_3$. $Bi_{1/2}K_{1/2}TiO_3$ was compounded as standby material by conventional solid-state reaction technique. The starting materials were $Bi_2O_3$, $K_2CO_3$, $BaCO_3$ and $TiO_2$ powder, and using solid-state reaction method, too. The microstructures of samples were investigated by SEM, DSC, XRD and dielectric properties. Phase composition and lattice parameters were investigated by X-ray diffraction.

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An Experimental Study on the Durability of Recycled Aggregate Concrete (재생골재 콘크리트의 내구특성에 관한 실험적 연구)

  • Seo Chi-Ho;Kim Byung-Yun
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.385-392
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    • 2005
  • The object of this study is to prove the quality and reliability of recycled aggregate concrete by finding a way to improve the durability of the material through the experiment on the accelerated carbonation, freezing and thaw, and drying shrinkage, analysing the influence on the durability to Promote more active use of recycled aggregate concrete. The result of study as follows. (1) Resistibility to the freeze and thaw of the recycled aggregate concrete showed relative dynamic modulus of elasticity over $90\%$ which is very good, and all cycles show $99.2{\~}91.0\%$ dynamic modulus of elasticity which is improved compared with the $97.5{\~}90.6\%$ relative dynamic modulus of elasticity of ordinary concrete made of broken stone. (2) Carbonated thickness of the recycled aggregate concrete and the normal concrete was similar or it appeared with the tendency which it diminishes more or less. (3) Length change rate in drying contraction of the recycled aggregate concrete made of the recycled aggregate was lower than the ordinary concrete made of the broken stone by $18.5{\~}3.9\%$ in all blending.

Weatherability of Epoxy Cement Mortars without Hardener (경화제를 첨가하지 않은 에폭시 시멘트 모르타르의 내후성)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.801-809
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    • 2006
  • Epoxy resin has widely been used as adhesives and corrosion-resistant paints in the construction industry for many years, since it has desirable properties such as high adhesion and chemical resistance. Until now, in the production of conventional epoxy cement mortars, the use of any hardener has been considered indispensable for the hardening of the epoxy resin. However we have noticed the fact that even without any hardener, the hardening process of the epoxy resin can proceed by the action of hydroxides in cement mortars. As a result the disadvantages of the two-component mixing of the epoxy resin and hardener have been overcome. The purpose of this study is to evaluate the mechanical properties and durability of epoxy cement mortar without a hardener exposed at indoor and outdoor for one year. The epoxy cement mortars without and with a hardener were prepared with various polymer-cement ratios, and tested for weight change, flexural and compressive strengths, water absorption, carbonation depth and pore size distribution. Especially, the basic properties of the epoxy cement mortars without hardener are discussed in comparison with ones with the hardener. From the test results, it is concluded thai the epoxy cement mortars without a hardener exposed at indoor and outdoor for one year have higher strength and better durability than ones with the hardener within the polymer-cement ratios of 10 to 20%.

Reliability Studies on Cu/SnAg Double-Bump Flip Chip Assemblies for Fine Pitch Applications (미세피치용 Cu/SnAg 더블 범프 플립칩 어셈블리의 신뢰성에 관한 연구)

  • Son, Ho-Young;Kim, Il-Ho;Lee, Soon-Bok;Jung, Gi-Jo;Park, Byung-Jin;Paik, Kyung-Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.2
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    • pp.37-45
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    • 2008
  • In this study, reliabilities of Cu (60 um)/SnAg (20 um) double-bump flip chip assemblies were investigated for the flip chip interconnections on organic substrates with 100 um pitch. After multiple reflows at $250^{\circ}C\;and\;280^{\circ}C$, bump contact resistances were almost same regardless of number of reflows and reflow temperature. In the high temperature storage test, there was no bump contact resistance change at $125^{\circ}C$ up to 2000 hours. However, bump contact resistances slightly increased at $150^{\circ}C$ due to Kirkendall voids formation. In the electromigration test, Cu/SnAg double-bump flip chip assemblies showed no electromigration until about 600 hours due to reduced local current density. Finally, in the thermal cycling test, thermal cycling failure mainly occurred at Si chip/Cu column interface which was found out the highest stress concentration site in the finite element analysis. As a result, Al pad was displaced out under thermal cycling. This failure mode was caused by normal compressive strain acting Cu column bumps along perpendicular direction of a Si chip.

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