• 제목/요약/키워드: residual carbon

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활성탄에 의한 사염화탄소 흡착공정에서 잔존수분의 영향 (The Effect of Residual Water on the Adsorption Process of Carbon Tetrachloride by Activated Carbon Pellet)

  • 정성준;이대로;김태영;김진환;김승재;조성용
    • Korean Chemical Engineering Research
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    • 제40권6호
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    • pp.694-702
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    • 2002
  • 활성탄은 산업분야에서 촉매로도 사용되고 용제 회수, 가스 분리, 그리고 악취제거 등 다양한 용도로 사용되고 있다. 본 연구에서는 입상활성탄에서 CTC(Carbon Tetrachloride, $CCl_4$)의 흡착능에 따른 잔존수분의 영향을 연구하였다. 고정층 흡착탑에서 CTC의 입구농도, 유속변화에 따른 파과곡선과 흡착량의 변화 및 활성탄의 잔존수분 탈착특성도 함께 연구하였다. 활성탄의 잔존수분량은 0에서 20%(w/w)범위에 있었으며, 모든 실험은 298.15 K에서 수행하였으며 활성탄에 대한 사염화탄소의 흡착평형실험결과는 Langmuir등온식으로 잘 묘사되었다. 활성탄의 잔존 수분량이 증가함에 따라 $CCl_4$의 흡착량은 감소하였으며 사염화탄소의 흡착에 따른 잔존수분의 탈착은 지수적으로 감소되었고, LDF(linear driving force)모델을 이용하여 파과곡선을 잘 모사할 수 있었다.

고탄소강 다단 신선 와이어의 표면 온도 상승에 의한 축방향 잔류응력 예측 (Prediction of Axial Residual Stress in Drawn High-Carbon Wire Resulting Due to Increase in Surface Temperature)

  • 김대운;이상곤;김병민;정진영;반덕영
    • 대한기계학회논문집A
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    • 제34권10호
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    • pp.1479-1485
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    • 2010
  • 최근 와이어의 생산성 및 고강도화를 위한 고탄소강의 고속신선으로 인해 와이어 표면의 급격한 온도상승으로 잔류응력이 크게 증가하는 문제점이 발생되고 있다. 와이어의 다단 신선 공정시에는 소성변형과 마찰열에 의하여 와이어 내부의 온도가 더욱 크게 상승하게 된다. 특히, 고속 신선의 경우 마찰에 의한 온도구배가 더욱 크게 되어 와이어 표면층에 축방향 인장 잔류응력을 과도하게 발생시킨다. 따라서, 본 연구에서는 먼저 표면 온도 상승과 축방향 잔류응력과의 관계를 규명한 다음에 와이어의 평형온도 예측 모델을 제안하고, 이를 토대로 표면 온도 상승에 의한 축방향 잔류응력 예측식을 개발하였다. 고탄소강(0.82%C)소재의 다단신선 실험을 통해 얻어진 시편에 대하여 X 선 회절을 이용하여 잔류응력을 측정하여 제안된 예측식을 검증하였다.

아공정 구상흑연주철의 Fading 거동에 미치는 탄소당량의 영향 (Effect of Carbon Equivalent on the Fading Behavior of Hypoeutectic Ductile Cast Iron)

  • 박헌범;박상준
    • 한국주조공학회지
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    • 제24권5호
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    • pp.290-294
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    • 2004
  • The effect of carbon equivalent on the fading behavior of hypoeutectic ductile cast iron was investigated. The carbon content was slightly increased right after graphite spheroidization treatment and remained almost constant with holding at $1,490^{\circ}C$ after 4 minute. The residual magnesium content was decreased slowly with holding. The empirical equation expressing the relationship between this and holding time was proposed ; $C=C_o-P{\times}t$. The proportionality constant, P, was inversely proportional to carbon content.

고온.고습 환경에서 CFRP 적층재의 충격손상와 잔류강도 (Impact Damages and Residual Strength of CFRP Laminates under the Hygrothermal Environment)

  • 정종안;양인영
    • 대한기계학회논문집A
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    • 제20권12호
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    • pp.3748-3758
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    • 1996
  • This study is to investigate experimentally relationships between the impact energy and moisture absorption characteristies vs.the residual bending strength with the variation of stacking seqences. When Carbon-fiber reinforced plastics(CFRP) impact-induced laminates are subjected to the high temperatures and hygrothermal effects, it is found that what CFRP laminates are impacted by a steel ball (5 mm in diametar) ; thus, the generated delamination is observed by the ultrasonic microscope. And the residual bending strength is evaluated by a three-point bending test. Also, a thermostat is used in test with the unimpacted and impacted specimens for the moisture experimentaiton. The percision electro lever scles is used to measure the moisture content(1/10, 000g).

전기화학적 방법과 활성탄 흡착 연계 공정을 이용한 절임염수 재이용 기술 연구 (A Study on Cabbage Salting Brine Reuse Technology Combining an Electrochemical Method and Activated Carbon Adsorption)

  • 이은실;김대기
    • 한국환경기술학회지
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    • 제19권6호
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    • pp.536-542
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    • 2018
  • 절임염수 재이용을 위한 전기화학적 시스템과 활성탄 흡착시스템 연계를 위한 평가를 수행하였다. 대상 전극은 IrOx/Ti 불용성촉매전극을 사용하였으며, 염분 농도 10 %에서의 전류밀도에 따른 잔류염소 농도 변화와 활성탄을 이용한 잔류된 염소 및 유기물 흡착능을 확인하였다. 실험 결과, $500A/m^2$, $1,000A/m^2$의 경우 인가된 전류량이 0.33 Ah/L일 때 더 이상 잔류염소 농도 증가 없이 일정하게 유지되는 것을 확인하였다. 잔류염소 농도 별 흡착효율 평가 시 단위흡착량은 $Y=0.0066+2.087{\times}10^{-4}b$ 식을 유추할 수 있으며 전기화학 방법에 의한 잔류염소 발생과 활성탄 흡착에 의한 제거 시 단위흡착제거량이 0.33 g/g으로 동일하게 나타나는 것을 확인하였다. 또한 활성탄 최대 유기물 흡착량은 $COD_{Cr}$의 경우 0.021 g/g, $COD_{Mn}$의 경우 0.004 g/g을 확인하였다.

분말사출성형한 W-15 wt%Cu 나노복합분말의 고상소결에 미치는 잔류불순물의 영향 (Effect of Residual Impurities on Solid State Sintering of the Powder Injection Molded W-15 wt%Cu Nanocomposite Powder)

  • 윤의식;이재성;윤태식
    • 한국분말재료학회지
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    • 제9권4호
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    • pp.235-244
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    • 2002
  • The effects of residual impurities on solid state sintering of the powder injection molded (PIMed) W-15wt%Cu nanocomposite powder were investigated. The W-Cu nanocomposite powder was produced by the mech-ano-chemical process consisting of high energy ball-milling and hydrogen reduction of W blue powder-cuO mixture. Solid state sintering of the powder compacts was conducted at $1050^{\circ}C$ for 2~10 h in hydrogen atmosphere. The den-sification of PIM specimen was slightly larger than that of PM(conventional PM specimen), being due to fast coalescence of aggregate in the PIM. The only difference between PIM and PM specimens was the amount of residual impurities. The carbon as a strong reduction agent effectively reduced residual W oxide in the PIM specimen. The $H_2O$ formed by $H_2$ reduction of oxide disintegrated W-Cu aggregates during removal process, on the contrary to this, micropore volume rapidly decreased due to coalescence of the disintegrated W-Cu aggregates during evolution of CO.It can be concluded that the higher densification was due to the earlier occurred Cu phase spreading that was induced by effective removal of residual oxides by carbon.

직접 용액 코팅법에 의해 제조한 CuInSe2 에 잔존하는 탄소 불순물층 형성에 관한 연구 (On Formation of Residual Carbon Layer in CuInSe2 Thin Films Formed via direct Solution Coating Process)

  • 안세진;;어영주;곽지혜;윤경훈;조아라
    • Current Photovoltaic Research
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    • 제2권1호
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    • pp.36-39
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    • 2014
  • Formation mechanism of residual carbon layer, frequently observed in the $CuInSe_2$ (CIS) thin film prepared by direct solution coating routes, was investigated in order to find a way to eliminate it. As a model system, a methanol solution with dissolved Cu and In salts, whose viscosity was adjusted by adding ethylcellulose (EC), was chosen. It was found that a double layer, a top metal ion-derived film and bottom EC-derived layer, formed during an air drying step presumably due to different solubility between metal salts and EC in methanol. Consequently, the top metal ion-derived film acts as a barrier layer inhibiting further thermal decomposition of underlying EC, resulting a formation of bottom carbon residue layer.

Improvement of Photo-Alignment Characteristics for Device Applications

  • Hwang, Yong-Jae;Choi, Kil-Yeong;Yi, Mi-Hie;Hong, Sung-Hwan;Shin, Dong-Myung
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.867-870
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    • 2007
  • In order to solve image sticking phenomena, the gas-phase and liquid-phase interfacial reactions of photosensitive polyimide can annihilate photoreactive carbon-carbon double bonds, which remain after photo-alignment process. The annihilation processes dramatically affect residual DC and photochemical reorientation of photoactive functional groups.

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단섬유 복합재료 사출성형물의 잔류응력 측정 (Measurement of Residual Stress Distribution in Injection-Molded Short Fiber Composites)

  • 김상균;이석원;윤재륜
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.61-63
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    • 2001
  • Residual stress distribution in injection-molded short fiber composites was determined using layer-removal method. Polysterene with 3 vol% carbon fibers was injection-molded into the tensile specimen. With milling machine layer-removal process was conducted and the curvature data were acquired. Treuting and Read analysis which is assuming isotropic material, and White analysis considering anisotropy due to the fiber orientation were used to calculate residual stress of the flow direction through the thickness direction and compared with each other.

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