• Title/Summary/Keyword: reduction-diffusion process

Search Result 142, Processing Time 0.03 seconds

The reliability physics of SiGe hetero-junction bipolar transistors (실리콘-게르마늄 이종접합 바이폴라 트랜지스터의 신뢰성 현상)

  • 이승윤;박찬우;김상훈;이상흥;강진영;조경익
    • Journal of the Korean Vacuum Society
    • /
    • v.12 no.4
    • /
    • pp.239-250
    • /
    • 2003
  • The reliability degradation phenomena in the SiGe hetero-junction bipolar transistor (HBT) are investigated in this review. In the case of the SiGe HBT the decrease of the current gain, the degradation of the AC characteristics, and the offset voltage are frequently observed, which are attributed to the emitter-base reverse bias voltage stress, the transient enhanced diffusion, and the deterioration of the base-collector junction due to the fluctuation in fabrication process, respectively. The reverse-bias stress on the emitter-base junction causes the recombination current to rise, increasing the base current and degrading the current gain, because hot carriers formed by the high electric field at the junction periphery generate charged traps at the silicon-oxide interface and within the oxide region. Because of the enhanced diffusion of the dopants in the intrinsic base induced by the extrinsic base implantation, the shorter distance between the emitter-base junction and the extrinsic base than a critical measure leads to the reduction of the cut-off frequency ($f_t$) of the device. If the energy of the extrinsic base implantation is insufficient, the turn-on voltage of the collector-base junction becomes low, in the result, the offset voltage appears on the current-voltage curve.

Removal of Organic Wax and Particles on Final Polished Wafer by Ozonated DI Water

  • Yi, Jae-Hwan;Lee, Seung-Ho;Kim, Tae-Gon;Lee, Gun-Ho;Choi, Eun-Suck;Park, Jin-Goo
    • Korean Journal of Materials Research
    • /
    • v.18 no.6
    • /
    • pp.307-312
    • /
    • 2008
  • In this study, a new cleaning process with a low cost of ownership (CoO) was developed with ozonated DI water ($DIO_3$). An ozone concentration of 40 ppm at room temperature was used to remove organic wax film and particles. Wax residues thicker than $200\;{\AA}$ remained after only a commercial dewaxer treatment. A $DIO_3$ treatment in place of a dewaxer showed a low removal rate on a thick wax layer of $8000\;{\AA}$ due to the diffusion-limited reaction of ozone. A dewaxer was combined with a $DIO_3$ rinse to reduce the wax removal time and remove wax residue completely. Replacing DI rinse with the $DIO_3$ rinse resulted in a surface with a contact angle of less than $5^{\circ}$, which indicates no further cleaning steps would be required. The particle removal efficiency (PRE) was further improved by combining a SC-1 cleaning step with the $DIO_3$ rinsing process. A reduction in the process time was obtained by introducing $DIO_3$ cleaning with a dewaxing process.

Influence of Carbonation and Freezing-thawing on the Chloride Diffusion in Concrete (탄산화 및 동결융해 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구)

  • Kim, Dong-Baek;Kwon, Ki-Jun;Jung, Sang-Hwa;Bok, Hoon
    • Journal of the Korean Society of Safety
    • /
    • v.22 no.3 s.81
    • /
    • pp.57-64
    • /
    • 2007
  • Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

A Study on Government Support for Logistics Security (물류보안 인증을 위한 정부지원 방안 연구)

  • Lee, DonHee
    • Journal of Korea Society of Industrial Information Systems
    • /
    • v.21 no.6
    • /
    • pp.109-123
    • /
    • 2016
  • This study investigates the importance of government's support for logistics security assurance through certification programs. First, the study analyzed priorities among the requirements of logistics firms through Analytic Hierarchy Process(AHP) and Quality Function Deployment(QFD) approaches. For this process we invited 21 logistics experts to assess the relationships between logistic firms' requirements and government policies regarding logistics security using the house of quality, a set of matrices of QFD. The results of this phase of the study revealed the priorities of logistics firms' goals regarding the diffusion of the government security certification program as follows: integrated logistics security systems(40.3%), strengthening government support systems(32.4%), and operational effectiveness of logistics security certification(27.2%). Second, a relative weights applied QFD method based on AHP was applied to determined the expected outcome of the logistics security certification program. The results indicated as follows: productivity improvement(28.4%), improved level of service(26.7%), logistics cost reduction(21.6%), advanced information systems(19.7%), and improved environmental protection(3.6%). The results of this study provide new insights concerning logistics firms' requirements for supply chain security and the importance of government's support policies through logistics security certification programs.

Internal Stress, Anelasticity and Recovery in Steady State Creep of 2024 Al Alloy at High Temperature (2024 Al 합금의 고온 정상크리이프 중의 내부응력의 탄성 및 회복에 관한 연구)

  • 박경동;오세욱;강상훈
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.10 no.3
    • /
    • pp.292-297
    • /
    • 1986
  • Measurements of internal stress .sigma.$_{i}$, anelastic strain .epsilon.$_{A}$ and recovery rate .gamma. were made in steady state creep of 2024 Al alloys over a wide range of stresses at temperatures between 260.deg. C and 380.deg. C, for the purpose of investigating the relations among the three parameters. Values of .sigma.$_{i}$ were obtained by the method of strain transient dip test, and those of .epsilon.$_{A}$ and .gamma. were determined from the results of sudden stress removal or reduction tests. As a main result, it is thought that the anelastic behavior and recovery process are basically dependent on same deformation mechanisms.sms.sms.

PLASTICITY-BASED WELDING DISTORTION ANALYSIS OF THIN PLATE CONNECTIONS

  • Jung, Gonghyun;Tsai, Chon L.
    • Proceedings of the KWS Conference
    • /
    • 2002.10a
    • /
    • pp.694-699
    • /
    • 2002
  • In autobody assembly, thin-wall, tubular connections have been used for the frame structure. Recent interest in light materials, such as aluminum or magnesium alloys, has been rapidly growing for weight reduction and fuel efficiency. Due to higher thermal expansion coefficient, low stiffness/strength, and low softening temperature of aluminum and magnesium alloys, control of welding-induced distortion in these connections becomes a critical issue. In this study, the material sensitivity to welding distortion was investigated using a T-tubular connection of three types materials; low carbon steel (A500 Gr. A), aluminum alloy (5456-H116) and magnesium alloy (AZ91C-T6). An uncoupled thermal and mechanical finite element analysis scheme using the ABAQUS software program was developed to model and simulate the welding process, welding procedure and material behaviors. The predicted angular distortions were correlated to the cumulative plastic strains. A unique relationship between distortion and plastic strains exists for all three materials studied. The amount of distortion is proportional to the magnitude and distribution of the cumulative plastic strains in the weldment. The magnesium alloy has the highest distortion sensitivity, followed by the other two materials with the steel connection having the least distortion. Results from studies of thin-aluminum plates show that welding distortion can be minimized by reducing the cumulative plastic strains by preventing heat diffusion into the base metal using a strong heat sink placed directly beneath the weld. A rapid cooling method is recommended to reduce welding distortion of magnesium tubular connections.

  • PDF

Structural and Magnetic Properties of Fe50Cr50 Alloys Prepared by Mechanical Alloying Method

  • Yang, Dong-Seok;Park, Ji-Yeon;Yoo, Yong-Goo;Kim, Kyeong-Sup;Yu, Seong-Cho
    • Journal of Magnetics
    • /
    • v.15 no.3
    • /
    • pp.108-111
    • /
    • 2010
  • Fe50Cr50 metastable alloys were prepared by the mechanical alloying method with milling periods of 1, 2, 4, 6, 12 and 24 hours, respectively. The structural evolution was analyzed by the extended x-ray absorption fine structure (EXAFS). In this work, the EXAFS analysis provided the local structural information around Fe central atom. The saturation magnetization was also measured by VSM. The magnetization decreased as the process mechanical alloying progressed. The magnetic property was related to the local structural variation as a function of processing time. The analysis showed that the diffusion Cr atoms into Fe clusters caused the reduction of magnetization. EXAFS analysis exhibited that the local ordering of magnetic atoms caused the magnetic ordering. Also, EXAFS analysis showed that the long range order of Fe atoms was destroyed completely in 24 hour milling.

Effects of Coal Particle Array on Coal Combustion (미분탄 입자들의 배열이 미분탄 연소에 미치는 영향)

  • Cho, Chong-Pyo;Kim, Ho-Young;Chung, Jin-Taek
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.29 no.12 s.243
    • /
    • pp.1321-1328
    • /
    • 2005
  • The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 4 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis indicate that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increase due to flow acceleration. When the vertical particle spacing is smaller than $6R_0$, volatile release and carbon conversion ratio of the second particle decrease due to reduction of flame penetration depth and interference of oxygen diffusion by the first particle.

Fabrication of Ultra Fine Grained Molybdenum and Mechanical Properties (초미세 결정립을 가지는 몰리브덴의 제조 및 기계적 특성)

  • Kim, Se-Hoon;Seo, Young-Ik;Kim, Dae-Gun;Suk, Myung-Jin;Kim, Young-Do
    • Journal of Powder Materials
    • /
    • v.17 no.3
    • /
    • pp.235-241
    • /
    • 2010
  • Mo nanopowder was synthesized by ball-milling and subsequent hydrogen-reduction of $MoO_3$ powder. To fabricate ultra fine grained molybdenum, two-step sintering and spark plasma sintering process were employed. The grain size of specimen by two-step sintering and spark plasma sintering was around $0.6\;{\mu}m$ and $0.4\;{\mu}m$, respectively. Mechanical properties of ultra fine grained Mo with relative density of above 90% were significantly improved at room and high temperatures comparing to commercial bulk Mo of 99% relative density. This result was mainly explained by the grain size refinement due to diffusion-controlled sintering.

Electrochemical dehalogenation of disinfection by-products and iodine-containing contrast media: A review

  • Korshin, Gregory;Yan, Mingquan
    • Environmental Engineering Research
    • /
    • v.23 no.4
    • /
    • pp.345-353
    • /
    • 2018
  • This paper summarizes results of research on the electrochemical (EC) degradation of disinfection by-products (DBPs) and iodine-containing contrast media (ICMs), with the focus on EC reductive dehalogenation. The efficiency of EC dehalogenation of DBPs increases with the number of halogen atoms in an individual DBP species. EC reductive cleavage of bromine from parent DBPs is faster than that of chlorine. EC data and quantum chemical modeling indicate that the EC reduction of iodine-containing DBPs (I-DBPs) is characterized by the formation of active iodine that reacts with the organic substrate. The occurrence of ICMs has attracted attention due to their association with the generation of I-DBPs. Indirect EC oxidation of ICMs using anodes that produce reactive oxygen species can result in a complete degradation of these compounds yet I-DBPs are formed in the process. Reductive EC deiodination of ICMs is rapid and its overall rate is diffusion-controlled yet I-DBPs are also produced in this reaction. Further progress in practically feasible EC methods to remove DBPs, ICMs and other trace-level organic contaminants requires the development of novel electrocatalytic materials, elimination of mass transfer limitations via innovative design of 3D electrodes and EC reactors, and further progress in the understanding of intrinsic mechanisms of EC reactions of DBPs and TrOC at EC interfaces.