• Title/Summary/Keyword: reduction and sequestration

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Technical and Economic Assessment of CO2 Transportation Options for Large-scale Integrated Carbon Capture & Sequestration(CCS) Project in South Korea

  • Lee, Ji Hyun;Kim, Beom-Ju;Kwak, No Sang;Shim, Jae-Goo;Shin, Su Hyun;Hwang, Sun-Na;Lee, Jung-Hyun
    • KEPCO Journal on Electric Power and Energy
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    • v.3 no.1
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    • pp.49-56
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    • 2017
  • In order to examine the feasibility of Carbon Capture & Sequestration, a major technological strategy for the national goal of greenhouse gas reduction, this paper studies the various methods and corresponding costs for the transportation of $CO_2$ captured at the domestic thermal power plants, as well as performing comparative analysis with overseas CCS demonstration projects. It is predicted that the investment cost would be about 98 million USD when the using land-based pipelines to transport captured $CO_2$ from the thermal power plant located in the south coast. And using marine-based offshore pipelines, it will cost about twice the amount. When the captured $CO_2$ is transported from the power plant in the west coast instead, the cost is expected to increase substantially due to the transportation distance to the storage site being more than double to that of the south coast power plant case.

Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane

  • Bhagiyalakshmi, Margandan;Anuradha, Ramani;Park, Sang-Do;Park, Tae-Sung;Cha, Wang-Seog;Jang, Hyun-Tae
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.120-124
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    • 2010
  • Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{\circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.

Comparative Evaluation between Administrative and Watershed Boundary in Carbon Sequestration Monitoring - Towards UN-REDD for Mt. Geum-gang of North Korea - (탄소 저장량 감시에서 배수구역과 행정구역의 비교 평가 - 금강산에 대한 UN-REDD 대응 차원에서 -)

  • Kim, Jun-Woo;Um, Jung-Sup
    • Journal of Environmental Impact Assessment
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    • v.22 no.5
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    • pp.439-454
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    • 2013
  • UN-REDD (United Nations programme on Reducing Emissions from Deforestation and forest Degradation) is currently being emerged as one of important mechanism to reduce carbon dioxide in relation to the deforestation. Although administrative boundary has already gained world-wide recognition as a typical method of monitoring unit in the process of GHG (Greenhouse Gas) reduction project, this approach did not provide a realistic evidence in the carbon sequestering monitoring in terms of UN-REDD; the meaningful comparison of land use patterns among watershed boundaries, interpretation for distribution trends of carbon density, calculation of opportunity cost, leakage management, etc. This research proposes a comparative evaluation framework in a more objective and quantitative way for carbon sequestering monitoring between administrative and watershed boundary approaches. Mt. Geumgang of North Korea was selected as a survey objective and an exhaustive and realistic comparison of carbon sequestration between the two approaches was conducted, based on change detection using TM satellite images. It was possible for drainage boundary approach to identify more detailed area-wide patterns of carbon distribution than traditional administrative one, such as estimations of state and trends, including historical trends, of land use / land cover and carbon density in the Mt. Geumgang. The distinctive changing trends in terms of carbon sequestration were specifically identified over the watershed boundary from 4.0% to 34.8% while less than 1% difference was observed in the administrative boundaries, which were resulting in almost 21-22%. It is anticipated that this research output could be used as a valuable reference to support more scientific and objective decision-making in introducing watershed boundary as carbon sequestering monitoring unit.

Effects of Bottom Ash Amendment on Soil Respiration and Microbial Biomass under Anaerobic Conditions (혐기조건에서 석탄바닥재가 토양호흡량 및 미생물 생체량에 미치는 영향)

  • Park, Jong-Chan;Chung, Doug-Young;Han, Gwang-Hyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.260-265
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    • 2012
  • Soil respiration under flooded conditions is considered to be very small compared with aerobic soil respiration of soil organic matter. However, anaerobic decomposition of soil plays a key role in carbon cycling in flooded ecosystems. On the other hand, coal-ash wastes, such as fly ash and bottom ash, are known to function as a soil amendment for mitigating $CO_2$ emission and enhancing carbon sequestration in up land soils. In this study, we investigated bottom ash as a soil amendment for mitigating $CO_2$ emission, and thus enhancing carbon sequestration under anaerobic conditions. We observed that amendment of bottom ash without external organic source led to significant reduction in $CO_2$ emission rate and in total cumulative $CO_2$ emission flux over the incubation period, which was proportional to the amount of bottom ash applied. We also found that soil microbial biomass increased in response to application of bottom ash. These results suggest that bottom ash can be utilized to store $CO_2$ as a stable soil organic carbon in flooded ecosystems, as in aerobic situations.

Impact Assessment of Forest Development on Net Primary Production using Satellite Image Spatial-temporal Fusion and CASA-Model (위성영상 시공간 융합과 CASA 모형을 활용한 산지 개발사업의 식생 순일차생산량에 대한 영향 평가)

  • Jin, Yi-Hua;Zhu, Jing-Rong;Sung, Sun-Yong;Lee, Dong-Ku
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.20 no.4
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    • pp.29-42
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    • 2017
  • As the "Guidelines for GHG Environmental Assessment" was revised, it pointed out that the developers should evaluate GHG sequestration and storage of the developing site. However, the current guidelines only taking into account the quantitative reduction lost within the development site, and did not consider the qualitative decrease in the carbon sequestration capacity of forest edge produced by developments. In order to assess the quantitative and qualitative effects of vegetation carbon uptake, the CASA-NPP model and satellite image spatial-temporal fusion were used to estimate the annual net primary production in 2005 and 2015. The development projects between 2006 and 2014 were examined for evaluate quantitative changes in development site and qualitative changes in surroundings by development types. The RMSE value of the satellite image fusion results is less than 0.1 and approaches 0, and the correlation coefficient is more than 0.6, which shows relatively high prediction accuracy. The NPP estimation results range from 0 to $1335.53g\;C/m^2$ year before development and from 0 to $1333.77g\;C/m^2$ year after development. As a result of analyzing NPP reduction amount within the development area by type of forest development, the difference is not significant by type of development but it shows the lowest change in the sports facilities development. It was also found that the vegetation was most affected by the edge vegetation of industrial development. This suggests that the industrial development causes additional development in the surrounding area and indirectly influences the carbon sequestration function of edge vegetaion due to the increase of the edge and influx of disturbed species. The NPP calculation method and results presented in this study can be applied to quantitative and qualitative impact assessment of before and after development, and it can be applied to policies related to greenhouse gas in environmental impact assessment.

Analysis of Consumption of Homemade Organically Processed Food Analysis of The Carbon Emission Reduction Effect from No-Tillage in Pepper (Capsicum annuum L.) Cultivation (고추의 무경운 재배에 따른 탄소저감효과 분석)

  • Lee, Gil-Zae;Choi, Yoon-Sil;Yang, Seung-Koo;Lee, Jin-Hong;Yoon, Sung-Yee
    • Korean Journal of Organic Agriculture
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    • v.20 no.4
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    • pp.503-518
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    • 2012
  • Korean type of no-tillage cultivation method which was applied on this study used the ridge and the furrow and constantly recycling them as it was suitable for Korea's weather and farming conditions. This no-tillage cultivation was reported to have little negative impact such as reduction of production (Kwon et al., 1997). In addition, it was found to have a lot of benefits as it requires less agro-materials and energy costs as well as shortened working hours because tillage operation is not needed. (Yang et al., 2012). According to an analysis, no-tillage cultivation can reduce greenhouse gas emissions by $344.7kgCO^2$ (58%) in every 10a ($1,000m^2$) compared to ordinary pepper farming technique (Korea averages). Direct-indirect reduction effects from using fertilizer and using less amount of energy were 92% and 44% respectively both of which can be considered very high. Besides the direct effects of no-tillage cultivation, soil management using no-tillage technique raises carbon sequestration effect on soil as time goes on (West & Marland, 2002), that is why the technique is expected to have constant carbon emission reduction effect. For theses reasons, distribution and expansion of Korean type no-tillage cultivation are expected to play a role as major agro-green technologies for achieving our goal of reducing greenhouse gas emissions in agricultural sector.

A Comparative Study on the $CO_2$ Storage Method ($CO_2$ 해양처리방안 비교연구)

  • Jung, R.T.;Kang, S.G.;Kang, C.G.;Park, Y.C.;Yoon, C.H.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.8 no.3
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    • pp.111-115
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    • 2005
  • The concentration of atmosphere carbon dioxide ($CO_2$) which is one of the major greenhouse gas, continues to rise by the increase in fossil fuel consumption, forest destruction and decrease of biological diversity, etc. In order to weaken the global warming, a reduction of $CO_2$ discharge to the atmosphere is required. The $CO_2$ ocean sequestration technology utilizes the intrinsic oceanic capacity of $CO_2$ absorption, diluting and/or dispersing the liquefied $CO_2$ in the deep ocean (>2,000 m). This geo-engineering approach is regarded as one of the occasions to mitigate the $CO_2$ concentration in the atmosphere. Some developed centuries such as Japan, USA, Norway, etc. have intensively carried out the projects on the research and development of $CO_2$ ocean sequestration since 1990s. There have been several approaches to develop the relative technological system to mitigate the increasing $CO_2$, however, there was no systematic and practical R&D programme in the $CO_2$ ocean sequestration. This paper has described the state of the art on the three optional methods of $CO_2$ sequestration, and compared with them in the aspect of the applicable possibility.

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Selective Catalytic Reduction of NO on Manganese Sulfates (망간황화물을 이용한 NO의 선택적 촉매 환원)

  • Jeong, Soon Kwan;Park, Tae Sung;Hong, Sung Chang
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.473-478
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    • 2008
  • In this experimental, selective catalytic reduction (SCR) of NO with NH3 over manganese sulfates and manganese sulfates was investigated with catalytic activity, kinetics, temperature programmed reduction (TPR) and TGA. Manganese oxides showed high catalytic activity for SCR at temperature below $200^{\circ}C$. In case of manganese sulfates, the temperature at which SCR of nitric oxide appears shifted to high temperature with sulfation degree, and the maximum catalytic efficiency decreased. The temperature of the onset of reduction for manganese oxides and manganese sulfates is about $160^{\circ}C$ and over $280^{\circ}C$, respectively. We suggest that the onset of reduction in TPR correlates with the onset of SCR activity. Because the pre-exponential factor of manganese sulfates is lower as 1/1000 times than that of other catalysts, catalytic activity of manganese sulfates for NO showed low. The reduction temperature of natural manganese ore which consists of various metal oxides showed lower than that of pure manganese oxides.

The Analysis of Potential Reduction of CO2 Emission In Soil and Vegetation due to Land use Change (토지이용변화에 따른 식생 및 토양의 이산화탄소 저감잠재량 분석)

  • Lee, Dong-Kun;Park, Chan
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.2
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    • pp.95-105
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    • 2009
  • Land Use Changes (LUCs) have effects on greenhouse gas emissions and carbon stocks in soil and vegetation. Therefore, predictions for LUC are very important for achieving quantitative targets of $CO_2$ reduction rates. Some research exists on carbon fluxes and carbon cycles to estimate carbon stocks in terrestrial ecosystems in Korea. However, these researches have limitations in terms of helping us understand future potential reductions of $CO_2$ that reflect the influence of LUC. The aim of this study is to analyze the reduction levels of $CO_2$ emissions while considering LUC scenarios that effect carbon fluxes for LCS basic study in the year 2030. In this study, a common approach to model the effects of LUC on carbon stocks is the use of CA-Markov technical process with LUC patterns in the past. Potential reduction of $CO_2$ is calculated by change of land use that contains different soil organic carbon, each land use type, and biomass in vegetation. An IPCC analytical method of natural carbon sink and coefficient results from previous study in Korea is used as a calculation method for potential reduction of $CO_2$. As a result, 12,419 KtC will be reduced annually, which is 8.3% percent of 2005 $CO_2$ emissions in Korea. This will result in 3,226 hundred million won of economic efficiency. In conclusion, conservation of natural carbon sinks is necessary even if the amount of potential reduction change is little.

Recent Development of Carbon Dioxide Conversion Technology (이산화탄소 전환 기술의 현황)

  • Choi, Ji-Na;Chang, Tae-Sun;Kim, Beom-Sik
    • Clean Technology
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    • v.18 no.3
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    • pp.229-249
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    • 2012
  • At present, global warming and depletion of fossil fuels have been one of the big issues which should be solved for sustainable development in the future. CCS (carbon capture and sequestration) technology as the post $CO_2$ reduction technology has been considered as a promising solution for global warming due to increased carbon emission. However, the environmental and ecological effects of CCS have drawn concerns. There are needs for noble post reduction technology. More recently, CCU (carbon capture and utilization) Technology, which emphasizes transforming carbon dioxide into value-added chemicals rather than storing it, has been attracted attentions in terms of preventing global warming and recycling the renewable carbon source. In this paper, various technologies developed for carbon dioxide conversion both in gas and liquid phase have been reviewed. For the thermochemical catalysis in gas phase, the development of the catalytic system which can be performed at mild condition and the separation and purification technology with low energy supply is required. For the photochemical conversion in liquid phase, efficient photosensitizers and photocatalysts should be developed, and the photoelectrochemical systems which can utilize solar and electric energy simultaneously are also in development for more efficient carbon dioxide conversion. The energy needed in CCU must be renewable or unutilized one. CCU will be a key connection technology between renewable energy and bio industry development.