• Title/Summary/Keyword: reduced iron

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Evaluation of Improvement on Sediment for Practical Application in Prawn Farm (새우 양식장에 적용을 위한 저질개선 평가)

  • Kim Woo-Hang;Kim Doo Hee
    • Proceedings of KOSOMES biannual meeting
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    • 2004.05b
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    • pp.81-84
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    • 2004
  • Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

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Hardenability of Ductile Cast Iron (구상흑연주철의 경화능)

  • Lee, Y.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.1 no.1
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    • pp.13-23
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    • 1988
  • The hardenability of alloyed ductile cast irons was studied for 54 different alloy compositions obtained from eight commercial and laboratory foundries. The alloying elements investigated for their effects on hardenability were Si(2.0 to 3.0%), Mn(0.0 to 0.8%), Mo(0.0 to 0.6%), Cu(0.0 to 1.5%), and Ni(0.0 to 1.5%). Two hardenability criteria, a first-pearlite hardenability criterion and a half-hard hardenability criterion, were used to determine hardenability of ductile irons. Prediction models for each hardenability criterion were developed by multiple regression analysis and were well agreed with previous experimental results. Molybdenum was the most potent hardenability promoting element followed by manganese, copper and nickel ; silicon had little effect on hardenability and reduced the hardenability as silicon content increased. When alloying elements were presented in combination, strong synergistic effects on the hardenability were observed especially between molybdenum, copper and nickel. The hardenability of ductile iron was strongly influenced by austenitizing temperature. Increasing austenitizing temperature up to $955^{\circ}C$, hardenability increased gradually but decreasing rate and then decreased as temperature increased above $955^{\circ}C$. Unless reducing segregation by very long-time annealing treatment, the hardenability of ductile iron was not significantly influenced by segregation of alloying elements.

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Synthesis of Nanoscale Zerovalent Iron Particle and Its Application to Cr(VI) Removal from Aqueous Solutions

  • Awad, Yasser M.;Abdelhafez, Ahmed A.;Ahmad, Mahtab;Lee, Sang-Soo;Kim, Rog-Young;Sung, Jwa-Kyung;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.402-407
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    • 2010
  • Zerovalent iron (ZVI) is one of the most commonly used metallic reducing agents for the treatment of toxic contaminants in wastewater. Traditional ZVIs are less effective than nanoscale ZVI (nZVI) due to prolonged reaction time. However, the reactivity can be significantly increased by reducing the size of ZVI particles to nanoscale. In this study, nZVI particles were synthesized under laboratory condition and their efficiency in removing hexavalent chromium (Cr(VI)) from aqueous solutions were compared with commercially available ZVI particles. The results showed that the synthesized nZVI particles (SnZVI) reduced >99% of Cr(VI) at the application rate of 0.2% (w/v), while commercial nZVI (CnZVI) particles resulted in 59.6% removal of Cr(VI) at the same application rate. Scanning electron micrographs (SEM) and energy dispersive spectra (EDS) of the nZVI particles revealed the formation of Fe-Cr hydroxide complex after reaction. Overall, the SnZVI particles can be used in treating chromium contaminated wastewater.

Analysis of WPT Characteristics by Shielding Materials (차폐 재질에 따른 무선전력전송 특성 분석)

  • Lee, Yu-Kyeong;Jeong, In-Sung;Choi, Hyo-Sang
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.4
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    • pp.623-628
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    • 2015
  • In this paper, the shield plate was applied to the wireless power transfer (WPT) system. Then we compared transmission efficiency of WPT system between transmitter and receiver coils. The superconductor coil was applied to transmitter and receiver coils in order to increase the transmission efficiency of WPT. The superconductor coil was more effective to power transmission as its current density was higher than normal conductor coil. Efficiency of WPT between transmitter and receiver coils was changed by a quality of shielding. We used the shielding materials such as glass, iron, steels, aluminum etc. The efficiency of WPT system was depended on the shielding materials of transmitter and receiver coils. As a result, magnetic material such as aluminum, iron reduced the magnetic flux density and the efficiency of WPT. remarkably, but in non-magnetic material such as glass and plastic, the efficiency of WPT was unaffected.

Mineralogy and Iron Chemistry of Garnets and Clinopyroxenes in the Skarn Deposits, the Hambaek Geosyncline Belt, Korea (함백지향내의 스카른광상에서 산출되는 석류석과 단사휘석의 광물학과 철화학)

  • 최진범;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.4 no.2
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    • pp.119-128
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    • 1991
  • In the southern limb of the Hambaek geosyncline belt, large-scaled skarn deposits are developed in the Cambro-Ordovician sedimentary rocks of the Chosun Supergroup. They are the Sangdong tungsten deposit, Geodo iron-copper deposit, Yeonhwa I and II lead-zinc deposits, and Ulchin zinc-lead deposit, all of which are associated with various skarn minerals. Though different occurrences and paragenesis are found in different deposits, most skarn deposits always have skarns of garnet (andradite-grossular series) and clinopyroxene(heden-bergite-diopside series). Andradite and hedenbergite are Fe-dominant members, but show different oxidation states, that is, Fe3+ for andradite and Fe2+ for hedenbergite. According to iron chemistry and log([Fe/Al]gd/[Fe/Mg]cpx) derived from equilibrium reactions, the diopside-andradite and hedenbergite-grossular pairs suggest the oxidized state (dian type) and reduced state (hegro type), respectively. Among skarn deposits developed in the Hambaek geosynline, it can be classified that the Geodo and Yeonhwa I skarns are of dian type, while the Sangdong, Yeonhwa II, and Ulchin deposits are of hegro type. This classification is not applicable to all kinds of skarn deposits, but may be applicable to such deposits as are more controlled by oxygen fugacity than composition of skarn fluid.

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Effect of DNA Repair Inhibitors and Iron on the Chromosome Aberration Induced by Bleomycin and Hydrogen Peroxide in CHO Cells (DNA 회복합성저해제 및 철이 Bleomycin과 과산화수소에 의해 유발된 CHO 세포의 염색체 이상빈도에 미치는 영향)

  • 정해원;유은경
    • Journal of Environmental Health Sciences
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    • v.19 no.4
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    • pp.59-66
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    • 1993
  • The cellular toxicity and antitumor effects of bleomycin are thought to be occurred by formation of O$_2$-Fe$^{2+}$-bleomycin complexes that degrade DNA and release O$_2^-$ and $^{\cdot}$OH radicals. Hydroxyl radicals derived from hydrogen peroxide seem most likely to be involved in the various stages of carcinogenesis, and transition metals such as iron play a central role in activation of bleomycin and in formation of hydroxyl radicals. This study was performed to investigate whether treatment with ferrous sulfate increase chromosome aberration induced by bleomycin and hydrogen peroxide, and whether there is different repair mechanism for DNA damage induced by those chemicals. Treatment with 3AB, Ara C, during G$_1$ and post-treatment with caffeine, and Hu during G$_2$ increased the frequency of chromosome aberration induced by bleomycin but post-treatment with caffeine only did function that way when hydrogen peroxide was treated. When 6.6X 10$^{-7}$ M of bleomycin or 5.0X10$^{-5}$M of hydrogen peroxide were treated simultaneously with iron, the frequency of chromosome aberration was reduced, if compared with the results by bleomycin or hydrogen per oxide alone.

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Effect of Annealing for YIG Single Crystal Thick Films (YIG 단결정 후막의 열처리의 효과)

  • 김근영;윤석규;김용탁;이성문;윤대호
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.855-858
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    • 2003
  • When the PbO-based flux system is used in the Liquid Phase Epitaxy (LPE) method for Yttrium Iron Garnet (YIG) thick film, the effect of Pb ions incorporated into the grown crystal; increase the lattice parameter, changed the uniaxial magnetic anisotropy constant (Ku) or conductance of grown film. It exerts a bad influence on physical property such as increasing optical absorption of grown film. The content of the Pb ion in crystal was decreased by volatilization of Pb ion after annealing; therefore, the lattice parameter of film was reduced on an average 0.0115 ${\AA}$ by the the Pb ion.

The Research for a Structure of Current Limiter using a Phasic Similitude of Magnetic Circuit (자기회로의 위상학적 상사성을 이용한 전류제한기 구조에 관한 연구)

  • Ji, Geun-Yang;Min, Kyung-Il;Lee, Su-Won;Jang, Bong-Hwan;Moon, Young-Hyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.11
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    • pp.2128-2135
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    • 2009
  • In this paper, current limiter using a magnetic switching which is based on magnetic flux change in the case of fault is proposed. This current limiter consists of iron-core and three parts of coils. One is the primary coil connected to the power system. Another is the secondary coil wound to the opposite direction of the primary coil's winding. The other is the secondary of the secondary coil which is a movable copper plate winding and located below the secondary coil. In the normal state, the magnetic flux produced in the primary and secondary coils flows to the opposite directions each other and becomes to be canceled out. Therefore the voltages induced between the coils are zero. In the case of a fault, at the moment of a fault occurrence recognition, the switch connected to a secondary coil is opened and the secondary of the secondary coil is pulled out to the outside of the iron-core. Then, magnetic flux becomes to flow through the iron-core. Accordingly, the voltage is induced between the both ends of the primary coil and makes the current reduced. Therefore it is possible to cut off the circuit breaker easily with the proposed current limiter. This paper analyzes the current limiting effects and the detailed results are given.

Effects of Processing and Designing Variables on Formation of Shrinkage Cavities in GC150 Gray Cast Iron (GC150 회주철의 수축결함생성에 미치는 주조 및 설계공정인자들의 영향)

  • Yu, Sung-Kon;Shin, Sang-Woo
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.580-586
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    • 2002
  • The effect of processing and designing variables such as pouring temperature(1400 or $1500^{\circ}C$), inoculation and risering design(T and H type) on the formation of defects such as external depression, primary and secondary shrinkage cavities in GC150 gray cast iron was investigated. In T type risering design, external depression or primary shrinkage cavity due to liquid contraction was formed in all of the eight cases. Regardless of its modulus value, the riser could not function properly in T type risering design because directional solidification was not promoted toward the riser. On the other hand, the four cases of H type risering design in which thermal sleeves were set onto the risers produced defect-free castings. In both types of the risering designs, secondary shrinkage cavity caused by solidification contraction was not observed in the casting because of the expansion pressure due to graphite precipitation and the application of rigid pep-set mold. The degree of external depression or primary shrinkage cavity was reduced with lowered pouring temperature. The effect of inoculation was diminished because of the high carbon equivalent of GC 150 gray cast iron.

Direct and Indirect Reduction of Cr(VI) by Fermentative Fe(III)-Reducing Cellulomonas sp. Strain Cellu-2a

  • Khanal, Anamika;Hur, Hor-Gil;Fredrickson, James K.;Lee, Ji-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.31 no.11
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    • pp.1519-1525
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    • 2021
  • Hexavalent chromium (Cr(VI)) is recognized to be carcinogenic and toxic and registered as a contaminant in many drinking water regulations. It occurs naturally and is also produced by industrial processes. The reduction of Cr(VI) to Cr(III) has been a central topic for chromium remediation since Cr(III) is less toxic and less mobile. In this study, fermentative Fe(III)-reducing bacterial strains (Cellu-2a, Cellu-5a, and Cellu-5b) were isolated from a groundwater sample and were phylogenetically related to species of Cellulomonas by 16S rRNA gene analysis. One selected strain, Cellu-2a showed its capacity of reduction of both soluble iron (ferric citrate) and solid iron (hydrous ferric oxide, HFO), as well as aqueous Cr(VI). The strain Cellu-2a was able to reduce 15 μM Cr(VI) directly with glucose or sucrose as a sole carbon source under the anaerobic condition and indirectly with one of the substrates and HFO in the same incubations. The heterogeneous reduction of Cr(VI) by the surface-associated reduced iron from HFO by Cellu-2a likely assisted the Cr(VI) reduction. Fermentative features such as large-scale cell growth may impose advantages on the application of bacterial Cr(VI) reduction over anaerobic respiratory reduction.