• Title/Summary/Keyword: recycling efficiency

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Effect of substrate concentration on the operating characteristics of microbial electrolysis cells (기질 농도에 따른 미생물전기분해전지의 운전 특성)

  • Hwijin Seo;Jaeil Kim;Seo Jin Ki;Yongtae Ahn
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.4
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    • pp.41-49
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    • 2023
  • This study examined the effect of input substrate concentration on hydrogen production of microbial electrolysis cells. To compare the performance of MEC according to the input substrate concentration, six laboratory-scale MEC reactors were operated by sequentially increasing the input substrate concentration from 2 g/L of sodium acetate, to 4 g/L, and 6 g/L. The current density, hydrogen production, and SCOD removal rate were analyzed, and energy efficiency and cathodic hydrogen recovery were calculated to compare the performance of MEC. The maximum volumetric current density was obtained at 4 g/L condition (76.3 A/m3) and it decreased to 19.0 A/m3, when the input concentration was increased to 6 g/L, which was a 75% decrease compared to the 4 g/L input condition. Maximum hydrogen production was obtained also at 4 g/L condition (47.3 ± 16.8 mL), but maximum hydrogen yield was obtained at 2 g/L input condition (1.1 L H2/g CODin). Energy efficiencies were also highest in 2 g/L condition; the lowest result was observed at 6 g/L condition. Maximum electrical energy efficiency was 76.4%, and the maximum overall energy efficiency was 39.7% at 2 g/L condition. However, when the substrate concentration increased to 6 g/L, the performance was drastically decreased. Cathodic hydrogen recovery also showed a similar tendency with energy efficiency, with the lowest concentration condition showing the best performance. It can be concluded that operating at low input substrate concentration might be better when considering not only hydrogen yield but also energy efficiency.

Utilization of Waste Concrete as Vertical Drain Material (연직배수재료로 폐콘크리트 활용에 관한 기초연구)

  • 이용수;정하익;김우성;권용완
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.571-576
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    • 2001
  • This paper presents the utilization of waste concrete as vertical drain material. The materials used as vertical drain material were the waste concrete, obtained from the demolished apartments or concrete structure and sand. In this study, laboratory model test was performed to investigate settlement and bearing capacity between sand compaction pile and waste concrete compaction pile. The results of laboratory model test showed that the improvement efficiency of soft ground by waste concrete compaction pile was better than sand compaction pile.

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The adsorption efficiency of ceramic filter media prepared with the steel-making slag for the removal of VOCs (휘발성 유기화합물 제거를 위한 제강슬래그로 제조된 세라믹 여재의 흡착효율)

  • Sin, Jun-Ho;Kim, Tae-Heui;Park, Kyung-Bong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.153-157
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    • 2010
  • We studied the adsorption efficiency of steelmaking slag in removing volatile organic compounds (VOCs) for increasing the recycling rate of steel-making slag. Ceramic filter was prepared by mixing the steel-making slag and the diatomite which is used as adsorbents due to the advantage of the high specific surface area and regular mesopores. The adsorption efficiency for VOCs removal was about 80%, 96% and 85% in acetaldehyde, formaldehyde and ammonia, respectively. The adsorption efficiency over 80% for all The gases showed the practical possibility as the adsorption filter.

Recycling of Wastepaper(12) -Froth-Flotation Conditions for Enhancement of Fines Fractionation Selectivity and Efficiency- (고지재생연구(제12보) -부상부유 처리의 미세분 분급 선택성과 효율 상승을 위한 처리조건-)

  • 여성국;류정용;신종호;송봉근;서영범
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.1
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    • pp.16-23
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    • 2001
  • Hydraulic transport of fines up to the surface of flotation cell was supposed to be a mechanism of fines fractionation through the froth-flotation. Efficient fractionation of fines means efficient skimming out of flotation rejects as much as possible with least long fiber loss. The selectivity of fines fractionation was found to be mainly affected by long fibers flocculation degree in this study. Lack of sufficient flocculation of long fibers could lead to extensive loss of long fibers. It was also found that higher flotation flux caused higher flotation reject as well as the increase of long fiber loss, but did not affect the fine content ratio in the flotation reject. We controlled the flotation flux and the stock consistency, and chose a cationic polymer to maximize the flocculation of long fibers and to increase the amount of flotation reject. The highest efficiency of fines fractionation was obtained at 1.3% of stock consistency and at 100L/min of flotation flux in our experimental set up. The cationaic polymer we chose was found to be very effective in fiber flocculation and flotation froth stabilization. New definitions of fractionation efficiency were introduced in this study to compare the results more clearly.

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Sales Energy Promotion Efficiency and Policy Utilization Plan for Energy Facilities

  • KWON, Lee-Seung;LEE, Woo-Sik;KWON, Woo-Taeg
    • Journal of Distribution Science
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    • v.18 no.9
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    • pp.67-75
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    • 2020
  • Purpose: The purpose of this study is to enhance sales promotion efficiency for using solid refuse fuel facilities. Renewable energy technology using Solid Refuse Fuel (SRF) is an economic efficiency technology that recovers waste by burning various wastes. A survey on the pollutants discharged from the solid fuels facilities was investigated so that the SRF facilities could be expanded, distributed and reflected in the policy. Research design, data, and methodology: In this study, 9 business sites using SRF and Bio-SRF as main raw materials were investigated for 2 years. The characteristics of target business sites such as the type of fuel used, combustion method, combustion temperature, daily fuel consumption and environmental prevention facilities were studied. Results: The average pollution & ammonia concentration of Bio-SRF facilities was found to be 88.15% higher than that of SRF facilities. But the average acetaldehyde concentration of SRF facilities was found to be 88.15% higher than that of Bio-SRF facilities. Conclusions: The main issue is how much electric power generation using combustible materials affects air pollution. The waste recycling law provides the standard value according to the fuel property, but there is a considerable gap with the mixed fuel. Therefore, for efficient utilization of facilities using solid fuel products, additional research is needed to improve the distribution structure of exhaust pollutants is needed.

Development of Synthetic Sizing Agent Using Recycling Polyethylene Terephthalate and its Sizing Efficiency (Part 2) - Sizing efficiency of modified PET - (재활용 PET를 활용한 합성 사이즈제 개발 및 종이의 내수성 부여에 관한 연구 (제2보) - 개질 PET의 내수특성 평가 -)

  • Park, Jae-Seok;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.95-101
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    • 2010
  • For the development of higher-sizing performance of paper, a sizing agent using recycled PET was synthesised. Polyester resin was extracted from wasted PET by subcritical hydrolysis and finally modified to synthetic sizing agent by mixing water-disperse PET with triphenyl phosphite(TPP). The modified PET was considered as an internal sizing agent in different wet-end papermaking conditions. The optimum condition in sizing efficiency was obtained in initial pH of 6.5 in case of rosin+alum system, and 7.5 in case of rosin+alum+PET system, respectively, and in addition amount of PET 3%. The sizing efficiency was also closely related according to the fiber properties of wet-end slurry, such as virgin fibres from UKP and recycled fibres from KOCC. The application of modified PET was good in strength improvement of paper, specially in tensile strength.

Parametric study for enhanced performance of Cu and Ni electrowinning

  • Kim, Joohyun;Kim, Han S.;Bae, Sungjun
    • Membrane and Water Treatment
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    • v.10 no.3
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    • pp.201-206
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    • 2019
  • In this study, we performed an electrowinning process for effective removal of metals (Cu and Ni) in solution and their recovery as solid forms. A complete removal of Cu and Ni (1,000 mg/L) was observed during four times recycling test, indicating that our electrowinning system can ensure the efficient metal removal with high stability and durability. In addition, we investigated effect of operation parameters (i.e., concentration of boric acid only for Ni, variation of pH, concentration of electrolyte ($H_2SO_4$), and cell voltage) on the efficiency of metal removal (Cu and Ni) during the electrowinning. The addition of boric acid significantly enhanced removal efficiency of Ni as the concentration of boric acid increased up to 10 g/L. Compared to negligible pH effect (pH 1, 2, and 4) on the Cu removal, we observed the increase in removal efficiency of Ni as the pH increased from 1 to 4. The electrolyte concentration did not significantly influence the removal of Cu and Ni in this study. We also obtained great removal rates of Cu and Ni at 2.5 V and 4.0 V, which were much faster than those at lower voltages. Finally, almost 99% of each Cu and Ni (1,000 mg/L) was selectively removed from the mixture of metals by adjusting pH and addition of boric acid after the completion of Cu removal. The findings in this study can provide a fundamental knowledge about effect of important parameters on the efficiency of metal recovery during the electrowinning.

On the Recycling Substances and a Clean Technology Development for the Treatment of Mixed Acid Waste Water with Ozone (오존을 이용한 혼산폐수처리에 관한 청정기술개발 및 재이용 물질 회수에 관한 연구)

  • 김재우
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.34-40
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    • 2000
  • In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.

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Removal Characteristics of Nitrogen and Phosphorus in swine wastewater by Using Acetic acid on the SBR Process (SBR에서 아세트산을 이용한 양돈폐수의 질소·인 제거 특성)

  • Huh, Mock;Kang, Jin-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.12 no.1
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    • pp.84-93
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    • 2004
  • This study was performed : 1) to find the suitable HRT(hydralic retention time), 2) to evaluate the effects of the ratio of mixing/aeration time and injection time of external carbon source, for the removal of organics, nitrogen and phosphorus in swine wastewater by SBR(sequencing batch reactor process), which is one of the biological treatment process. The result of this study were summarized as follows : (1) As the ratio of mixing/aeration time was higher, $NH_4{^+}-N$ removal efficiency was increased and it was increased with increasing injection time of external carbon source because nitrification was affected by denitrification microbes propagation when injection time of external carbon soruce was shorted. T-N removal efficiency was increased with increasing the ratio of mixing/aeration time and injection time of external carbon source. (2) The T-P removal efficiency showed a great difference in each operating condition, and it was increased with increasing the ratio of mixing/aeration time increased and when the injection time of external carbon source was shorted because denitrification was done with effect by denitrification microbes propagation. (3) The highest removal efficiency of organic and nitrogen were obtained by the operating condition of Run 4-1(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 15hours) and T-P were obtained by the operation condition of Run 4-2(the ratio of mixing/aeration time : 16.5/5.5, injection time of external carbon source : 3hours), and efficiency(effluent concentration)of $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, T-N and T-P in the treated water was 96.1%, 87.7%, 90.6%, 86.6% and 84.5%, respectively.

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Heat Balance during the Electrowinning of Neodymium Metal in Molten Salt (네오디뮴 금속의 전해 채취 중의 열수지)

  • Cho, Sung-Wook;Yu, Jeong-Hyun;Choi, Ho-Gil
    • Resources Recycling
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    • v.31 no.3
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    • pp.81-87
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    • 2022
  • Energy consumption per unit weight of metal (kwh/kg of metal) is one of the most important economic indicators in the process of molten salt electrolysis. It is related to the heat loss of salt bath and the current efficiency of the process. The current efficiency is highly dependent on electrolysis temperature. On the other hand, the temperature of salt bath may increase significantly due to the difference (larger energy input than consumption) in heat balance at the beginning of electrolysis, which may cause different electrolysis temperature from an initially targeted value. This results in a bad effect on current efficiency. Therefore, it will be helpful to the reduction of energy consumption to compare the calculated and measured values of the temperature change of salt bath through the heat balance review at the early stage of electrolysis and to evaluate the energy loss to outside. In this study, based on the authors' experimental data, the heat balance was reviewed at the beginning of the electrolysis, and it was possible to evaluate the energy loss to the outside and the increase of the temperature of the salt bath quantitatively. Through such a method, heat loss reduction plan can be derived and current efficiency can be improved so that energy consumption can be reduced.