Abstract
In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.
