• Title/Summary/Keyword: real-time particle characterization

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Effects of Temperature and Precursor-concentration on Characteristics of TiO2 Nanoparticles in Chemical Vapor Condensation Process -Part I: Real-time Particle Characterization by SMPS (화학기상응축 공정에서 TiO2 나노입자 특성에 미치는 반응온도와 전구체 농도의 영향 - Part I: SMPS를 이용한 실시간 입자특성 평가)

  • Lee, Chang-Woo;Yu, Ji-Hun;Im, Sung-Soon;Yun, Sung-Hee;Lee, Jai-Sung;Choa, Yong-Ho
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.323-327
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    • 2003
  • Properties of nanoparticles synthesized during gas phase reaction were studied in terms of particle behaviors using real-time particle characterization method. For this study, $TiO_2$ nanoparticles were synthesized in the chemical vapor condensation process(CVC) and their in-situ measurement of particle formation and particle size distribution was performed by scanning mobility particle sizer(SMPS). As a result, particle behaviors in the CVC reactor were affected by both of number concentration and thermal coagulation, simultaneously. Particularly, growth and agglomeration between nanoparticles followed two different ways of dominances from coagulations by increase of number concentration and sintering effect by increased temperature.

Aerosol Particle Analysis Using Microwave Plasma Torch (마이크로파 플라즈마 토치를 이용한 에어로졸 입자 분석)

  • Kim, Hahk-Joon;Park, Ji-Ho
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.204-207
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    • 2011
  • A particle counting system that can also provide sensitive, specific chemical information, while consuming very less power, occupying less space, and being inexpensive has been developed. This system uses a microwave plasma torch (MPT) as the excitation source for atomic emission spectrometry (AES). Emission from a single particle can be detected, and the wavelength at which the emission is observed indicates the elements present in the particle. It is believed that correlating the particle size and emission intensity will allow us to estimate the particle size in addition to abovementioned capabilities of the system. In the long term, this system can be made field-portable, so that it can be used in atmospheric aerosol monitoring applications, which require real-time detection and characterization of particles at low concentrations.

Verification of a novel fuel burnup algorithm in the RAPID code system based on Serpent-2 simulation of the TRIGA Mark II research reactor

  • Anze Pungercic;Valerio Mascolino ;Alireza Haghighat;Luka Snoj
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3732-3753
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    • 2023
  • The Real-time Analysis for Particle-transport and In-situ Detection (RAPID) Code System, developed based on the Multi-stage Response-function Transport (MRT) methodology, enables real-time simulation of nuclear systems such as reactor cores, spent nuclear fuel pools and casks, and sub-critical facilities. This paper presents the application of a novel fission matrix-based burnup methodology to the well-characterized JSI TRIGA Mark II research reactor. This methodology allows for calculation of nuclear fuel depletion by combination and interpolation of RAPID's burnup dependent fission matrix (FM) coefficients to take into account core changes due to burnup. The methodology is compared to experimentally validated Serpent-2 Monte Carlo depletion calculations. The results show that the burnup methodology for RAPID (bRAPID) implemented into RAPID is capable of accurately calculating the keff burnup changes of the reactor core as the average discrepancies throughout the whole burnup interval are 37 pcm. Furthermore, capability of accurately describing 3D fission source distribution changes with burnup is demonstrated by having less than 1% relative discrepancies compared to Serpent-2. Good agreement is observed for axially and pin-wise dependent fuel burnup and nuclear fuel nuclide composition as a function of burnup. It is demonstrated that bRAPID accurately describes burnup in areas with high gradients of neutron flux (e.g. vicinity of control rods). Observed discrepancies for some isotopes are explained by analyzing the neutron spectrum. This paper presents a powerful depletion calculation tool that is capable of characterization of spent nuclear fuel on the fly while the reactor is in operation.

Potential of polylactic-co-glycolic acid (PLGA) for delivery Jembrana disease DNA vaccine Model (pEGFP-C1-tat)

  • Unsunnidhal, Lalu;Wasito, Raden;Setyawan, Erif Maha Nugraha;Warsani, Ziana;Kusumawati, Asmarani
    • Journal of Veterinary Science
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    • v.22 no.6
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    • pp.76.1-76.15
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    • 2021
  • Background: The development of a vaccine for Jembrana disease is needed to prevent losses in Indonesia's Bali cattle industry. A DNA vaccine model (pEGFP-C1-tat) that requires a functional delivery system will be developed. Polylactic-co-glycolic acid (PLGA) may have potential as a delivery system for the vaccine model. Objectives: This study aims to evaluate the in vitro potential of PLGA as a delivery system for pEGFP-C1-tat. Methods: Consensus and codon optimization for the tat gene was completed using a bioinformatic method, and the product was inserted into a pEGFP-C1 vector. Cloning of the pEGFP-C1-tat was successfully performed, and polymerase chain reaction (PCR) and restriction analysis confirmed DNA isolation. PLGA-pEGFP-C1-tat solutions were prepared for encapsulated formulation testing, physicochemical characterization, stability testing with DNase I, and cytotoxicity testing. The PLGA-pEGFP-C1-tat solutions were transfected in HeLa cells, and gene expression was observed by fluorescent microscopy and real-time PCR. Results: The successful acquisition of transformant bacteria was confirmed by PCR. The PLGA:DNA:polyvinyl alcohol ratio formulation with optimal encapsulation was 4%:0.5%:2%, physicochemical characterization of PLGA revealed a polydispersity index value of 0.246, a particle size of 925 nm, and a zeta potential value of -2.31 mV. PLGA succeeded in protecting pEGFP-C1-tat from enzymatic degradation, and the percentage viability from the cytotoxicity test of PLGA-pEGFP-C1-tat was 98.03%. The PLGA-pEGFP-C1-tat demonstrated luminescence of the EGFP-tat fusion protein and mRNA transcription was detected. Conclusions: PLGA has good potential as a delivery system for pEGFP-C1-tat.

Characterization of fine particulate matter during summer at an urban site in Gwangju using chemical, optical, and spectroscopic methods (화학적·광학적·분광학적 방법을 이용한 광주 도심지역 여름철 초미세먼지의 특성)

  • Son, Se-Chang;Park, Tae-Eon;Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.91-106
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    • 2021
  • Daily PM2.5 was collected during summer period in 2020 in Gwangju to investigate its chemical and light absorption properties. In addition, real-time light absorption coefficients were observed using a dual-spot 7-wavelength aethalometer. During the study period, SO42- was the most important contributor to PM2.5, accounting for on average 33% (10-64%) of PM2.5. The chemical form of SO42- was appeared to be combination of 70% (NH4)2SO4 and 30% NH4HSO4. Concentration-weighted trajectory (CWT) analysis indicated that SO42- particles were dominated by local pollution, rather than regional transport from China. A combination of aethalometer-based and water-extracted brown carbon (BrC) absorption indicated that light absorption of BrC due to aerosol particles was 1.6 times higher than that due to water-soluble BrC, but the opposite result was found in absorption Ångström exponent (AAE) values. Lower AAE value by aerosol BrC particles was due to the light absorption of aerosol BrC by both water-soluble and insoluble organic aerosols. The BrC light absorption was also influenced by both primary sources (e.g., traffic and biomass burning emissions) and secondary organic aerosol formation. Finally the ATR-FTIR analysis confirmed the presence of NH4+, C-H groups, SO42-, and HSO42-. The presence of HSO42- supports the result of the estimated composition ratio of inorganic sulfate ((NH4)2SO4) and bisulfate (NH4HSO4).