• Title/Summary/Keyword: reactive behavior

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Post-fire test of precast steel reinforced concrete stub columns under eccentric compression

  • Yang, Yong;Xue, Yicong;Yu, Yunlong;Gong, Zhichao
    • Steel and Composite Structures
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    • v.33 no.1
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    • pp.111-122
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    • 2019
  • This paper presents an experimental work on the post-fire behavior of two kinds of innovative composite stub columns under eccentric compression. The partially precast steel reinforced concrete (PPSRC) column is composed of a precast outer-part cast using steel fiber reinforced reactive powder concrete (RPC) and a cast-in-place inner-part cast using conventional concrete. Based on the PPSRC column, the hollow precast steel reinforced concrete (HPSRC) column has a hollow column core. With the aim to investigate the post-fire performance of these composite columns, six stub column specimens, including three HPSRC stub columns and three PPSRC stub columns, were exposed to the ISO834 standard fire. Then, the cooling specimens and a control specimen unexposed to fire were eccentrically loaded to explore the residual capacity. The test parameters include the section shape, concrete strength of inner-part, eccentricity ratio and heating time. The test results indicated that the precast RPC shell could effectively confine the steel shape and longitudinal reinforcements after fire, and the PPSRC stub columns experienced lower core temperature in fire and exhibited higher post-fire residual strength as compared with the HPSRC stub columns due to the insulating effect of core concrete. The residual capacity increased with the increasing of inner concrete strength and with the decreasing of heating time and load eccentricity. Based on the test results, a FEA model was established to simulate the temperature field of test specimens, and the predicted results agreed well with the test results.

Effect of Al and Mg Contents on Wettability and Reactivity of Molten Zn-Al-Mg Alloys on Steel Sheets Covered with MnO and SiO2 Layers

  • Huh, Joo-Youl;Hwang, Min-Je;Shim, Seung-Woo;Kim, Tae-Chul;Kim, Jong-Sang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1241-1248
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    • 2018
  • The reactive wetting behaviors of molten Zn-Al-Mg alloys on MnO- and amorphous (a-) $SiO_2$-covered steel sheets were investigated by the sessile drop method, as a function of the Al and Mg contents in the alloys. The sessile drop tests were carried out at $460^{\circ}C$ and the variation in the contact angles (${\theta}_c$) of alloys containing 0.2-2.5 wt% Al and 0-3.0 wt% Mg was monitored for 20 s. For all the alloys, the MnO-covered steel substrate exhibited reactive wetting whereas the $a-SiO_2$-covered steel exhibited nonreactive, nonwetting (${\theta}_c>90^{\circ}$) behavior. The MnO layer was rapidly removed by Al and Mg contained in the alloys. The wetting of the MnO-covered steel sheet significantly improved upon increasing the Mg content but decreased upon increasing the Al content, indicating that the surface tension of the alloy droplet is the main factor controlling its wettability. Although the reactions of Al and Mg in molten alloys with the $a-SiO_2$ layer were found to be sluggish, the wettability of Zn-Al-Mg alloys on the $a-SiO_2$ layer improved upon increasing the Al and Mg contents. These results suggest that the wetting of advanced high-strength steel sheets, the surface oxide layer of which consists of a mixture of MnO and $SiO_2$, with Zn-Al-Mg alloys could be most effectively improved by increasing the Mg content of the alloys.

Transport properties of polycrystalline TaNx thin films prepared by DC reactive magnetron sputtering method

  • Hwang, Tae Jong;Jung, Soon-Gil
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.1-5
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    • 2021
  • We have investigated the electrical transport properties of polycrystalline tantalum nitride (TaNx) films. Various compositions of tantalum (nitride) thin films have been deposited on SiO2 substrates by reactive DC magnetron sputtering while changing the ratio of nitrogen partial pressure. The substrate temperature was maintained at 283 K during deposition. X-ray diffraction analyses indicated the presence of α-Ta and β-Ta phases in the Ta film deposited in pure argon atmosphere, while fcc-TaNx phases appeared in the sputtering gas mixture of argon and nitrogen. The N/Ta atomic ratio in the film increased ranging from 0.36 to 1.07 for nitrogen partial pressure from 7 to 20.7%. The superconducting transition temperatures of the TaNx thin films were measured to be greater than 3.86 K with a maximum of 5.34 K. The electrical resistivity of TaNx thin film was in the range of 177-577 𝜇Ωcm and increased with an increase in nitrogen content. The upper critical filed at zero temperature for a TaN0.87 thin film was estimated to exceed 11.3 T, while it showed the lowest Tc = 3.86 K among the measured superconducting TaNx thin films. We try to explain the behavior of the increase of the residual resistivity and the upper critical field for TaNx thin films with the nitrogen content by using the combined role of the intergrain Coulomb effect and disorder effect by grain boundaries.

Static buckling analysis of bi-directional functionally graded sandwich (BFGSW) beams with two different boundary conditions

  • Berkia, Abdelhak;Benguediab, Soumia;Menasria, Abderrahmane;Bouhadra, Abdelhakim;Bourada, Fouad;Mamen, Belgacem;Tounsi, Abdelouahed;Benrahou, Kouider Halim;Benguediab, Mohamed;Hussain, Muzamal
    • Steel and Composite Structures
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    • v.44 no.4
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    • pp.503-517
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    • 2022
  • This paper presents the mechanical buckling of bi-directional functionally graded sandwich beams (BFGSW) with various boundary conditions employing a quasi-3D beam theory, including an integral term in the displacement field, which reduces the number of unknowns and governing equations. The beams are composed of three layers. The core is made from two constituents and varies across the thickness; however, the covering layers of the beams are made of bidirectional functionally graded material (BFGSW) and vary smoothly along the beam length and thickness directions. The power gradation model is considered to estimate the variation of material properties. The used formulation reflects the transverse shear effect and uses only three variables without including the correction factor used in the first shear deformation theory (FSDT) proposed by Timoshenko. The principle of virtual forces is used to obtain stability equations. Moreover, the impacts of the control of the power-law index, layer thickness ratio, length-to-depth ratio, and boundary conditions on buckling response are demonstrated. Our contribution in the present work is applying an analytical solution to investigate the stability behavior of bidirectional FG sandwich beams under various boundary conditions.

An Experimental Study on Alkali-Silica Reaction of Alkali-Activated Ground Granulated Blast Furnace Slag Mortars (알칼리 활성 고로슬래그 미분말 모르터의 알칼리-실리카 반응에 관한 실험적 연구)

  • Kim, Young-Soo;Moon, Dong-Il;Lee, Dong-Woon
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.4
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    • pp.345-352
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    • 2011
  • The purpose of this study was to investigate the expansion of alkali-activated mortar based on ground granulated blast furnace slag containing reactive aggregate due to alkali-silica reaction. In addition, this study was particularly concerned with the behavior of these alkaline materials in the presence of reactive aggregates. The experimental program included expansion measurement of the mortar bar specimens, as well as the determination of the morphology and composition of the alkali-silica reaction products by using scanning electron microscopy(SEM), and energy dispersive x-ray(EDX). The experiment showed that while alkali-activated ground granulated blast furnace slag mortars showed expansion due to the alkali-silica reaction, the expansion was 0.1% at Curing Day 14, showing that it is safe. After the accelerated test, SEM and BEM analysis showed the presence of alkali-silica gel and rim around the aggregate and cement paste. According to the EDX, the reaction products decreased markedly as alkali-activated ground granulated blast furnace slag was used. In addition, for the substitutive materials of mineral admixture, a further study on improving the quality of alkali-activated ground granulated blast furnace slag is needed to assure of the durability properties of concrete.

Simultaneous Removal of Cd and Cr(VI) in the Subsurface Using Permeable Reactive Barrier Filled with Fe-loaded Zeolite: Soil Box Experiment (Fe-loaded zeolite로 충진된 투수성 반응벽체를 이용한 지반 내 Cd과 Cr(VI)의 동시제거: 모형 토조 실험)

  • Rhee, Sung-Su;Lee, Seung-Hak;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.26 no.10
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    • pp.61-68
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    • 2010
  • A pilot-scale model test was performed to estimate the availability of new material, Fe-loaded zeolite, as the filling material in permeable reactive barrier (PRB) against the contaminated groundwater with both Cd and Cr(VI). Aquifer was simulated by filling up a large scale soil tank with sands, and mobilizing the water flow by the head difference of water level in both ends of the tank. Then, the mixture of concentrated Cd and Cr(VI) solution was injected into the aquifer to form a contaminant plume, and its behavior through Fe-loaded zeolite barrier was monitored. The test results showed that Fe-loaded zeolite barrier successfully treated the contaminant plume containing both Cd and Cr(VI) and that the immobilized contaminants in the barrier were not desorbed or released. The results indicated that the Fe-loaded zeolite could be a promising material in PRBs against the multiple contaminants with different ionic forms like Cr(VI) and Cd.

Crystallization Behavior of Poly(lactic acid) / Poly($\varepsilon$-caprolactone) Blends (폴리락트산/폴리카프로락톤 블렌드의 결정화 거동)

  • 이종록;천상욱;강호종
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.285-292
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    • 2003
  • The compatibility of poly(lactic acid)/poly($\varepsilon$-caprolactone) (PLA/PCL) blends as a function of blend composition was studied and triphenyl phosphite (TPP) was applied to PLA/PCL blends as a reactive compatibilizer. Especially the effect of compatibility on the crystallization behavior in both PLA/PCL blends and PLA/PCL blends with TPP was considered. PLA/PCL blends were immiscible based on thermal characteristics of PLA/PCL blends and the miscibility was depend upon the blend composition. The enhancement of compatibility was found in PLA/PCL blends with TPP depend upon its content. The rate of crystallization in PLA/PCL blend varied with blend composition. This was understood as the development of nucleation at the interface of PLA-PCL due to the immiscibility. TPP was acting as a compatibilizer as well as an agent for the acceleration of spherulite growth In PLA. As a result, the crystallization rate increased and the size of spherulite became larger than that of PLA/PCL blend without TPP.

Effect of Parthenogenetic Mouse Embryonic Stem Cell (PmES) in the Mouse Model of Huntington′s Disease

  • 이창현;김용식;이영재;김은영;길광수;정길생;박세필;임진호
    • Proceedings of the KSAR Conference
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    • 2003.06a
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    • pp.80-80
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    • 2003
  • Huntington's disease (HD) is an autosomal dominant neurodegenerative disorder characterized by motor, cognitive, and psychiatric symptoms, accompanied by marked cell death in the striatum and cortex. Stereotaxic injection of quinolinic acid (QA) into striatum results in a degeneration of GABAergic neurons and exhibits abnormal motor behaviors typical of the illness. The objective of this study was carried out to obtain basic information about whether parthenogenetic mouse embryonic stem (PmES) cells are suitable for cell replacement therapy of HD. To establish PmES cell lines, hybrid F1 (C57BL/6xCBA/N) mouse oocytes were treated with 7% ethanol for 5 min and cytochalasin-B for 4 hr to initiate spontaneous cleavage. Thus established PmES cells were induced to differentiate using bFGF (20ng/ml) followed by selection of neuronal precursor cells for 8 days in N2 medium. After selection, cells were expanded at the presence of bFGF (20 ng/ml) for another 6 days, then a final differentiation step in N2 medium for 7 days. To establish recipient animal models of HD, young adult mice (7 weeks age ICR mice) were lesioned unilaterally with a stereotaxic injection of QA (60 nM) into the striatum and the rotational behavior of the animals was tested using apomorphine (0.1mg/kg, IP) 7 days after the induction of lesion. Animals rotating more than 120 turns per hour were selected and the differentiated PmES cells (1$\times$10$^4$cells/ul) were implanted into striatum. Four weeks after the graft, immunohistochemical studies revealed the presence of cells reactive to anti-NeuN antibody. However, only a slight improvement of motor behavior was observed. By Nissl staining, cell mass resembling tumor was found at the graft site and near cortex which may explain the slight behavioral improvement. Detailed experiment on cell viability, differentiation and migration explanted in vivo is currently being studied.

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Improvement of Dynamic Behavior of Shunt Active Power Filter Using Fuzzy Instantaneous Power Theory

  • Eskandarian, Nasser;Beromi, Yousef Alinejad;Farhangi, Shahrokh
    • Journal of Power Electronics
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    • v.14 no.6
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    • pp.1303-1313
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    • 2014
  • Dynamic behavior of the harmonic detection part of an active power filter (APF) has an essential role in filter compensation performances during transient conditions. Instantaneous power (p-q) theory is extensively used to design harmonic detectors for active filters. Large overshoot of p-q theory method deteriorates filter response at a large and rapid load change. In this study the harmonic estimation of an APF during transient conditions for balanced three-phase nonlinear loads is conducted. A novel fuzzy instantaneous power (FIP) theory is proposed to improve conventional p-q theory dynamic performances during transient conditions to adapt automatically to any random and rapid nonlinear load change. Adding fuzzy rules in p-q theory improves the decomposition of the alternating current components of active and reactive power signals and develops correct reference during rapid and random current variation. Modifying p-q theory internal high-pass filter performance using fuzzy rules without any drawback is a prospect. In the simulated system using MATLAB/SIMULINK, the shunt active filter is connected to a rapidly time-varying nonlinear load. The harmonic detection parts of the shunt active filter are developed for FIP theory-based and p-q theory-based algorithms. The harmonic detector hardware is also developed using the TMS320F28335 digital signal processor and connected to a laboratory nonlinear load. The software is developed for FIP theory-based and p-q theory-based algorithms. The simulation and experimental tests results verify the ability of the new technique in harmonic detection of rapid changing nonlinear loads.

Carrier-enhanced Ferromagnetism in Cr-doped ZnO (Cr이 치환된 ZnO에서 나르개에 의한 강자성의 향상)

  • Sim, Jae-Ho;Kim, Hyo-Jin;Kim, Do-Jin;Ihm, Young-Eon;Yoon, Soon-Kil;Kim, Hyun-Jung;Choo, Woong-Kil
    • Journal of the Korean Magnetics Society
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    • v.15 no.3
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    • pp.181-185
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    • 2005
  • We have investigated the effects of Al codoping on the structural, electrical transport, and magnetic properties of oxide diluted magnetic semiconductor $Zn_{1-x}Cr_xO$ thin films prepared by reactive sputtering. Nondoped $Zn_{0.99}Cr_{0.01}O$ thin films show semiconducting transport behavior and weak ferromagnetic characteristic. The Al doping increases the carrier concentration and results in an decrease of resistivity and metal-insulator transition behavior. With increasing carrier concentration, the magnetic properties drastically change, exhibiting a remarkable increase of the saturation magnetization. These results show carrier-enhanced ferromagnetic order in Cr-doped ZnO.