• Title/Summary/Keyword: reaction time

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Optimization of Alkali Pretreatment from Steam Exploded Barley Husk to Enhance Glucose Fraction Using Response Surface Methodology

  • Jung, Ji Young;Ha, Si Young;Park, Jai Hyun;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.2
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    • pp.182-194
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    • 2017
  • The optimum alkali pretreatment parameters (reaction time, reaction temperature and potassium hydroxide concentration) for facilitate the conversion into fermentable sugar (glucose) from steam exploded (severity log Ro 2.45) barley husk were determined using Response Surface Methodology (RSM) based on a factorial Central Composite Design (CCD). The prediction of the response was carried out by a second-order polynomial model and regression analysis revealed that more than 88% of the variation can be explained by the models. The optimum conditions for maximum cellulose content were determined to be 201 min reaction time, $124^{\circ}C$ reaction temperature and 0.9% potassium hydroxide concentration. This data shows that the actual value obtained was similar to the predicted value calculated from the model. The pretreated barley husk using acid hydrolysis resulted in a glucose conversion of 94.6%. This research of steam explosion and alkali pretreatment was a promising method to improve cellulose-rich residue for lignocellulosic biomass.

Formation of Meatlike Flavors by Maillard Reaction Using Hydrolyzed Vegetable Protein (HVP) (HVP를 이용한 Maillard 반응에 의한 Meatlike Flavor의 생성)

  • Yoon, Suk-Hwan;Lee, Jung-Keun;Nam, Hee-Sop;Lee, Hyung-Jae
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.781-786
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    • 1994
  • Meatlike flavors were manufactured using hydrolyzed vegetable protein (HVP) with several reactive precursors at different reaction conditions. Both pH and temperature affected significantly on brown colority of reaction product, whose velocity became fast with increasing pH and temperature. Drastic decrease in residual reducing sugars and free amino acids appeared until 1 hour, being little affected by reaction temperature. Glutamic acid and cysteine were decreased with reaction time, whereas glycine and methionine remained constant. Forty nine aroma compounds formed through Maillard reaction were isolated and identified with GC/MSD, including 3-methyl butanal, 2-methyl tetrahydrothiophen-3-one, 3,4-dimethylthiophene and 2,4-dimethyl thiazole previously known as natural meat flavors. The sensory evaluation showed that one-hour reaction product was the highest in savory taste and the lowest in nasty taste on the level of 5% significant difference among all reaction products tested in this experiment. From the results above, it could be speculated that the initial stage of Maillard reaction in this experimental system occured until one hour, thereafter, savory taste decreased accompanied by increasing nasty taste with elapsed reaction time.

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A Parametric Study of Pervaporation-facilitated Esterification (전산모델링을 통한 투과증발-촉진 에스테르화 반응에 대한 연구)

  • Yeom, C.K.;Choi, Seung-Hak;Park, You-In;Chang, Sung-Soon
    • Membrane Journal
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    • v.17 no.2
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    • pp.146-160
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    • 2007
  • A parametric study on pervaporation-facilitated esterification was performed by using a practical model based on non-perfect separation through membrane which is not perfectly permselective to water. Thus, membrane selectivity as well as membrane capability to remove water should be taken into account in establishing the simulation model to explain how the membrane separation influence the esterification reaction process. It was shown by simulation that in the reaction systems with non-perfect separation, the permeation of reactants which are acid or/and alcohol retards the reaction by inducing the backward reaction so that reaction conversion curve is located between a reaction system coupled with pervaporation process having a perfect permselectivity to water and a reaction system without pervaporation process. The volume change of reaction system occurs as a result of the permeation through the membrane. The reaction volume change which can be characterized by the reaction ratio of $r_{\Psi}\;to\;r_{{\Psi}=1}$ affects reaction kinetics by concentrating reactants and products, respectively, with different extent with time; reactant-concentrating effect is dominant during the initial stage of reaction, resulting in facilitating the reaction, and then product-concentrating effect is exerted more on reaction, causing to slow down the reaction. When pervaporative dehydration is applied to the reaction system plays an important role in the reaction as well. The effect of timing to impose pervaporation on reaction system affected the reaction kinetics in terms of reaction rate and reaction conversion. A relationship was derived to explain membrane unit capacity and reaction parameters that will be used as a design tool to determine membrane unit capacity at a given reaction conditions or reaction parameters at a membrane unit capacity.

Enhancing the Flavor of Pearl Oyster (Pinctada fucata) Extract Using Reaction Flavoring (Reaction Flavoring에 의한 진주조개 (Pinctada fucata) 추출물의 풍미개선)

  • Kang, Jeong-Goo;Nam, Gi-Ho;Kang, Jin-Yeong;Hwang, Seok-Min;Kim, Jeong-Gyun;Oh, Kwang-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.40 no.6
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    • pp.350-355
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    • 2007
  • The optimal substrates and reaction flavoring conditions were examined to develop pearl oyster extract (POE) flavor using the Maillard reaction under a model system. The sugar for the Maillard reaction was glucose, and the amino acid was cysteine, with glycine as the reaction substrate. A three-dimensional response surface method was used to monitor the dynamic changes of the substrates during the Maillard reaction. To enhance the flavor of POE, a two-step enzymatic hydrolysate (Brix $20^{\circ}$) was reacted with the precursors (1:1, v/v). A 2:1:1 mixture of 0.4 M glucose:0.4 M glycine:0.4 M cysteine (v/v) was selected as a suitable reaction system for the reappearance of baked potato odor and boiled meat odor, and masking the shellfish odor. The two-step enzymatic hydrolysate and selected precursors were reacted in a high-pressure reactor to optimize the reaction parameters. The optimum conditions were 150 minutes at $120\;^{\circ}C$ and pH 7.0. The pH was the most critical factor for the response of the baked potato odor and masking the shellfish odor, while the reaction time affected the reappearance of the boiled meat odor.

Refining of Invar and Permalloy Fe-Ni Alloys by $Ar/Ar-H_2$ Plasma and Electron Beam Melting (Ar/Ar-$H_2$ 플라즈마 및 전자선 용해에 의한 인바 및 퍼멀로이 Fe-Ni 합금의 정련)

  • Park, Byung-Sam;Baik, Hong-Koo
    • Journal of Korea Foundry Society
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    • v.15 no.2
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    • pp.175-183
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    • 1995
  • It is difficult to remove such interstitial impurities as sulfur, oxygen, hydrogen and carbon in Fe-Ni alloys. Thermodynamic and kinetic studies were carried out on the behavior of hydrogen gas, oxygen gas, Si, Al and slag, and the reaction time by the $Ar/Ar-H_2$ plasma and electron beam melting. After the addition of Al, Si, they were melted by Ar plasma with reaction time changed. 80%Ni-Fe alloys showed a better deoxidation than 36%Ni-Fe alloys. At $Ar-H_2$ plasma melting, the deoxidation was significant. In the case of the electron beam melting, the residual oxygen was higher than in Ar plasma melting because electron beam melting temperature was lower than that of Ar plasma. For the decaburization, it was melted by $Ar-O_2$ plasma melting, which could remove effectively carbon by activated oxygen in plasma. We added slag to Fe-Ni alloys for the desulfurization. As the result of this experiments, the amount of residual sulfur was not changed according to the slag ratio and reaction time.

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REACTION TIME, SEMEN OUTPUT AND SEMEN QUALITY OF BUFFALO BULLS AFTER PRE-COLLECTION INJECTION OF PROSTAGLANDIN F2 ALPHA (PGF2 ALPHA)

  • Capitan, S.S.;Antiporda, G.S.;Momongan, V.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.3 no.4
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    • pp.343-346
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    • 1990
  • A study was conducted to determine the effect of prostaglandin $F_2$ alpha ($PGF_2$ alpha) on the reaction time and seminal characteristics of buffalo bulls. Semen was collected from three Murrah bulls in three periods: pre-treatment, treatment and post-treatment. During the treatment period each bull was administered 2 ml $PGF_2$ alpha (Synchrocept, Fenprostalene) im, 1 hour prior to semen collection. In the post-treatment, semen was collected 7 days after the last injection of $PGF_2$. Semen samples were evaluated immediately after collection. Pre-collection injection of $PGF_2$ alpha has no significant effect on reaction time, semen volume, percentage motility, sperm concentration and total number of sperms per ejaculate. Fluctuations in semen color and consistency were observed. There is a significant (p<0.05) increase in the mean percentage of normal spermatozoa during the treatment and post treatment periods. Likewise, administration of PG results into a significant (p<0.05) rise on the average percentage of live sperms but this effect was not manifested in the post-treatment period. Improvement in mass activity was observed during the treatment and post-treatment periods.

Elucidation of the Vulcanization Structures of Filled cis-1,4-Polybutadiene Rubber by Solid State Carbon-13 NMR Spectroscopy (고체상태 NMR을 이용한 cis-1,4-polybutadiene 충진고무의 가황가교 구조 규명)

  • Kim, Su-Dong;Park, Eun-Kyung;Ryu, Ju-Whan
    • Elastomers and Composites
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    • v.43 no.4
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    • pp.281-287
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    • 2008
  • Using solid state $^{13}C$ NMR, polybutadiene rubber vulcanizates were qualitatively and quantitatively analyzed. In the filled conventional system of BR vulcanizate accelerated with TBBS, addition to the olefinic double bond and substitution in the $\alpha$ position to the double bond occurred simultaneously. Also the latter $\alpha$ substitution reaction was faster than the former addition reaction at initial reaction time. In addition, it was suggested that double bond-addition-polysulfide structures might be modified into 5-membered and 6-membered cyclic structures in overcure time. These chain modifications were correlated with the decrease in the chemical crosslink density in overcure time.

A Study on Water Quality and THMs Formation in Lake-Waters at Kunsan (군산시 호소수에서의 수질특성과 THMs 생성에 관한 연구)

  • 황갑수;김강주;이영남;여성구;김진남
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.44-50
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    • 2001
  • This study was carried out to investigate characteristics of water quality and THMs formation in lake-waters at kunsan. Of the parameters examined for water quality, pH, alkalinity, SO$_4$$^{-2}$ and Co- reflected the characteristics according to the origin, geography and water source of lakes while COD, SS, T-P, T-N and chlorophyll-a corelatively reflected well the influence of pollution factors around factors around lakes. The result of water quality analysis showed that most lakes in Kunsan area have the severe eutropnication problem, especially in summer. In lake-waters, THMFP overally continued to increase until 48 hour with the reaction time and THMs formation was largely achieved within 24 hour of the reaction time. The average formation ratio were 68.2% for CHCl$_3$, 23.6% for CHCl$_2$Br, 7.6% for CHClBr$_3$ and 0.6% for CHBr$_3$respectively and much difference depending on the reaction time was not shown. Overally, 96h-THEFP levels in lakes were high during June~September and showed higher tencency in lakes where could be regarded more contaminated on the whole. These results suggest that THMFP may be available for the management of lake-water quality as one if the useful parameters for the general evaluation of contamination. 96h-THEMFP failed to show the strong corelation individually with pH, TOC, COD and chlorphyll-a.

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Effect of Nap between Therapeutic Interventions on Motor Learning in Patients with Stroke (치료적 중재 사이 낮잠이 뇌졸중 환자의 운동학습에 미치는 효과)

  • Lee, Najung;Choi, Yongwon;Choi, Minkyung;Kam, Kyungyoon
    • Journal of The Korean Society of Integrative Medicine
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    • v.2 no.3
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    • pp.9-14
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    • 2014
  • Purpose : The purpose of this research was to determine the effects of nap between therapeutic interventions on motor learning in patients with stroke. Method : Thirty stroke patients with hemiplegia were participated in this study. After the screening by questionnaire about nap time, the patients were assigned to nap or non-nap group. Therapeutic interventions for 30 min were provided two times per day for 5 days per week and the serial reaction time tasks were conducted 2 times before and after a nap per day for 3 days per week. Between the therapeutic interventions, a nap for 60~120 minutes was allowed to the nap group while non-nap group was not. Intervention programs were carried out during the total 15-day. Result : Compared with the non-nap group, the reaction-precision level of nap group was increased (p<.05) for the non-affected upper extremity in the serial reaction time tasks. Conclusion : This study demonstrated that nap between therapeutic interventions has positive effects on motor learning in patients with stroke.

A Study on the Reaction Speed according to Human Physical Condition (인간의 신체특성에 따른 반응속도에 관한 연구)

  • Kwon, Kyu-Sik;Choi, Chul
    • Science of Emotion and Sensibility
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    • v.6 no.2
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    • pp.9-16
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    • 2003
  • This study deals with human reaction speed according to human Physical conditions (head width, breast width, arm extent etc). According to this study, the thickness and extent factor do not affect to human reaction speed, but width factor (head width, breast width). The result of this study can be used to find fitter person for a special job such as emergency condition job, sports man (because you can find a person having a good talent for it before the test). Also, the result of this study can be applied to make CNT (Channel Noise Time) clear The word of CNT is to explain the relation between Channel Noise and Time. (Channel Noise is a kind of noise in the human information transmission channel.).

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