• 제목/요약/키워드: rate equation

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Phenylvinylsulfone의 가수분해 반응메카니즘과 그의 반응속도론적 연구 (Kinetics and Mechanism of the Hydrolysis of Phenylvinylsulfone)

  • 김태린;최준시
    • 대한화학회지
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    • 제19권2호
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    • pp.123-129
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    • 1975
  • Phenylvinylsulfone의 가수분해 속도상수를 자외선분광기를 사용하여 구하였으며 아울러 넓은 범위에서 잘맞는 반응속도식도 얻었다. 이 식에 의하면 넓은 pH범위, 특히 종전에 잘 규명된 바 없는 산성용매 속에서의 반응 및 수산화이온의 촉매역할등도 정량적으로 잘 설명할 수 있음을 알았다. 즉 pH7 이하에서는 물의 첨가로 부터 반응이 시작됨을 알 수 있었으며 pH9 이상에서는 수산화이온만이 반응에 참여함을 알았다.

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동하중을 받는 발포 폴리프로필렌에 대한 EPU 구성 방정식 적용 (Application of the EPU Constitutive Equation to expanded Polypropylene under Dynamic Loading)

  • 정광영;김병준;전성식
    • Composites Research
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    • 제27권4호
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    • pp.135-140
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    • 2014
  • 발포 폴리우레탄의 변형거동을 설명하기 위해 제안된 구성방정식을 발포 폴리프로필렌에 적용하였다. 이 방정식은 7개의 매개변수를 갖고 있으며, 그중 5개의 변수는 기준 변형률속도에서 준정적 압축시험을 하여 얻은 결과를 커브 피팅하여 구하고, 나머지 두 변수는 변형률 속도를 다르게 한 준정적 압축시험으로부터 얻은 결과를 커브 피팅하여 구한다. 이렇게 구한 응력-변형률 방정식이 높은 변형률속도에서도 유효한지 알기 위해 충격시험으로부터 얻은 결과와 비교하였으며 30배와 40배로 발포된 폴리프로필렌 폼 시편에 대하여 각각 시행하였다.

포신 마모 예측의 정확도 향상을 위한 실험적 방법 유도 (Derivation of Empirical Method to Enhance the Accuracy of Cannon Tube Erosion Rate)

  • 정동윤;오명호
    • 한국군사과학기술학회지
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    • 제5권3호
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    • pp.23-32
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    • 2002
  • We predict the erosion rate of unknown cannon tubes by substituting measured values of the standard cannon, 155㎜ Howitzer M185 and ballistic data for the erosion equation. We know ten measured erosion values of the standard cannon at every 400 rounds. An approximate formula is derived to interpolate six values up to 2,000 rounds. Numerical example is presented and its results are analyzed. The new erosion equation is also suggested. This equation produces more accurate cannon tube erosion rate than the Rauf Imam's empirical approaches. Computer simulations are presented.

활성오니공법에 있어서 수온이 처리효율에 미치는 영향에 관한 분석 -청계천 하수종말처리장에 대하여- (Analysis of Temperature Effect on Activated Sludge Process at Cheong-Gye Cheon Sewage Treatment Plant)

  • 이은경
    • 한국환경보건학회지
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    • 제7권1호
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    • pp.9-20
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    • 1981
  • This study was performed to determine the correlationship between temperature and overall removals of BOD, SS and to demonstrate the effect of temperature on treatment performance. These data for a period from February 1, 1977 to January 31, 1980 were obtained from the Cheong-Gye Cheon Sewage Treatment plant. The results of correlation and stepwise multiple regression analysis were as follows. 1) Secondary effluent BOD and SS showed negative correlationship with water temperature, with correlation coefficient of -0.1710, and -0.1654 respectively. 2) Correlation coefficient of BOD, SS removal rate and water temperature were 0.1823 and 0.0429 respectively. 3) Regresion equation for estimate of BOD removal rate was as follows $\widehat{Y}_1$ (BOD removal rate)=63.9994+0.5442X(water temperature). And BOD removal rate showed non significant change according to the water temperature. 4) Regression equation for estimate of SS removal rate was as follows $\widehat{Y}_2$ (SS removal rate)=61.6881+0.1514X(Water temperature). And SS removal rate showed non significant change according to the water temperature. 5) According to the Stepwise Multiple Regression analysis, water temperature ranked second order in the BOD removal rate estimation and the equation was as follows $\widehat{Y}_1$ (BOD removal rate)=69.7398+0.2665 $X_1$ (Primary effluent BOD)+0.3562 $X_2$ (Water temperature)-0.0122 $X_3(Flow)+4413.271X_4$ (Organic Loading).

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New Empirical Approach to Enhance The Accuracy of Cannon Tube Erosion Rate

  • Chung, Dong-Yoon;Oh, Myoung-Ho
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.231-232
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    • 2002
  • Various methods that utilize erosion rate measurement of standard cannon, 155mm Howitzer M185, as reference, are being used to calculate erosion rate of an interested unknown cannon tubes. We know ten measured erosion values of the standard cannon from 391 rounds to 4.000. An approximate function fitting these value s is derived. The new erosion equation is also suggested and computer simulations arc presented.

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EXPONENTIAL DECAY FOR THE SOLUTION OF THE VISCOELASTIC KIRCHHOFF TYPE EQUATION WITH MEMORY CONDITION AT THE BOUNDARY

  • Kim, Daewook
    • East Asian mathematical journal
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    • 제34권1호
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    • pp.69-84
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    • 2018
  • In this paper, we study the viscoelastic Kirchhoff type equation with a nonlinear source for each independent kernels h and g with respect to Volterra terms. Under the smallness condition with respect to Kirchhoff coefficient and the relaxation function and other assumptions, we prove the uniform decay rate of the Kirchhoff type energy.

STABILIZATION FOR THE VISCOELASTIC KIRCHHOFF TYPE EQUATION WITH A NONLINEAR SOURCE

  • Kim, Daewook
    • East Asian mathematical journal
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    • 제32권1호
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    • pp.117-128
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    • 2016
  • In this paper, we study the viscoelastic Kirchhoff type equation with a nonlinear source $$u^{{\prime}{\prime}}-M(x,t,{\parallel}{\bigtriangledown}u(t){\parallel}^2){\bigtriangleup}u+{\int}_0^th(t-{\tau})div[a(x){\bigtriangledown}u({\tau})]d{\tau}+{\mid}u{\mid}^{\gamma}u=0$$. Under the smallness condition with respect to Kirchhoff coefficient and the relaxation function and other assumptions, we prove the uniform decay rate of the Kirchhoff type energy.

Application of Reaction Path Smoluchowski Equation Formalism to the Photoisomerization of Trans-Stilbene

  • Kim, Dong-Sup;Lee, Sang-Youb
    • Bulletin of the Korean Chemical Society
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    • 제12권6호
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    • pp.692-698
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    • 1991
  • The reaction path Smoluchowski equation approach developed in a recent work to calculate the rate constant for a diffusive multidimensional barrier crossing process is extended to incorporate the configuration-dependent diffusion matrix. The resulting formalism is then applied to the investigation of stilbene photoisomerization dynamics. Adapting a model two-dimensional potential and a model diffusion matrix proposed by Agmon and Kosloff [J. Phys. Chem.,91 (1987) 1988], we derive an eigenvalue equlation for the relaxation rate constant of the stilbene photoisomerization. This eigenvalue equation is solved numerically by using the finite element method. The advantages and limitations of the present method are discussed.

NEWTON'S METHOD FOR SOLVING A QUADRATIC MATRIX EQUATION WITH SPECIAL COEFFICIENT MATRICES

  • Seo, Sang-Hyup;Seo, Jong-Hyun;Kim, Hyun-Min
    • 호남수학학술지
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    • 제35권3호
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    • pp.417-433
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    • 2013
  • We consider the iterative solution of a quadratic matrix equation with special coefficient matrices which arises in the quasibirth and death problem. In this paper, we show that the elementwise minimal positive solvent of the quadratic matrix equations can be obtained using Newton's method if there exists a positive solvent and the convergence rate of the Newton iteration is quadratic if the Fr$\acute{e}$chet derivative at the elementwise minimal positive solvent is nonsingular. Although the Fr$\acute{e}$chet derivative is singular, the convergence rate is at least linear. Numerical experiments of the convergence rate are given.

균열을 내재한 회전체의 에너지방출률 (The Energy Release Rate for Cracks in a Rotating Continuum)

  • 이태원
    • 대한기계학회논문집
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    • 제19권2호
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    • pp.330-337
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    • 1995
  • For a rotating body with cracks, the new energy release rate equation is presented. The derived equation is different from the other researcher's results. It is a path-independent integral which excluded the derivatives of displacements near the crack tip, thereby improving the numerical accuracy of the energy release rate computation. Moreover, as the equation was derived on basis of the energy principle and non-linear elasticity without assumptions, it can applied to the cracked body with arbitrary shape under elastic-plastic deformation. Several examples are treated to demonstrate the efficiency and accuracy of the proposed method compared to existing methods.