• Title/Summary/Keyword: rate constant(k)

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Electrochemical Generation of Chlorine Dioxide Using Polymer Ion Exchange Resin (고분자 이온교환수지를 이용한 의료.식품용 멸균제 이산화염소의 전기화학분해 발생)

  • Rho, Seung Baik;Kim, Sang Seob
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.86-92
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    • 2012
  • A characteristic study of chlorine dioxide generation by the electrolysis system was performed after chlorite ($ClO_2^-$) is adsorbed from sodium chlorite by a polymer ion exchange resin. A strongly basic anion exchange resin was used and a Ti plate coated with Ru and Ir was used as an electrode. Various parameters such as reaction stirring velocity, reaction temperature, chlorine dioxide product concentration, ion exchange resin content and product maker type for the adsorption quantity in the chlorite adsorption of ion exchange resin were investigated and found the ion exchange resin with the maximum adsorption quantity. A generation trend of chlorine dioxide was observed by the electrolysis system and optimum conditions on the desired value were found using response surface design of DOE (Design of Experiments). The strongly basic anion exchange resin with the maximum adsorption quantity was SAR-20 (TRILITE Gel type II) and the adsorption quantity was around 110 mg/IER (g). Observed generation optimum conditions of chlorine dioxide were constant-current (electrode area base; $A/dm^2$) and flow rate of $N_2$ gas (4.7 L/min) at the desired value of sterilization (900~1000 ppm, 1 h).

The Efficiency on the Oral Health Training of Elderly Adults at Welfare Institutions (노인복지센터 이용노인의 구강보건교육 효율성)

  • Park, Myung-Suk;Choi, Mi-Suk
    • Journal of dental hygiene science
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    • v.8 no.4
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    • pp.347-352
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    • 2008
  • The purpose of this survey was to evaluate the efficiency on the oral health training of elderly adults who have experienced the oral health training program at welfare institutions in An-yang city, Korea. A total of 451 adults (aged 65 or more) were selected and surveyed by the self-reporting questionnaire that consist of 4 items and socio-economic general characteristics (gender, age). Oral health indices were produced by using the SPSS. The percentage of perceived oral health status that felt poor or very poor was decreased about 8.5% than before and the frequency of perceived oral symptom was decreased too and the practice rate and satisfaction with oral health training was significantly increase than before. Oral health promotion of the elderly adults at welfare institutions in An-yang city should focused on the constant attention the means of the preventive oral health training program.

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Antioxidant Property of Aqua-Acupuncture Solution from Circium japonicum (대계 약침액의 항산화 효능)

  • Lee, Jeong-Joo;Moon, Jin-Young
    • Korean Journal of Acupuncture
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    • v.22 no.4
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    • pp.57-65
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    • 2005
  • Objectives : Circium japonicum is a pharmacologically active used in traditional Korean medicine. An aqua-acupuncture solution of the Circium japonicum was assessed to determine the mechanism of its antioxidant activity. Materials : Circium japonicum was obtained from a Dongguk Korean Medicine Hospital (Kyung-ju, Kyungbuk). The freeze-dry powder was collected (yield 5.1%) for the aqua-acupuncture solution. Scavenging activity on DPPH free radicals by the Circium japonicum aqua-acupuncture solution (CJAS) was assessed according to the method followed by Gyamfi et al.. and then scavenging activity orl superoxide radicals $(O_2^-{\cdot})$ was assessed by the method described by Gotoh et al. with slight modification. Deoxyribose assay to determine the rate constant for the reactions between either antioxidants and hydroxyl radicals or antioxidants and iron ions. We tested by; (1) Non-site-specific scavenging assay (hydroxyl radicals, OH), (2) Site-specific scavenging assay (chelate iron ions), and (3) Pro-oxidant effect of the CJAS on iron dependent hydroxyl radical generation. Finally, we determined hydroxyl radical-mediated DNA nicking formation. Conclusion : Our study demonstrated that CJAS has antioxidant activities and we investigated the potential effectiveness of CJAS in preventing oxidative stress-mediated disease further.

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Physicochemical Properties of Rice Affected by Steeping Conditions (수침이 멥쌀의 이화학적 성질에 미치는 영향)

  • Kim, Sung-Kon;Bang, Jung-Bum
    • Korean Journal of Food Science and Technology
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    • v.28 no.6
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    • pp.1026-1032
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    • 1996
  • The effects of steeping temperature $(7^{\circ},\;15^{\circ},\;20^{\circ}\;and\;30^{\circ}C)$ and steeping time $(2{\sim}14\;hr)$ on the physicochemical properties of milled rice (variety; Chucheongbyeo) were investigated. The pH of the steep water decreased as the steeping time increased, which was more pronounced at higher steeping temperature. The solid loss was about 4.0% during steeping. The contents of protein, fat and ash decreased during steeping, which was greater at elevated temperature. The lightness of rice was slightly increased, and the yellowness was decreased upon steeping. The water-binding capacity of rice was increased during steeping at above $15^{\circ}C$. The slight increase of the swelling power of rice at $80^{\circ}C$ was observed upon steeping. The maximum wavelengh for the rice flour-iodine complex was moved to a higher wavelengh, but X-ray diffraction patterns remained constant regardless the steeping conditions. The pasting properties of rice flour (10%) by amylograph indicated that the peak viscosity increased as the steeping time was increased at all steeping temperatures. The steeping resulted in the greater breakdown and the 1ower setback. The log peak viscosity showed a linear relationship with the steeping time. The activation energy and $Q_{10}$ value for the visciosity increase rate was 2, 320 cal/mole and 1.14, respectively.

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AERODYNAMIC EFFECT OF ROOF-FAIRING SYSTEM ON A HEAVY-DUTY TRUCK

  • KIM C. H.;YOUN C. B.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.221-227
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    • 2005
  • Aim of this study is to investigate an aerodynamic effect of a drag-reducing device on a heavy-duty truck. The vehicle experiences two different kinds of aerodynamic forces such as drag and uplifting force (or downward force) as it is traveling straight forward at constant speed. The drag force on a vehicle may cause an increase of the rate of fuel consumption and driving instability. The rolling resistance of the vehicle may be increased as result of the negative uplifting or downward force on the vehicle. A device named roof-fairing system has been applied to examine the reduction of aerodynamic drag force on a heavy-duty truck. As for a engineering design information, the drag-reducing system should be studied theoretically and experimentally for the best efficiency of the device. Four different types of roof-fairing model were considered in this study to investigate the aerodynamic effect on a model truck. The drag and downward force generated by vehicle has been obtained from numerical calculation conducted in this study. The forces produced on four fairing models considered in this study has been compared each other to evaluate the best fairing model in terms of aerodynamic performance. The result shows that the roof-fairing mounted truck has bigger negative uplifting or downward force than that of non-mounted truck in all speed ranges, and drag force on roof-fairing mounted truck has smaller than that of non-mounted truck. The drag coefficient $(C_D)$ of the roof-fairing mounted truck (Model-3) is reduced up to $41.3\%$ than that of non-mounted trucks (Model-1). A downward force generated by a roof-fairing mounted on a truck is linearly proportional to the rolling resistance force. Therefore, the negative lifting force on a heavy-duty truck is another important factor in aerodynamic design parameter and should be considered in the design of a drag-reducing device of a tractor-trailer. According to the numerical result obtained from present study, the drag force produced by the model-3 has the smallest of all in all speed ranges and has reasonable downward force. The smaller drag force on model-3 with 2/3h in height may results of smallest thickness of boundary layer generated on the topside of the container and the lowest intensity of turbulent kinetic energy occurs at the rear side of the container.

The Self-healing and Ageing Effect of OPC-GGBFS Cement in Sea-water and Tap-water (해수와 담수에서 OPC-GGBFS 시멘트의 자기치유와 재령효과)

  • Kim, Tae-Wan;Kang, Choonghyun
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.11-21
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    • 2017
  • The paper presents experimental results of self-healing effects of OPC-GGBFS paste with cracked and uncracked specimens. The self-healing of cracked specimens is processes of crack closing with re-hydration of unhydrated in crack surface. The OPC paste with GGBFS replacement ratios of 0%, 10%, 20% and 30% were prepared having a constant water-binder ratios of 0.5. The OPC-GGBFS paste specimens immersed in tap-water and sea-water. The temperature of tap and sea-water was $5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$. The cracked specimens after deterioration were immersed for 60 days. The relationship between self-healing effect and age-effect was calculate based upon the experimental results. The self-healing effect was measured in ultrasonic pulse velocity (UPV) before and after loading. When the relative change rate of UPV is increases with the increase in GGBFS replacement ratios. Moreover, the self-healing effect is increased with the temperature of tap-water is increase. But the cracked specimens immersed in sea-water was unclear effects of different temperature. Furemore, most of the healing for OPC-GGBFS specimens immersed in tap-water and sea-water occurred during the first 30 days. The self-healing effect until 30 days is higher than that the age-effect. After 30 days, self-effect and age-effect was largely decreases. SEM/EDS analysis of crack on the surface of the specimens in tap-water were covered with aragonite, and sea-water were covered with brucite.

Synthesis of Diketo Copper(II) Complex and Its Binding toward Calf Thymus DNA (CTDNA) (이케토 구리(II) 착물의 합성 및 송아지 Thymus DNA(CTDNA)와의 상호작용)

  • Tak, Aijaz Ahmad;Arjmand, Farukh
    • Journal of the Korean Chemical Society
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    • v.55 no.2
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    • pp.177-182
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    • 2011
  • A diketo-type ligand was synthesized by the Knoevenagel condensation reaction of thiophene-2-aldehyde with acetylacetone, subsequently its transition metal complexes with Cu(II), Ni(II), and Co(II) chlorides were also prepared. All the complexes were characterized by various physico-chemical methods. The molar conductivity data reveals ionic nature for the complexes. The electronic spectrum and the EPR values suggest square planar geometry for the Cu(II) ion. Interaction of the Cu(II) complex with CTDNA (calf thymus DNA) was studied by absorption spectral method and cyclic voltammetry. The $k_{obs}$ values versus [DNA] gave a linear plot suggesting psuedo-first order reaction kinetics. The cyclic voltammogram of the Cu(II) complex reveals a quasi-reversible wave attributed to Cu(II)/Cu(I) redox couple for one electron transfer with $E_{1/2}$ values -0.240 V and -0.194 V. respectively. On addition of CTDNA, there is a shift in the $E_{1/2}$ values 168 mV and 18 mV respectively and decrease in Ep values. The shift in $E_{1/2}$ values in the presence of CTDNA suggests strong binding of Cu(II) complex to the CTDNA.

Performance Characteristics of the 300 MW Integrated Gasification Combined Cycle Plant according to Ambient Temperature (대기온도에 따른 300 MW 석탄가스화복합발전 성능특성)

  • Kim, Young-Mook;Yoo, Ho-Seon
    • Plant Journal
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    • v.14 no.3
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    • pp.29-34
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    • 2018
  • In this study, the output and thermal efficiency of Taean Integrated Gasification Combined Cycle Plant were calculated by using the manufacturer's basic design data and the performance correction factor for each atmospheric temperature, and the actual performance was measured at summer and winter representative points. The results were compared with the calculated values to verify their validity. The thermal efficiency is the highest at around $15^{\circ}C$ and lower at lower temperature and higher temperature. This is similar to that of natural gas Combined Cycle Power Plant, but the thermal efficiency has drastically decreased due to the increase of power consumption of the air separation unit at relatively high temperature. The output is highest in the range of 5 to $15^{\circ}C$, and is kept almost constant at below $5^{\circ}C$ and declines above $15^{\circ}C$. The reason why the output does not increase at low temperatures is that the torque limit of the shaft is activated by the increase of the flow rate due to the nitrogen injection of the gas turbine combustor. In order to improve the performance in the future, efforts should be made to improve the power generation output and to reduce the power consumption of the air separation unit in summer.

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Qualities of spawned eggs during the spawning period in red spotted grouper, Epinephelus akaare (산란기간중의 붉바리 난질 변화)

  • Lee, Chang-Kyu;Hur, Sung-Bum;Park, Seung;Kim, Byung-Gyoon
    • Journal of Aquaculture
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    • v.10 no.4
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    • pp.463-472
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    • 1997
  • Floating and hatching rates, size and survival activity index(SAI) of spawned eggs of red spotted grouper, Epinephelus akaara were studied to understand egg qualities during the spawning periods in 1992, 1993 and 1995. The fish spawned from mid-July to mid-August when temperature ranged 23~$28^\circC$. Floating, fertilization and hatching rates were higher in the eggs from early to middle than those from late during the spawning period. SAI ranged 1.8~9.6, and it was closely related to survival rate until mouth operning time (SMOT). Egg diameter decreased gradually with the time of spawning, while diameter of oil globule was constant during the spawning periods. Induced spawnings were carried out with one injection of HCG over 5, 000 IU/kg body weight. Floating, fertilization and hatching rates of the induced spawning eggs were higher than those of untreated ones. Thus, induced spawning method with HCG was recommended for collecting fertilized eggs in bulk. Optimal time for the collection of high quality eggs was supposed to be from early to middle during the spawning periods. Considering that egg qualities were vulnerable within the period, hatchability, incidence of malformed larvae, SMOT and SAI were factors to be considered together to get good quality of eggs.

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Adaptive Modulation System Using SNR Estimation Method Based on Correlation of Decision Feedback Signal (Decision Feedback 신호의 자기 상관 기반 SNR 추정 방법을 적용한 적응 변조 시스템)

  • Kim, Seon-Ae;Ryu, Heung-Gyoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.3
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    • pp.282-291
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    • 2011
  • Adaptive modulation(AM) is an important technique to increase the system efficiency, in which transmitter selects the most suitable modulation mode adaptively according to channel state in the temporary and spatially varying communication environment. Fixed modulation on channels with varying signal-to-noise ratio(SNR) is that the bit-errorrate(BER) probability performance is changing with the channel quality. An adaptive modulation scheme can be designed to have a BER which is constant for all channel SNRs. The correct as well as fast and simple SNR estimation is required essentially for this adaptive modulation. In order to operate adaptive modulation system effectively, in this paper, we analyze the effect of SNR estimation performance to it through the average BER and data throughput. Applying SNR estimation based on auto-correlation of decision feedback signal and others to adaptive modulation system, we also confirm performance degradation or improvement of its which is decided by SNR estimation error at each transition point of modulation level. Since SNR estimation based on auto-correlation of decision feedback signal shows stable estimation performance for various quadrature amplitude modulation(QAM) comparatively, this can be reduced degradation than others at each transition point of modulation level.