Journal of the Korea Concrete Institute (콘크리트학회논문집)

Korea Concrete Institute (한국콘크리트학회)
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The Self-healing and Ageing Effect of OPC-GGBFS Cement in Sea-water and Tap-water

해수와 담수에서 OPC-GGBFS 시멘트의 자기치유와 재령효과

  • Kim, Tae-Wan (Research Institute of Industrial Technology (RIIT), Pusan National University) ;
  • Kang, Choonghyun (Dept. of Marine and Civil Engineering, College of Engineering, Chonnam National University)
  • 김태완 (부산대학교 생산기술연구소) ;
  • 강충현 (전남대학교 해양토목공학과)
  • Received : 2016.07.04
  • Accepted : 2016.12.08
  • Published : 2017.02.28
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Abstract

The paper presents experimental results of self-healing effects of OPC-GGBFS paste with cracked and uncracked specimens. The self-healing of cracked specimens is processes of crack closing with re-hydration of unhydrated in crack surface. The OPC paste with GGBFS replacement ratios of 0%, 10%, 20% and 30% were prepared having a constant water-binder ratios of 0.5. The OPC-GGBFS paste specimens immersed in tap-water and sea-water. The temperature of tap and sea-water was $5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$. The cracked specimens after deterioration were immersed for 60 days. The relationship between self-healing effect and age-effect was calculate based upon the experimental results. The self-healing effect was measured in ultrasonic pulse velocity (UPV) before and after loading. When the relative change rate of UPV is increases with the increase in GGBFS replacement ratios. Moreover, the self-healing effect is increased with the temperature of tap-water is increase. But the cracked specimens immersed in sea-water was unclear effects of different temperature. Furemore, most of the healing for OPC-GGBFS specimens immersed in tap-water and sea-water occurred during the first 30 days. The self-healing effect until 30 days is higher than that the age-effect. After 30 days, self-effect and age-effect was largely decreases. SEM/EDS analysis of crack on the surface of the specimens in tap-water were covered with aragonite, and sea-water were covered with brucite.

본 연구는 OPC-GGBFS 페이스트 시험체에 균열을 발생시키지 않은 시험체와 균열을 발생시킨 시험체의 자기치유 효과에 대한 실험결과이다. 균열이 발생된 시험체의 자기치유는 균열면의 미수화 입자들의 재수화로 인한 균열면 닫힘 현상이다. OPC 페이스트에 GGBFS를 0%, 10%, 20% 그리고 30% 치환하고 물-결합재 비는 0.5로 일정하게 하였다. OPC-GGBFS 시험체를 담수(tap-water)와 해수(sea-water)에 침지하였다. 담수와 해수의 온도는 $5^{\circ}C$, $15^{\circ}C$ 그리고 $25^{\circ}C$이다. 균열을 발생시킨 시험체는 균열발생 후 60까지 침지하였다. 실험결과를 바탕으로 자기치유 효과(self-effect)와 재령효과(age-effect) 사이의 관계를 계산하였다. 자기치유 효과는 균열발생 전후의 초음파속도(UPV) 측정을 통해 이루어졌다. GGBFS 치환율이 증가하면 UPV 증가율이 증가하였다. 더구나, 침지한 담수의 온도가 증가할수록 자기치유 효과도 향상되었다. 그러나 해수에 침지한 시험체는 온도와의 관계가 명확하지 않았다. 담수와 해수에 침지한 OPC-GGBFS 시험체의 가장 높은 자기치유 효과는 침지 30일 동안 발생하였다. 침지 30일까지는 자기치유효과가 높았다. 30일 이후에는 자기치유 효과와 재령 효과가 모두 크게 감소하였다. SEM/EDS 분석을 통해 담수에 침지한 시험체의 균열에는 aragonite가, 해수에 침지한 시험체의 균열부에는 brucite가 생성된 것을 확인하였다.

Keywords

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