• Title/Summary/Keyword: rate constant(k)

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Low dielectric material etching technology for Cu interconnection (Plasma를 이용한 구리배선용 저유전 물질의 etching에 대한 연구)

  • Lee, Kil-Hun;Jung, Do-Hyun;Choi, Jong-Sun
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.519-521
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    • 2000
  • The application of low dieletric constant material instead of $SiO_2$ has been considered to reduce interconnection delay, crosstalk, power exhaustion. Methylsilsesquioxane (MSSQ) have a dieletric constant less than k>3 which is lower than that for the convention $SiO_2$ insulator ($k{\sim}4$). The Propose of this study is to know etching rate of MSSQ. Expermentation in this paper use RIE(Reactive ion Etching) and centre) flow rate of $CF_4/O_2$ gas, RF power.

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FERRATE(VI) FOR WASTE WATER TREATMENT : OXIDATION OF CYANIDE IN AQUEOUS MEDIUM

  • Tiwari, Diwakar;Kim, Hyoung-Uk;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • v.11 no.6
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    • pp.318-324
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    • 2006
  • The higher valence state of iron i.e., Fe(VI) was employed for the oxidation of one of an important toxic ion, cyanide in the aqueous medium. Cyanide was oxidized into cyanate, which is 1,000 times less toxic to cyanide and often accepted for its ultimate disposal. It was to be noted that Fe(VI) is a very powerful oxidizing agent and can oxidize most of the cyanide within few minutes i.e., ca 5 mins of contact. The data was obtained by the UV-Visible measurements for the Fe(VI) decomposition. The UV-Visible data was used to evaluate the overall rate constant for second order redox reaction between ferrate(VI) and cyanide. Also the pseudo first order rate constant was calculated as keeping the cyanide concentration in excess.

Kinetics Study of the Reaction of Bromine with Phenylhydrazine in Sulfuric Acid Media (페닐히드라진과 브롬의 반응메카니즘에 관한 연구)

  • Park Byoung Bin;Park Il H.;Kong Young Kun;Choi Q. Won
    • Journal of the Korean Chemical Society
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    • v.21 no.4
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    • pp.227-234
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    • 1977
  • The reaction of phenylhydrazine with bromine in sulfuric acid solution has been studied kinetically. The pseudo-second-order rate constant is approximately inversely proportional to hydrogen-ion concentration when the concentration of sulfuric acid is lower than 1M. arom the study of the effect of potassium bromide concentration on the rate constant, it is concluded that both neutral bromine and tribromide ion participate in the reaction, the rate constants in 0.01M $H_2SO_4$ being $5{\times}10^5M^{-1},sec^{-1}\;and\;0. 7{\times}10^5M^{-1},sec^{-1}$, respectively at $20^{\circ}C$. The pseudo-second-order rate constant of 2.4-dinitrophenylhydrazine-bromine reaction is independent of hydrogen ion concentration. From the KBr addition experiment, the rate constants for $Br_2\;and\;Br_3^-$ were obtained as $1.2{\times}10^5M^{-1},sec^{-1}\;and\;2.0{\times}10^4M^{-1},sec^{-1}$, respectively.

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A Case Study on Learning of Fundamental Idea of Calculus in Constant Acceleration Movement (등가속도 운동에서 미적분의 기본 아이디어 학습 과정에 관한 사례연구)

  • Shin Eun-Ju
    • Journal of Educational Research in Mathematics
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    • v.16 no.1
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    • pp.59-78
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    • 2006
  • As a theoretical background for this research, the literatures which focus on the rationale of teaching and learning of connecting with mathematics and science in calculus were investigated. And teaching and learning material of connecting with mathematics and science in calculus was developed. And then, based on the case study using this material, the research questions were analyzed in depth. Students could understand mean-velocity, instant-velocity, and acceleration in the experimenting process of constant acceleration movement. Also Students could understand fundamental ideas that instant-velocity means slope of the tangent line at one point on the time-displacement graph and rate of distance change means rate of area change under a time-velocity graph.

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Pumpless Cell Culture Chip with a Constant Perfusion Rate Maintained by Balanced Droplet Dispensing (액적의 균형공급에 의해 관류유량이 일정한 펌프 없는 세포배양 칩)

  • Kim, Tae-Yoon;Cho, Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1127-1131
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    • 2011
  • We report on a pumpless cell culture chip in which a constant medium perfusion rate is maintained by balanced droplet dispensing. Previous chips had a decreasing perfusion rate due to the decreasing hydraulic-head difference ${\Delta}h$ between the inlet and drain. However, the present chip maintains a constant medium perfusion rate due to the constant ${\Delta}h$ between the inlet and drain maintained by balanced droplet dispensing. The perfusion rate Q was measured to be 0.1-$0.3{\mu}l$/min with a maximum deviation and error of 9.96% and 6.92%, respectively. In the perfusion culture (Q = 0.1-$0.3{\mu}l$/min), the maximum growth-rate of H358 cells was measured to be $57.8%{\pm}21.1%$ per day, which is 1.9 times higher than that of a static culture. The perfusion culture also resulted in higher cell viability than a static culture. The present chip offers a favorable environment with a high growth-rate and viability and thus has potential for use in the integrated cell culture system.

The Kinetics Study of Ozone with Sulfur Dioxide in the Gas Phase (기체 상태에서의 오존과 아황산가스의 반응연구)

  • Young Sik Kwon
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.111-118
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    • 1991
  • The kinetic of the gas phase reactions of ozone(0.5 torr) with sulfur dioxide was studied. The SO2 reaction was conducted in the 7∼22 torr range at 90∼155$^{\circ}$C. The reaction rate was faster than the reaction rate of O$_3$ in the presence of CO$_2$ alone. The reaction of O$_3$ with SO$_2$ follows the rate law: -d(O$_3)/dt=k_0(SO_2)(M)(O_3)+2k _1(SO_2)(O_3$). The first term of this rate law arises from a third order molecular reaction predominating in the lower temperature range and gave a rate constant k$_0$ = (9.35 $\pm$ 8.6) ${\times}$ 10$^9$e$^{-(11.05{\pm}2.04)kcal/RT}(M^{-2}s^{-1}$). The second term of the above rate law derived from a second order thermal decomposition reaction which was the major part of the reaction and gave a rate constant k$_0 =(9.35{\pm}8.6){\times}10^9e^{-(11.05{\pm}2.04)kcal/RT}(M^{-2}s^{-1}$). The overall reaction proceeds with kinetics of complex order composed mainly of second order and third order components.

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Optimization of Mold Coating Condition with Acetylene Soot in Continuous Casting of Copper Rod (구리봉의 연속주조금형에 사용된 아세틸렌 화염 도형의 최적화)

  • Kim, Jae-Uk;Kim, Young-Tae;Oh, Kyu-Hwan;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.16 no.2
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    • pp.158-164
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    • 1996
  • In copper continuous casting, the soot, which is the incomplete pyrolitic product of acetylene, has been used as a mold coat. In this work, under constant acetylene pressure, the characteristics of soot and the optimum condition of sooting were investigated with different acetylene and oxygen flow rate. The soot particles deposited on the mold surface had mainly spherical shape and their sizes were about 20nm. After reaction with melt, their shapes were changed into polygonal type due to the graphitization. With increasing oxygen flow rate up to $0.6{\ell}/min$, the amount of residues of soot after heat treatment were kept nearly constant. But the amount of residues increased rapidly with further increasing oxygen flow rate. Degree of graphitization was maximum at $0.4{\ell}/min$ and $5{\ell}/min$ of oxygen and acetylene flow rate, respectively.

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Failure rate of a bivariate exponential distribution

  • Hong, Yeon-Woong
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.1
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    • pp.173-177
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    • 2010
  • It is well known that if the parent distribution has a nonnegative support and has increasing failure rate, then all the order statistics have increasing failure rate (IFR). The result is not necessarily true in the case of bivariate distributions with dependent structures. In this paper we consider a symmetric bivariate exponential distribution and show that, two marginal distributions are IFR and the distributions of the minimum and maximum are constant failure rate and IFR, respectively.

Distortion Variation Minimization in low-bit-rate Video Communication

  • Park, Sang-Hyun
    • Journal of information and communication convergence engineering
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    • v.5 no.1
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    • pp.54-58
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    • 2007
  • A real-time frame-layer rate control algorithm with a token bucket traffic shaper is proposed for distortion variation minimization. The proposed rate control method uses a non-iterative optimization method for low computational complexity, and performs bit allocation at the frame level to minimize the average distortion over an entire sequence as well as variations in distortion between frames. The proposed algorithm does not produce time delay from encoding, and is suitable for real-time low-complexity video encoder. Experimental results indicate that the proposed control method provides better visual and PSNR performances than the existing rate control method.

Estimation of Heat and Rate Constant of Reaction by a Hight-Speed Isothermal Calorimeter

  • Jung, Heung-Joe;Ryu, Dong-Wan;Park, Chan-Young
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10b
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    • pp.1873-1878
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    • 1991
  • An high-speed isothermal calorimeter which can trace the progress of a liquid phase reversible reaction was constructed using analog and digital computer. By means of a set point change of the calorimeter, the thermal energy capacity and the heat of reaction in reversible reaction mixture can be measured. The heat of reaction between 2-methyl furan and maleic anhydride and the heat capacities of the adduct were 61,200 J/mol and 2.38 J/ g K, respectively. Also reaction equilibrium constant and reaction rate constants can be estimated from the response curves of the calorimeter.

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