• Title/Summary/Keyword: pure state

Search Result 549, Processing Time 0.03 seconds

Synthesis of an oxynitride-based green phosphor $Ba_3Si_6O_{12}N_2:Eu^{2+}$ via an aqueous-solution process, using propylene-glycol-modified silane

  • Yasushita, Chihiro;Kato, Hideki;Kakihana, Masato
    • Journal of Information Display
    • /
    • v.13 no.3
    • /
    • pp.107-111
    • /
    • 2012
  • An almost pure phase of $Ba_3Si_6O_{12}N_2$ doped with $Eu^{2+}$ was successfully synthesized through the ammonia nitridation of an oxide precursor prepared through an aqueous-solution method, using propylene- glycol-modified silane. The emission peak intensity of the obtained $Ba_3Si_6O_{12}N_2:Eu^{2+}$ was -2.2 times higher than that of the sample prepared through a solid-state reaction method.

Microstructures of Bonding Interfaces after Semi-Solid Brazing of Aluminum Using A357 as a Filler Metal (A357을 이용한 알루미늄 반응고 브레이징 접합 계면 특성)

  • Lee, S.Y.
    • Transactions of Materials Processing
    • /
    • v.21 no.8
    • /
    • pp.506-511
    • /
    • 2012
  • Aluminum brazing normally requires a careful control of temperature due to the small interval between brazing and melting temperatures for base materials. Unsuitable processing conditions, including brazing temperature outside admissible range, gap between brazed materials or inadequate flux feeding, can lead to joining defects. In this study, A357 was used as a filler metal for the brazing of pure aluminum base materials and brazed at temperatures in the semi-solid state. Interface microstructures with base materials were observed using optical metallography(OM) and scanning electron microcopy(SEM) with energy dispersive spectroscopy(EDS), and compared to conventional aluminum brazing.

CHARACTERIZATIONS OF BOOLEAN RANK PRESERVERS OVER BOOLEAN MATRICES

  • Beasley, Leroy B.;Kang, Kyung-Tae;Song, Seok-Zun
    • The Pure and Applied Mathematics
    • /
    • v.21 no.2
    • /
    • pp.121-128
    • /
    • 2014
  • The Boolean rank of a nonzero m $m{\times}n$ Boolean matrix A is the least integer k such that there are an $m{\times}k$ Boolean matrix B and a $k{\times}n$ Boolean matrix C with A = BC. In 1984, Beasley and Pullman showed that a linear operator preserves the Boolean rank of any Boolean matrix if and only if it preserves Boolean ranks 1 and 2. In this paper, we extend this characterization of linear operators that preserve the Boolean ranks of Boolean matrices. We show that a linear operator preserves all Boolean ranks if and only if it preserves two consecutive Boolean ranks if and only if it strongly preserves a Boolean rank k with $1{\leq}k{\leq}min\{m,n\}$.

A Lattice Model Based Molecular Clusters for Supercritical Fluids (초임계 유체를 위한 분자 클러스터 기반의 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
    • /
    • 2011.05a
    • /
    • pp.306-309
    • /
    • 2011
  • A lattice model based molecular clusters is presented to improve a classical equation of state(EOS) for volumetric properties in the critical region. The term is based on the two assumptions: (1) The Helmholtz energy is individually divided into classical and long-range density fluctuation contribution (2) All molecules form cluster near the critical region due to long-range density fluctuation. To formulate such molecular cluster, we extended the Veytsman statistics originally developed for the cluster due to hydrogen bonding. The probability function in the statistics is modified to represent the characteristics of long-range density fluctuation vanishing far from critical region. The proposed fluctuation contribution was incorporated into the Sanchez-Lacombe EOS and the combined model with 6 adjustable parameters has been tested against experimental VLE data for pure compounds. The combined model is found to well represent flatten critical isotherm for methane and top of the coexistence curve for the tested components.

  • PDF

Theoretical and Practical Aspects of Pb-Sn Alloy Plating (Pb-Sn 합금도금의 이론 및 실제적 경향)

  • Paik, Young-Nam
    • Journal of the Korean institute of surface engineering
    • /
    • v.12 no.3
    • /
    • pp.161-166
    • /
    • 1979
  • Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

  • PDF

Transport properties of carbide superconductor La2C3

  • Kim, J.S.;Kremer, R.K.
    • Progress in Superconductivity and Cryogenics
    • /
    • v.15 no.1
    • /
    • pp.6-10
    • /
    • 2013
  • We investigate the electrical and thermal transport properties of a sesquicarbide superconductor $La_2C_3$, including electrical resistivity, thermoelectric power, and thermal conductivity. The electrical resistivity exhibits a typical metallic character with a saturation behavior at high temperatures. The thermoelectric power shows a metallic behavior with pronounced phonon-drag effect, comparable with pure metals. The broad peak of the thermal conductivity is observed in the superconducting state, which is rapidly suppressed by magnetic fields. These observations suggest that the electron-phonon scattering is significant in $La_2C_3$, which is relevant with the relatively high-$T_c$ in $La_2C_3$ through strong electron-phonon coupling with low frequency phonon modes.

Photoluminescence of YVO4:Eu3+ Prepared by Li2CO3 Addition

  • Moon, Seong-Jun;Jeong, Hyun-Gon;Kwak, Jong-Ho;Sohn, Kee-Sun
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.11
    • /
    • pp.658-661
    • /
    • 2008
  • Deep red color emitting $YVO_4:Eu^{3+}$ phosphors were investigated in an attempt to achieve promising performances in cold cathode fluorescent lamp (CCFL) applications. For this purpose, several additives such as LiF, $Li_2CO_3$ and $HBO_3$ were introduced in the processing. While two of the additives were ineffective, the inclusion of $LiCO_3$ during the solid state synthesis of $YVO_4:Eu^{3+}$ phosphors was proven to enhance photoluminescent intensity and the color chromaticity. Unlike the commercially available $YVO_4:Eu^{3+}$ red phosphor for use in PDP applications, pure $YVO_4:Eu^{3+}$ excluding phosphorous was shown to be favorable for CCFL applications, improving color chromaticity at 254nm excitations.

PURE THIN FILMS FROM Ba/Ti ALKOXIDES

  • K. Musabekov;N. Korobova;Wha, Soh-Dea
    • Electrical & Electronic Materials
    • /
    • v.11 no.11
    • /
    • pp.46-52
    • /
    • 1998
  • Barium titanate owes its great importance to the fact that its dielectric constant is about 100 times higher than that of conventional dielectric materials provided its compositional and structural purity is extremely high. The value of crystalline BaTiO3 bodies as used, for instance, in computer elements, magnetic amplifiers, memory device, ets., depend on boththe compositional and the structural purity of the BaTiO3 crystals. This purity will, in turn, depend on the purity of the raw materials used in manufacturing the BaTiO3 compound and on the particularmethods of manufacture which determine the size, homogeneity, and the structural purity of the crystals. This paper reviews the important theoretical considerations, processing techniques and applications related to sol-gel derived thin films.

  • PDF

Electrical Properties of Nanoscale LB Layers of Amphiphilic Conducting Material (전도성 양친매성의 Nanoscale LB 막의 전기적 특성)

  • 최인희;박수길;김재호;조병호;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1996.11a
    • /
    • pp.221-224
    • /
    • 1996
  • We synthesized amphiphilic material including dye skeleton, p-phenylenediamine(PD) by attaching norma-decyl group of two strands at a part of coordinating atom, for obtaining reasonable design of LB uniform films. The synthesis of this compounds was quantitatively carried out under ultra pure state. This product was identified with FT-lR spectroscopy, UV absortion spectroscopy, and $^1$H-NMR spectroscopy, respectively. When manufacturing monolayer, we confirmed molecular area from pressure-area($\pi$-A) cutie of thiscompound onto the surface of the water. The spectroscopic approach also has done by UV absortion spectroscopy. It was shown that PD-complex LBfilms were deposited well with monolayer thickness. The conductivity based on I-V characteristics of PD-complex LB films were in the range of 10$^{-10}$ S/cm at room temperture. The microscopic properties by AFM, showed the good orientation of various monolayer or multilayer molecules

  • PDF

A study on insulation Characteristics of XLPE by various additives (다양한 첨가제에 따른 가교폴리에틸렌의 절연특성 분석)

  • Song, Sang-Min;Kim, Gyu-Sik;Son, Won-Keun;Ryu, Boo-Hyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.05c
    • /
    • pp.193-196
    • /
    • 2001
  • XLPE is occasionally happened to deteriorate cable insulation characteristics. It is happened to do a breakdown state by the degradation of electrical characteristic and electrical breakdown strength. I prepared TR-XLPE (Tree-Retardant XLPE) as adding various additives to prevent its states. Various additives are treeing retardants, anti-oxidants. Treeing retardants three kinds of aromatic compounds as adding each additive. Anti-oxidants use quinone compound and cresol compound as adding each additive. In order to observe each electrical characteristics, I measured breakdown strength, relative dielectric constant$({\varepsilon}_r)$, dielectric loss tangent$(tan{\delta})$. TR-XLPE specimens as adding treeing retardants and anti-oxidants enhance breakdown strength, ${\varepsilon}_r$, $tan{\delta}$ than pure XLPE.

  • PDF