Journal of Information Display

The Korean Infomation Display Society (한국정보디스플레이학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of an oxynitride-based green phosphor $Ba_3Si_6O_{12}N_2:Eu^{2+}$ via an aqueous-solution process, using propylene-glycol-modified silane

  • Yasushita, Chihiro (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ;
  • Kato, Hideki (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ;
  • Kakihana, Masato (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University)
  • Received : 2011.12.28
  • Accepted : 2012.05.04
  • Published : 2012.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

An almost pure phase of $Ba_3Si_6O_{12}N_2$ doped with $Eu^{2+}$ was successfully synthesized through the ammonia nitridation of an oxide precursor prepared through an aqueous-solution method, using propylene- glycol-modified silane. The emission peak intensity of the obtained $Ba_3Si_6O_{12}N_2:Eu^{2+}$ was -2.2 times higher than that of the sample prepared through a solid-state reaction method.

Keywords

References

  1. G. Blasse and A. Bril, Appl. Phys. Lett. 11, 53 (1967). https://doi.org/10.1063/1.1755025
  2. J. Yum, S. Seo, S. Lee, and Y. Sung, J. Electrochem. Soc. 150, H47 (2003). https://doi.org/10.1149/1.1535207
  3. S.H.M. Poort, W. Janssen, and G. Blasse, J. Alloys Compd. 260, 93 (1997). https://doi.org/10.1016/S0925-8388(97)00140-0
  4. J.K. Park, M.A. Lim, C.H. Kim, H.D. Park, and J.T. Park, Appl. Phys. Lett. 82, 683 (2003). https://doi.org/10.1063/1.1544055
  5. Y. Shimomura, T. Honma, M. Shigeiwa, T. Akai, K. Okamoto, and N. Kijima, J. Electrochem. Soc. 154, J35 (2007). https://doi.org/10.1149/1.2388856
  6. M. Mikami, S. Shimooka, K. Uheda, H. Imura, and N. Kijima, Key Eng. Mater. 403, 11 (2009). https://doi.org/10.4028/www.scientific.net/KEM.403.11
  7. Y.Q. Li, A.C.A. Delsing, G. deWith, and T. Hintzen, Chem. Mater. 17, 3242 (2005). https://doi.org/10.1021/cm050175d
  8. V. Bachmann, T. Justela, A. Meijerink, C. Ronda, and P.J. Schmidt, J. Lumin. 121, 441 (2006). https://doi.org/10.1016/j.jlumin.2005.11.008
  9. Y.Q. Li, J.E.J. van Steen, J.W.H. van Krevel, G. Botty, A.C.A. Delsing, F.J. DiSalvo, G. deWith, and H.T. Hintzen, J. Alloys Compd. 417, 273 (2006). https://doi.org/10.1016/j.jallcom.2005.09.041
  10. X. Piao, T. Horikawa, H. Hanzawa, and K. Machida, Appl. Phys. Lett. 88, 161908 (2006). https://doi.org/10.1063/1.2196064
  11. K. Uheda, N. Hirosaki,Y.Yamamoto, A. Naito, T. Nakajima, and H. Yamamoto, Electrochem. Solid-State Lett. 9, H22 (2006). https://doi.org/10.1149/1.2173192
  12. H. Watanabe, H. Wada, K. Seki, M. Itou, and N. Kijima, J. Electrochem. Soc. 155, F31 (2008). https://doi.org/10.1149/1.2829880
  13. N. Takahashi, Y. Suzuki, and M. Kakihana, J. Ceram. Soc. Jpn. 117, 313 (2009). https://doi.org/10.2109/jcersj2.117.313
  14. Y. Suzuki and M. Kakihana, J. Ceram. Soc. Jpn. 117, 330 (2009). https://doi.org/10.2109/jcersj2.117.330
  15. M. Kakihana, J. Ceram. Soc. Jpn. 117, 857 (2009). https://doi.org/10.2109/jcersj2.117.857
  16. T. Nakanishi and S. Tanabe, J. Light Vis. Environ. 32, 93 (2008). https://doi.org/10.2150/jlve.32.93
  17. M. Mikami, H. Watanabe, K. Uheda, S. Shimooka, Y. Shimomura, T. Kurushima, and N. Kijima, IOP Conf. Ser.: Mater. Sci. Eng. 1, 012002 (2009).

Cited by

  1. KSrScSi2O7:Eu2+: a novel near-UV converting blue-emitting phosphor with high efficiency and excellent thermal stability vol.3, pp.37, 2012, https://doi.org/10.1039/c3ra42882f
  2. Exploration of New Phosphors Using a Mineral-Inspired Approach in Combination with Solution Parallel Synthesis vol.3, pp.6, 2012, https://doi.org/10.4236/opj.2013.36a002
  3. Synthesis of a Novel Bluish-Green Emitting Oxynitride Ca<sub>3</sub>Al<sub>8</sub>Si<sub>4</sub>O<sub> vol.3, pp.6, 2012, https://doi.org/10.4236/opj.2013.36a006
  4. Eu2+-Activated CaSrSiO4: a New Red-Emitting Oxide Phosphor for White-Light-Emitting Diodes vol.6, pp.7, 2012, https://doi.org/10.7567/apex.6.072101
  5. Syntheses of Silicate Phosphors by Aqueous Solution Techniques using Water-Dispersible Inorganic Si Cluster vol.62, pp.4, 2012, https://doi.org/10.2497/jjspm.62.127