• 제목/요약/키워드: pseudo-science

검색결과 901건 처리시간 0.023초

Synthesis and Reactivity of a Mononuclear Manganese(II) Complex Having Pseudo-Seven Coordination Environment

  • Yoon, Jee-Hee;Seo, Mi-Sook;Kim, Young-Mee;Kim, Sung-Jin;Yoon, Sung-Ho;Jang, Ho G.;Nam, Won-Woo
    • Bulletin of the Korean Chemical Society
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    • 제30권3호
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    • pp.679-682
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    • 2009
  • Utilizing a planar five coordinating N3S2 ligand, 2,6-bis(2-methylthiophenyliminomethyl)pyridine, a pseudo 7-coordinated manganese(II) complex with two labile triflate anions in the axial positions was synthesized. The reaction of the manganese(II) complex with an oxidant, iodosylbenzene, produced a metastable high-valent manganese(IV)-oxo species at 0 ${^{\circ}C}$. The high-valent Mn(IV)-oxo intermediate was characterized with a UV-vis spectrophotometer and an electrospray ionization mass spectroscopy. Reactivity studies of the Mn(IV)=O species revealed that the intermediate is capable of oxygenating $PPh_3$ and N-dealkylating N,N-dimethyl-toludine.

Class Specific Autoencoders Enhance Sample Diversity

  • Kumar, Teerath;Park, Jinbae;Ali, Muhammad Salman;Uddin, AFM Shahab;Bae, Sung-Ho
    • 방송공학회논문지
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    • 제26권7호
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    • pp.844-854
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    • 2021
  • Semi-supervised learning (SSL) and few-shot learning (FSL) have shown impressive performance even then the volume of labeled data is very limited. However, SSL and FSL can encounter a significant performance degradation if the diversity gap between the labeled and unlabeled data is high. To reduce this diversity gap, we propose a novel scheme that relies on an autoencoder for generating pseudo examples. Specifically, the autoencoder is trained on a specific class using the available labeled data and the decoder of the trained autoencoder is then used to generate N samples of that specific class based on N random noise, sampled from a standard normal distribution. The above process is repeated for all the classes. Consequently, the generated data reduces the diversity gap and enhances the model performance. Extensive experiments on MNIST and FashionMNIST datasets for SSL and FSL verify the effectiveness of the proposed approach in terms of classification accuracy and robustness against adversarial attacks.

자연토양 및 카올린에 대한 코발트, 스트론튬, 세슘의 흡착 특성 (Adsorption Characteristics of Cobalt, Strontium, and Cesium on Natural Soil and Kaolin)

  • 천경호;최정학;신원식;최상준
    • 한국환경과학회지
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    • 제23권9호
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    • pp.1609-1618
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    • 2014
  • In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.

Improved Preimage Attacks on RIPEMD-160 and HAS-160

  • Shen, Yanzhao;Wang, Gaoli
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제12권2호
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    • pp.727-746
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    • 2018
  • The hash function RIPEMD-160 is a worldwide ISO/IEC standard and the hash function HAS-160 is the Korean hash standard and is widely used in Korea. On the basis of differential meet-in-the-middle attack and biclique technique, a preimage attack on 34-step RIPEMD-160 with message padding and a pseudo-preimage attack on 71-step HAS-160 without message padding are proposed. The former is the first preimage attack from the first step, the latter increases the best pseudo-preimage attack from the first step by 5 steps. Furthermore, we locate the linear spaces in another message words and exchange the bicliques construction process and the mask vector search process. A preimage attack on 35-step RIPEMD-160 and a preimage attack on 71-step HAS-160 are presented. Both of the attacks are from the intermediate step and satisfy the message padding. They improve the best preimage attacks from the intermediate step on step-reduced RIPEMD-160 and HAS-160 by 4 and 3 steps respectively. As far as we know, they are the best preimage and pseudo-preimage attacks on step-reduced RIPEMD-160 and HAS-160 respectively in terms of number of steps.

Chord rotation demand for effective catenary action of RC beams under gravitational loadings

  • Tsai, Meng-Hao
    • Structural Engineering and Mechanics
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    • 제58권2호
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    • pp.327-345
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    • 2016
  • Many experimental and analytical studies have been conducted with beam-column subassemblages composed of a two-span beam to investigate the progressive collapse resistance of RC frames. Most study results reveal a strength-decreased transition phase in the nonlinear static load-deflection curve, which may induce dynamic snap-through response and increase the chord rotation demand for effective catenary action (ECA). In this study, the nonlinear static response is idealized as a piecewise linear curve and analytical pseudo-static response is derived for each linearized region to investigate the rotation demands for the ECA of the two-span RC beams. With analytical parameters determined from several published test results, numerical analysis results indicate that the rotation demand of 0.20 rad recommended in the design guidelines does not always guarantee the ECA. A higher rotation demand may be induced for the two-span beams designed with smaller span-to-depth ratios and it is better to use their peak arch resistance (PAR) as the collapse strength. A tensile reinforcement ratio not greater than 1.0% and a span-to-depth ratio not less than 7.0 are suggested for the two-span RC beams bridging the removed column if the ECA is expected for the collapse resistance. Also, complementary pseudo-static analysis is advised to verify the ECA under realistic dynamic column loss even though the static PAR is recovered in the nonlinear static response. A practical empirical formula is provided to estimate an approximate rotation demand for the ECA.

Air Pollutants Tracing Model using Perceptron Neural Network and Non-negative Least Square

  • Yu, Suk-Hyun;Kwon, Hee-Yong
    • 한국멀티미디어학회논문지
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    • 제16권12호
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    • pp.1465-1474
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    • 2013
  • In this paper, air pollutant tracing models using perceptron neural network(PNN) and non-negative least square(NNLS) are proposed. When the measured values of the air pollution and the contribution concentration of each source by chemical transport modeling are given, they estimate and trace the amount of the air pollutants emission from each source. Two kinds of emissions data are used in the experiments : CH4 and N2O of Geumgo-dong landfill greenhouse gas, and PM10 of 17 areas in Northeast Asia and eight regions of the Korean Peninsula. Emission values were calculated using pseudo inverse method, PNN and NNLS. Pseudo inverse method could be used for the model, but it may have negative emission values. In order to deal with the problem, we used the PNN and NNLS methods. As a result, the estimation using the NNLS is closer to the measured values than that using PNN. The proposed tracing models have better utilization and generalization than those of conventional pseudo inverse model. It could be used more efficiently for air quality management and air pollution reduction.

Automatic Electronic Cleansing in Computed Tomography Colonography Images using Domain Knowledge

  • Manjunath, KN;Siddalingaswamy, PC;Prabhu, GK
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권18호
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    • pp.8351-8358
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    • 2016
  • Electronic cleansing is an image post processing technique in which the tagged colonic content is subtracted from colon using CTC images. There are post processing artefacts, like: 1) soft tissue degradation; 2) incomplete cleansing; 3) misclassification of polyp due to pseudo enhanced voxels; and 4) pseudo soft tissue structures. The objective of the study was to subtract the tagged colonic content without losing the soft tissue structures. This paper proposes a novel adaptive method to solve the first three problems using a multi-step algorithm. It uses a new edge model-based method which involves colon segmentation, priori information of Hounsfield units (HU) of different colonic contents at specific tube voltages, subtracting the tagging materials, restoring the soft tissue structures based on selective HU, removing boundary between air-contrast, and applying a filter to clean minute particles due to improperly tagged endoluminal fluids which appear as noise. The main finding of the study was submerged soft tissue structures were absolutely preserved and the pseudo enhanced intensities were corrected without any artifact. The method was implemented with multithreading for parallel processing in a high performance computer. The technique was applied on a fecal tagged dataset (30 patients) where the tagging agent was not completely removed from colon. The results were then qualitatively validated by radiologists for any image processing artifacts.