• 제목/요약/키워드: properties UV

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PVC 바닥상재용 광경화형 폴리우레탄 아크릴 수지의 합성 및 특성고찰 (Synthesis and Charcterization of UV-curable Polyurethane Acrylates Coating Composition for PVC Tiles)

  • 조홍;하진욱
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2009년도 추계학술발표논문집
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    • pp.80-83
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    • 2009
  • Application of UV curing technique for poly vinyl chloride (PVC) floor tiles coating has improved the quality of PVC floor. Various formulations including acrylated oligomers based on a polyurethane were blended with reactive monomers, photoinitiators and other additives. The used oligomers are commercial aliphatic urethane acrylates. Thin films were prepared on PVC tiles by bar coating with different formulations using UV radiation. The coating resins were characterized by FTIR. The properties of UV-cured films such as gloss grade and adhesion were examined. The properties of UV-cured films dependent on the influence of composition and processing conditions was studied. The investigation was conducted to achieve an optimal domain of composition and desired coating effect.

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UV경화성 수지와 Alkyd수지 복합재료의 경화거동과 동적 점탄성에 관한 연구 (A Study on the dynamic viscoelasticity of UV curing polymer and alkyd resin composite materials)

  • 정원식;최정병;김용욱
    • 한국인쇄학회지
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    • 제16권3호
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    • pp.29-41
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    • 1998
  • The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

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Comparison of Effects of Ultraviolet and $^{60}$ Co Gamma Ray Irradiation on Nylon 6 Mono-filaments

  • Ohtsuka, Mika;Suzuki, Yoshino;Sakai, Tetsuya;Netravali, Anil N.
    • Fibers and Polymers
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    • 제5권3호
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    • pp.225-229
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    • 2004
  • The effect of UV and $^60{Co}$ gamma radiations on the physical and mechanical properties of nylon 6 mono-filaments with different draw ratios has been studied. Specimens were exposed to either up to 25 Mrad of gamma or up to 168 hrs of intense UV irradiation. The results show that nylon mono-filaments exposed to gamma rays, with much higher quantum energy than UV, undergo a larger extent of molecular chain scission. Higher irradiation dose also results in the production of insoluble, macroscopic three-dimensional cross-linked network structure. The amorphous regions with a lower density of cohesive energy (lower molecular orientation) show a higher extent of cross linking reaction whereas amorphous regions with a higher density of cohesive energy (higher orientation) show higher extent of chain scission reaction, irrespective of UV ray or gamma ray irradiation.

UV Perspective for Dynamically Old and Young Clusters of Galaxies: Fornax and Virgo

  • 이영대;이수창;박민아;김석;성언창;이원형;정지원
    • 천문학회보
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    • 제36권2호
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    • pp.76.1-76.1
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    • 2011
  • We present ultraviolet (UV) photometric properties of galaxies in two clusters, the Fornax and Virgo, with different dynamical conditions. We construct UV color-magnitude relations (CMRs) of galaxies in the Fornax and Virgo clusters using GALEX UV data matching with optical B band data. Elliptical and lenticular galaxies locate on red sequence in UV CMRs and show UV upturn phenomenon in both clusters. While dwarf lenticular galaxies (dS0s) in the Fornax also follow the extension of red sequence of giant early type galaxies, they are redder than dS0s in the Virgo at a given magnitude. We also investigated the effect of neighbor galaxies and cluster environment to the UV properties. In the space of projected clustercentric radius and projected nearest neighbor galaxy distance, we found that red (NUV-B>3) galaxy fraction of the Fornax depends entirely on clustercentric radius. However, in the case of Virgo, galaxy colors are also affected by interactions between galaxies outside the cluster virial radius. We suggest that UV properties of early-type galaxies in the Fornax cluster is likely consistent with its dynamically evolved system compared to the Virgo cluster.

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UV조사에 의한 Poly(lactic acid)-g-Acrylic Acid 이온교환체의 합성 및 흡착특성 (Synthesis of Poly(lactic acid)-g-Acrylic Acid Ion Exchanger by UV Radiation Method and Metal Adsorption Properties)

  • 최은미;손복기;이창수;황택성
    • 폴리머
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    • 제33권1호
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    • pp.52-57
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    • 2009
  • 본 연구는 UV 조사법으로 poly(lactic acid)-g-acrylic acid(PLA-g-AAc) 이온교환체를 합성하고 이들의 금속흡착 특성을 ICP-AES 분석을 통해 확인하였다. PLA-g-AAC의 UV 조사량과 AAc의 농도변화에 따른 함수율, 그래프트율 및 이온교환용량을 측정하였다. 그래프트율은 AAc 및 benzophenone(BP) 농도가 각각 1.0, 0.1 mol/L일때 최대 28%이었으며, 이온교환용량과 함수율은 각각 1.13 meq/g와 38%로 UV 조사량 및 AAc의 농도가 증가함에 따라 증가하였다. 한편, PLA-g-AAc의 흡착시간에 따른 $Cu^{2+}$, $Co^{2+}$, $Ni^{2+}$에 대한 선택 흡착성은 모두 높게 나타났으며 $Cu^{2+}$가 가장 우수한 선택흡착성을 나타내었다.

UV Enhanced NO2 Sensing Properties of Pt Functionalized Ga2O3 Nanorods

  • An, Soyeon;Park, Sunghoon;Mun, Youngho;Lee, Chongmu
    • Bulletin of the Korean Chemical Society
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    • 제34권6호
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    • pp.1632-1636
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    • 2013
  • $Ga_2O_3$ one-dimensional (1D) nanostructures were synthesized by using a thermal evaporation technique. The morphology, crystal structure, and sensing properties of the $Ga_2O_3$ nanostructures functionalized with Pt to $NO_2$ gas at room temperature under UV irradiation were examined. The diameters of the 1D nanostructures ranged from a few tens to a few hundreds of nanometers and the lengths ranged up to a few hundreds of micrometers. Pt nanoparticles with diameters of a few tens of nanometers were distributed around a $Ga_2O_3$ nanorod. The responses of the nanorods gas sensors fabricated from multiple networked $Ga_2O_3$ nanorods were improved 3-4 fold at $NO_2$ concentrations ranging from 1 to 5 ppm by Pt functionalization. The Pt-functionalized $Ga_2O_3$ nanorod gas sensors showed a remarkably enhanced response at room temperature under ultraviolet (UV) light illumination. In addition, the mechanisms via which the gas sensing properties of $Ga_2O_3$ nanorods are enhanced by Pt functionalization and UV irradiation are discussed.

UV조사 처리한 PET의 역학적 특성변화와 감성평가 (The physiological properties and sensibility of PET irradiated by ultraviolet rays)

  • 최혜영;이정순
    • 한국생활과학회지
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    • 제15권2호
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    • pp.275-281
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    • 2006
  • The purpose of this study is to investigate hand and sensibility of PET treated by Ultra-Violet (UV). The 4-channel PET knit fabric was treated by a self-made UV instrument in 5cm distance with different time frames-0min, 30min, and 90min. For hand evaluation, mechanical properties were measured by the KES-FB system. The environmental condition was controlled at 29$^{\circ}C$, 75% (R.H.)-summer standard climate. Twenty female students evaluated 'roughness', 'smoothness', 'wetness', 'stiffness', 'coolness', 'touch', 'preference', and 'comfort'. The outcomes of the experiment are as follows: The surface roughness of mechanical properties showed significant differences and the value of PET irradiated by UV for 90min was highest. The order of primary hand value such as NUMERI and FUKURAMI was in a following order-Untreated > 30min treated > 90min treated. Total hand value showed that PET irradiated by UV for 90min was appropriate for using summer fabric. The results of subjective sensibility were that the untreated and 30min treated PET were recognized as similar and had a good evaluation on 'comfort', 'preference' and 'the sense of touch'. This consequence disagreed with total hand value, because it was considered that subjects' hand sensibility was dependent on the feel of smoothness.

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실란기가 도입된 폴리우레탄 아크릴레이트 합성 및 자외선 경화 특성 분석 (Synthesis of Silane Group Modified Polyurethane Acrylate and Analysis of Its UV-curing Property)

  • 김정수
    • 접착 및 계면
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    • 제22권3호
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    • pp.98-105
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    • 2021
  • 본 연구에서는 실란기가 도입된 UV 경화형 우레탄 아크릴레이트를 사용하여 투명성 및 접착성/이형성을 갖춘 silver nanoparticle 전사용 접착 조성물을 제조하였다. Silver nanoparticle이 PET 위에 패터닝되어 있는 Ag/PET 필름과 전사 대상인 PC필름 사이에 제조한 접착 조성물을 도포하고 UV로 광경화한 후, PET를 제거하여 Ag/PC 필름을 제조하였다. 실란기가 도입된 UV 경화형 우레탄 아크릴레이트는 polycaprolactone diol (PCL)과 isophrone diisocyanate (IPDI), 2-hydroxyethyl methacrylate (HEMA), (3-aminopropyl)triethoxysilane (APTES)를 사용하여 합성하였다. APTES의 실란기는 특수 처리된 Ag표면과 반응하여 계면접착력이 개선될 수 있으며, 실란기가 도입된 우레탄 아크릴레이트와 희석제로 투입하는 기능성 아크릴 희석제에 의하여 PC필름과의 접착력을 향상시켰다. 우레탄 아크릴레이트 합성은 FT-IR을 이용하여 분석하였으며, APTES의 몰비와 아크릴 희석제 조성에 따라, 접착 특성과 광학 특성, 전사 특성 등을 비교하였다. 결과적으로, PUA2S1_0.5의 조건으로 제조된 접착 조성물에서 가장 우수한 전사 특성을 확인하였다.

UV조사를 통한 PET의 표면개질(제2보) -수분특성 및 물리적 특성 변화- (Surface Modification of PET Irradiated by Ultra-Violet (Part II) - Transformation of moisture properties and physical Properties -)

  • 최혜영;이정순
    • 한국의류학회지
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    • 제29권5호
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    • pp.617-625
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    • 2005
  • The purpose of this study was to develop functional and environment-friendly polyester fabric by irradiating Ultra-Violet, which was produced by the low-pressure mercury lamp. UV irradiation was conducted with various treatment times and distances. Also, pretreatments of solvents and photoinitiator were used to improve the surface modification effects. The effects of UV irradiation on the moisture regain were found to increase gradually with increase of UV treatment time and decrease of treatment distance. Compared the effects of UVC and UVA, UVC was more effective than UVA. Moisture regain and wicking of PET was increased after UV treatment in our experimental condition. And owing to increasing of moisture regain, static charge was decreased. Pretreatment of solvents such as methanol, ethyl ether and addition of photoinitiator such as Benzophenone accelerated surface modification. The moisture regain was increased but wicking was decreased with pretreatment and addition of photoinitiatior. Therefore it is considered as inappropriate f3r clothing because of wicking effects. Yellowness, tensile strength and elasticity slightly decreased after UV irradiation.

TiO2 나노입자를 함유한 PLA 필름의 탈취성과 항균성 (The Deodorization and Antibacterial Activities of PLA Films Embedded with TiO2 Nanoparticles)

  • 구광회;장진호
    • 한국염색가공학회지
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    • 제20권6호
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    • pp.1-7
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    • 2008
  • The effects of $TiO_2$ contents and UV irradiation treatment on the surface properties of PLA films embedded with $TiO_2$ nanoparticle were investigated. Whereas UV irradiation decreased reflectance of the treated PLA films proportionally with increasing UV energy, the reflectance of PLA/$TiO_2$ films increased with increasing UV energy. The UV irradiation treatment caused PLA/$TiO_2$ blend films more polar as indicated in the generation of new carbonyl group and decrease in zeta potentials, which was more pronounced with the introduction of $TiO_2$. Upon UV irradiation, $TiO_2$ particles appeared on the film surface as observed in SEM images. The PLA/$TiO_2$ blend films showed photocatalytic properties such as photobleaching of methylene blue, deodorization of ammonia and antimicrobial activity in comparison with pure PLA films.