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http://dx.doi.org/10.17702/jai.2021.22.3.98

Synthesis of Silane Group Modified Polyurethane Acrylate and Analysis of Its UV-curing Property  

Kim, Jung Soo (Material & Component Convergence R&D Department, Korea Institute of Industrial Technology (KITECH))
Publication Information
Journal of Adhesion and Interface / v.22, no.3, 2021 , pp. 98-105 More about this Journal
Abstract
In this study, we prepared a silver nanoparticle transferable adhesive composition with transparency and adhesive properties using UV-curable urethane acrylate containing silane groups. The urethane-based adhesive composition was applied between the Ag/PET film in which silver nanoparticles were patterned on PET and the PC film to be transferred. Immediately after UV-curing with UV, PET was removed to complete the manufacture of Ag/PC film. UV-curable urethane acrylate containing silane groups was synthesized using polycaprolactone diol (PCL), isophrone diisocyanate (IPDI), 2-hydroxyethyl methacrylate (HEMA), and (3-aminopropyl) triethoxysilane (APTES). The silane group of APTES can improve interfacial adhesion by reacting with the specially treated silver nanoparticle surface of the Ag/PET film. In addition, we improved the adhesion between silver nanoparticle and PC film by mixing UV-curable urethane acrylate containing a silane group and a functional acrylic diluent used as a diluent. We analyzed the synthesis process of urethane acrylate using FT-IR, and compared the adhesive properties, optical properties, and transfer properties according to the molar ratio of APTES and the acrylic diluent composition. As a result, the best transfer properties were confirmed in the adhesive composition prepared under the conditions of PUA2S1_0.5.
Keywords
PUA; Silane coupling agent; Functional acrylate; Silver nanoparticle; Transfer adhesive;
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1 S.E. Im, S.Y. Kim, S.J. Kim, & J.H. Kim, Applied Chemistry for Engineering, 26(6), 640 (2015).   DOI
2 S.J. Kim, K. Choi, & S.Y. Choi, Korean J. Met. Mater., 53(12), 890 (2015).   DOI
3 M.H. Chung, S.Y. Kim, D.H. Yoo, & J.H. Kim, Appl. Chem. Eng., 25(3), 240 (2014).
4 J. Lee, P. Lee, H. Lee, D. Lee, S.S. Lee, & S.H. Ko, Nanoscale, 4(20), 6408 (2012).   DOI
5 I. V., Khudyakov, K. W., Swiderski, & R. W., Greer, Journal of Applied Polymer Science, 99(2), 489 (2006).   DOI
6 Z., Jiao, X., Wang, Q., Yang, & C., Wang, Polymer Bulletin, 74(7), 2497 (2017).   DOI
7 Y.W. Shin, K.B. Kim, S.J. Noh, & S.Y. Soh, Appl. Chem. Eng., 29(2), 162 (2018).   DOI
8 M., Alishiri, A., Shojaei, M. J., Abdekhodaie, & H., Yeganeh, Materials Science and Engineering: C, 42, 763 (2014).   DOI
9 Z., Jiao, X., Wang, Q., Yang, & C., Wang, Polymer Bulletin, 74(7), 2497 (2017).   DOI
10 B. H., Lee, & H. J. Kim, Polymer Degradation and Stability, 91(5), 1025 (2006).   DOI
11 A., Milinaviciute, V., Jankauskaite, & P., Narmontas, Materials Science, 17(4), 378 (2011).
12 W., Han, B., Lin, H., Yang, & X., Zhang, Journal of Applied Polymer Science, 128(6), 4261 (2013).   DOI
13 L., Han, J., Dai, L., Zhang, S., Ma, J., Deng, R., Zhang, & J., Zhu, RSC Advances, 4(90), 49471 (2014).   DOI
14 H. A., Mohamed, B. M., Badran, A. M., Rabie, & S. M. M., Morsi, Progress in Organic Coatings, 77(5), 965(2014).   DOI
15 M. D., Valcic, S. M., Cakic, I. S., Ristic, J. D., Cakic, M. J., Cvetinov, & C. J. Janos, Int. J. Adhesion and Adhesives, 104, 102738 (2021).   DOI
16 W., Han, B., Lin, Y., Zhou, & J., Song, Polymer Bulletin, 68(3), 729 (2012).   DOI
17 He, Z., Zhou, G., Byun, J. H., Lee, S. K., Um, M. K., Park, B. & Chou, T. W., Nanoscale, 11(13), 5884 (2019).   DOI
18 J. H., Chun, J. M., Cheon, B. Y., Jeong, & N. J. Jo, Journal of Nanoscience and Nanotechnology, 16(3), 2687 (2016).   DOI
19 H. A., Mohamed, S. M. M., Morsi, B. M., Badran, & A. M. Rabie, Polymer Bulletin, 74(2), 531 (2017).   DOI
20 Z., Grigale-Sorocina, M., Kalnins, J., Simanovska, E., Vindedze, I., Birks, & E., Brazdauska, Materials Science, 22(1), 54(2016).
21 X., Wang, & M. D. Soucek, Progress in Organic Coatings, 76(7-8), 1057 (2013).   DOI
22 S., Shokoohi, A., Arefazar, & R. Khosrokhavar, Journal of Reinforced Plastics and Composites, 27(5), 473 (2008).   DOI
23 F., Liao, X. R., Zeng, H. Q., Li, X. J., Lai, & F. C. Zhao, Journal of Central South University, 19(4), 911 (2012).   DOI
24 S., Ifuku, & H. Yano, International Journal of Biological Macromolecules, 74, 428 (2015).   DOI