• 한국재료학회지
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• 제18권7호
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• pp.362-366
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• 2008

The precipitation behavior in Mg-6 wt%Zn-1 wt%Y alloy annealed at different temperatures of $200^{\circ}C$ and $400^{\circ}C$ has been characterized by high resolution transmission electron microscope. When the alloy is annealed at $200^{\circ}C$ for 6 hr, the plate- and the rod-shaped ${\beta}_2'$ phases are precipitated in the matrix. The orientation relationship of plate-shaped precipitates with the matrix exhibits a [$11{\bar{2}}0]{\beta}_2$ || [$10{\bar{1}}0$]Mg, $(0001){\beta}_2'$ || (0001)Mg. While the rod-shaped precipitates have two kinds of the orientation relationships with the matrix, i.e. $[11{\bar{2}}0]{\beta}_2'$||[0001] Mg, $(0001){\beta}_2'||(11{\bar{2}}0)$ Mg and $[11{\bar{2}}0]{\beta}_2'$||[0001] Mg, $({\bar{1}}106){\beta}_2'||(10{\bar{1}}0)$ Mg. With increasing annealing time at $200^{\circ}C$ the ${\beta}_1'$ phases are also precipitated in the matrix and the orientation relationship exhibits a $[010]{\beta}_1'$ || [0001]Mg, $(603){\beta}_1'$ || ($01{\bar{1}}0$)Mg between the ${\beta}_1'$ precipitate and the matrix. The icosahedral phases are precipitated in the alloy annealed at $400^{\circ}C$ and exhibit a $[I2]_I$ || [0001]Mg relationship with the matrix.

• 열처리공학회지
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• 제26권1호
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• pp.14-20
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• 2013

Duplex stainless steel, which is a kind of stainless steel with a mixed microstructure of about equal proportions of austenite and ferrite, is generally known as a unique material with excellent corrosion resistance and high strength. However, toughness, strength, and corrosion resistance of the steel could be reduced due to precipitation of topologically closed packed phases such as sigma phase during cooling. In case of large forged products, they have strong possibility that ${\sigma}$-phase precipitates due to difference of cooling rate between surface and inner of the products. Investigation on sigma phase precipitation behavior of duplex stainless steel with change of cooling rate was carried out in this study. Forged SAF 2205 duplex stainless steel was used as specimens to examine the cooling rate effect. Dissolution behavior of sigma phase was also discussed through resolution test of duplex stainless steel containing lots of sigma phase. Experimental results revealed that impact energy was very sensitive to precipitation of small amount sigma phase. However, sigma phase could be removed by short term resolution treatment and impact resistance of the duplex stainless steel was restored.

• 한국재료학회지
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• 제2권2호
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• pp.119-125
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• 1992

수평자장을 건 Czochralski(HMCZ) 방법으로 자장강도(B)와 도가니 회전속도(C)가 실리콘 단결정의 산소편석에 미치는 영향에 대하여 연구하였다. B=2, 3, 4kG와 C=4-15rpm에서 <100> 방향으로 성장시킨 57mm 직경의 단결정들 내의 산소분포는 대체로 축을 따라서 불균일하였고 톱니모양을 나타내었다. 종래의 CZ 방법과 비교할 때, 이러한 산소분포의 불균일성은 위 강도의 수평자장이 결정성장계면으로의 산소전달에 불안정한 요소로 작용했음을 나타낸다고 볼 수 있다. 반면에 C의 증가는 산소분포의 불균일성의 약화와 산소농도의 전반적인 증가를 유도하였다. 이 결과를 토대로 B=2kG에서 27-36ppma인 산소분포를 가진 단결정이 프로그램된 C에 의해서 얻어졌다. 소자제조공정을 모의한 열처리 과정에서 HMCZ 실리콘의 산소석출은 종래의 CZ 실리콘의 산소석출에 비해서 상대적으로 불균일하였고, as-grown 상태에서의 고르지 못한 HMCZ 실리콘의 산소분포가 주요 원인임이 밝혀졌다.

• 대한금속재료학회지
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• 제50권4호
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• pp.285-292
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• 2012

Hot ductility behavior of precipitation-hardened low-carbon iron alloys containing 0.02 wt% Ti and 0.05 wt% Nb was characterized by a hot tensile stress test. Carbon (0.05, 0.1, 0.25 wt%) and boron (0.002 wt%) contents were varied to study the effect of precipitates on the high-temperature embrittlement of the alloys in the temperature range of $600{\sim}800^{\circ}C$. Ductility loss was observed at $700^{\circ}C$ for the tested alloys. The cause of the ductility loss was mainly attributed to the carbides and ferrite films formed at the grain boundaries during deformation. Although the carbon content tended to raise the total fraction of Nb (C, N), the precipitates were formed mostly in the grain interior as the precipitation temperature was raised above the deformation temperature by the high carbon content. Hence, carbon in excess suppressed the hot ductility loss. Meanwhile, boron addition improved the hot ductility of the alloys. The improvement is likely due to the boron atoms capturing carbon atoms and thus retarding the carbide formation.

• 대한금속재료학회지
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• 제46권8호
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• pp.477-481
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• 2008

The secondary hardening and fracture behavior in P/M high speed steels bearing V content of 9 to 10 wt% have been investigated in terms of austenitizing temperature and precipitation behavior. Austenitizing was conducted at 1,100 and $1,175^{\circ}C$ of relatively low and high temperatures. Coarse primary carbides retained after austenitization were mainly V-rich MC type. They give a significant influence on hardeness and toughness, as well as wear resistance. Tempering was performed in the range of $500{\sim}600^{\circ}C$. The peak hardness resulting from the precipitation of the fine MC secondary carbides was observed near 520, irrespective of austenitizing temperature. Aging acceleration(or deceleration) did not occur with increasing austenitizing temperature because it mainly influences contents of V and C of matrix through the dissloution of coarse primary MC containing lots of V and C. The precipitation of secondary MC carbides, which also contain V and C, did not change the aging kinetics itself. In the 10V alloy containing much higher C content, the impact toughness was lower than 9V alloy, because of the larger amount of primary carbide and high hardness.

• 열처리공학회지
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• 제22권2호
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• pp.101-107
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• 2009

Effect of isochronic aging on transformation behavior of Ti-50.85at%Ni alloy were investigated by differential scanning calorimeter (DSC). The martensitic transformation temperature increases with increasing annealing temperature until reaching a maximum, and then decreases with further increasing annealing temperature. This can be rationalized by interaction between the distribution of $Ti_3Ni_4$ precipitates and Ni content in the matrix. The R-phase transformation temperature increases with increasing annealing temperature until reaching a maximum, and then decreases with a further increase of annealing temperature. This is attributed to the change of Ni content in the matrix caused by precipitation of $Ti_3Ni_4$. The occurrence of the multiple-stage martensitic and R-phase transformation is attributed to precipitation-induced inhomogeneity of the matrix, both in terms of composition and of internal stress fields.

• Nuclear Engineering and Technology
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• 제35권6호
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• pp.515-522
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• 2003

Tritium behavior in the solid breeder blanket is one of the key factors in determining tritium self-sufficiency, as well as safety, of fusion reactors. Recently, a model has been developed to describe the tritium behavior in solid breeder material, which can predict the tritium release and inventory in the blanket. However, the model has limitation to account for tritium solubility effects, mainly existing as LiOT, especially inside the $Li_{2}O$ solid breeder. In order to improve the capability of predicting the LiOT precipitation in $Li_{2}O$ solid breeder, a new logic is developed and integrated in the existing tritium release and inventory calculation code. With the logic developed in this work, the code can have capabilities to analyze tritium release and inventories in $Li_{2}O$ under steady and transient conditions. It can be found that tritium inventory as LiOT is an important mechanism under pulsed operation, and the amount of inventory becomes higher as the tritium generation rate increases and the temperature decreases. Also, the temperature limits for the generation of LiOT precipitation are determined. Therefore the developed logic helps understand the tritium transport mechanism in $Li_{2}O$ solid breeder.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.219-222
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• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• 한국지구과학회지
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• 제35권1호
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• pp.41-53
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• 2014

겨울철 동해안 강수 현상에 대한 규명을 위하여 라디오존데를 활용한 특별관측을 2012년 1월 5일부터 2월 29일까지 실시하였고, 이 연구는 대기의 불안정을 나타내는 다양한 변수를 활용하여 강수 사례의 분석을 수행하였다. 그 결과, 강수가 발생할 때 지표면(1000 hPa)에서 중층(약 750 hPa)까지의 상당온위가 증가하는 것을 볼 수 있었고, 이러한 대기층(1000~750 hPa)은 불안정을 일으키기에 충분한 수준의 수증기를 함유하고 있었다. 대류가용잠재에너지의 시간적인 변화를 살펴본 결과 강수가 발생하였을 때 증가하는 것을 볼 수 있었고, 연직바람쉬어의 경우에서도 대류가용잠재에너지와 마찬가지로 강수 기간 동안 상승하여 일정수준 이상의 값을 유지하는 것을 확인할 수 있었다. 강수에 따른 대기 구조의 상세한 분석을 위하여 지상 원격 탐사 자료와 지상 관측 자료를 활용하여 분석을 수행하였다. 또한 가강수량과 바람벡터를 이용하여 가강수량플럭스를 계산하였다. 가강수량플럭스와 강수량은 북동풍 계열의 바람이 발생하였을 때 높은 관계성을 보였다. 그 결과 동해안영역에서 발생하는 강수 현상에서는 풍계와 같은 역학적인 작용의 이해가 중요한 것으로 판단되었다.

• 한국수자원학회논문집
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• 제56권10호
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• pp.655-665
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• 2023

본 연구에서는 일정한 경사와 조도를 갖는 가상 유역에서 10가지 규모의 강수가 순간적으로 발생할 때 단위유량도를 산출하였다. 그런 다음 강수 규모에 대하여 단위유량도 첨두유량의 관계와 첨두발생시간의 관계를 각각 산출하였다. 이때 강수 규모만이 유역의 단위유량도 첨두치에 주는 영향을 파악하기 위해서 자연 유역을 대신하여 마름모 형태, 일정 경사, 일정 조도의 유로 환경 상태 등으로 단순화한 가상 유역을 적용하였다. 그리고 유역에 내린 강수는 유효우량이고 유출은 직접유출이고 낙하지점에서 출구 방향으로 직선적인 등류로 유출된다고 가정하였다. 강수 규모를 10가지로 유효강수 10 mm, 40 mm, 90 mm, 160 mm, 250 mm, 360 mm, 640 mm, 1,000 mm, 1,210 mm, 1,690 mm의 경우로 하여 단위유량도의 첨두유량과 첨두발생시간을 각각의 관계를 산출하였다. 본 연구에서 주목할 만한 성과는 유역의 저류 효과가 없어도 강수 규모가 커질수록 유출 깊이가 커져서 유역의 유속이 빨라지고 단위 시간당 유하 거리도 커지므로 첨두유량은 커지고 첨두발생시간은 빨라진다는 것이었다. 이는 유역 유출의 비선형적 특성이다.