• Title/Summary/Keyword: pre-activation

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Study on the Pyrolysis Kinetics of RDF(Refuse Derived Fuel) with Thermogravimetric Analysis (열중량 분석 기법을 통한 RDF의 열분해 특성 조사)

  • Kim, Dong-Won;Lee, Jong-Min;Kim, Jae-Sung
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.676-682
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    • 2009
  • Devolatilization of the Refuse Derived Fuel(RDF) which is produced at WonJu in Korea was characterized in air atmosphere with variation of heating rate(10, 20 and $30^{\circ}C/min$) in TGA. The results of TG Analysis have shown that the pyrolysis and char combustion of the RDF occurred in the range of $350{\sim}700^{\circ}C$ depending on the heating rate. Activation energy of the RDF which was determined by using Friedman and Ozawa-Flynn-Wall method was in the range of 14.44~18.40 kcal/mol. Also, reaction order(n) and pre-exponential factors(A) were 1.219 and $3.02{\times}10^5$ by using Friedman method, respectively. In order to find out the devolatilization mechanism of the RDF, twelve solid-state mechanisms defined by Coats Redfern Method were tested. The results of the Coats Redfern Method have shown that chemical reaction is the effective mechanism by comparison with the value of the activation energy which was derived from the Friedman and Flynn-Wall-Ozawa method and correlation coefficient from twelve solid-state mechanisms of Coats Redfern Method. The solid state decomposition mechanism of the RDF was found to be a decelerated $F_1$ type, random nucleation with one nucleus on the individual particle.

Cure Kinetics of Diglycidyl ether of bisphenol A-Methylene dianiline-Succlnonitrile System (Diglycidyl ether of bisphenol A/Methylene dianiline/Succinonitrile계의 경화반응 속도론)

  • Jo, Seong-U;Sim, Mi-Ja;Kim, Sang-Ok
    • Korean Journal of Materials Research
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    • v.2 no.4
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    • pp.257-262
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    • 1992
  • The cure kinetics of a diglycidyl ether of bisphenol A (DGEBA) with 4, 4'-methylene dianiline (MDA) added succinonitrile was studied through the dynamic run method by applying the data to the Kissinger equation which analyses the effect of the heating rate on the temperature at maximum reaction rate using Differential Scanning Calorimetry (DSC) analyzer in the range of 3$0^{\circ}C$-35$0^{\circ}C$. In the DGEBA/MDA system with SN, the activation energy ($E_a$) and the pre-exponential factor (A) were calculated. From these results, the rate constants (k) were obtained according to the different SN contents.

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Effect of Loaded Warm-up Jumps on the Following Performance of Vertical Jump (과중량을 이용한 워밍업 점프가 사후 점프 수행에 미치는 영향)

  • Kim, Hyun-Goun;Kim, Young-Kwan;Cho, Hang Nan
    • Korean Journal of Applied Biomechanics
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    • v.25 no.2
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    • pp.167-174
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    • 2015
  • Purpose : The purpose of this study was to investigate the effects of loaded vertical jumps on the following vertical jumps and to find how long the transient effect of warm-ups would continue. Methods : Twelve healthy college male students, majoring in physical education, participated in this study voluntarily. They performed three sets of unloaded jumps (pre-jump, 5% post jump, and 10% post jump) and two sets of loaded jumps (5% and 10% loaded jumps) according to the counter-balanced order. At each set, three trials of maximal vertical jumps were performed by a 30 second interval between trials and a 3 minute break after warm-up jumps. Force platform and motion capturing system were used to record motions and ground reaction force. Results : Only 5% post-warm-up jumps ($48.29{\pm}2.06cm$) showed significant increase in the jump height compared with pre-warm-up jumps ($47.35{\pm}2.21cm$). The transient effects of loaded warm-ups disappeared 4 minutes after loaded jumps. Conclusion : Conclusively, a decent amount of loading (around 5% extra of body weight) during sport specific warm-ups would give a positive, transient effect on the performance of the vertical jump.

Fertilization by Microinjection of Mouse Round Spermatid (생쥐 원형정자세포의 미세주입에 의한 수정)

  • 이상민;백청순;구덕본;김묘경;김진회;박흠대;이훈택;정길생
    • Korean Journal of Animal Reproduction
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    • v.19 no.3
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    • pp.171-179
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    • 1995
  • This study was carried out to investigate the fertilizing ability of round spematids isolated from seminiferous tubules. A round spermatid was introduced into the perivitelline space of a mature oocyte using Leitz micromanipulators and then subjected to electrofusion. Electrofusion was induced by applying a single DC pulse of 90V with a duration of 60$\mu$sec using Model 611 Square Wave Stimulator(Phipps and Bird, U.S.A) in 0.3 M sucrose fusion medium containing 0.05mM CaCl2 and 0.1mM MgSO4, Oocyte pre-activation was conducted by exposure to a single DC(80V, 80$\mu$sec) pulse in electrofusion medium at 1 hour before electrofusion. The incidence of fusion with pre-activated oocytes(23.8%, 57/239) was higher than that with nonactivated oocytes(6.7%, 3/45). The most of electro-stimulated mouse oocytes cleaved regardless of the success or failure of fusion. Karyotyping of embryos that developed into blastocysts after exposure to the fusion pulse were performe. We found that blastocysts from the fused oocytes were diploid whereas blastocysts from the unfused oocytes were haploid. About 11.7 and 11.5% of fused and unfused oocytes were developmental potentials of fused and unfused oocytes. Therefore, these results suggest that the mouse mture oocyte can be fertilized by fusion with a round spermtid and subsequently developed normally.

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Immunoaffinity Characteristics of Exosomes from Breast Cancer Cells Using Surface Plasmon Resonance Spectroscopy

  • Sohn, Young-Soo;Na, Wonhwi;Jang, Dae-Ho
    • Journal of Sensor Science and Technology
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    • v.28 no.6
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    • pp.355-359
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    • 2019
  • Exosomes, known as nanoscale extracellular vesicles in the range of 30-150 nm, are known to contain clinically significant information. However, there is still insufficient information on exosomal membrane proteins for cancer diagnosis. In this work, we investigated the characteristics of the membrane proteins of exosomes shed by cultured breast cancer cell lines using a surface plasmon resonance (SPR) spectroscopy and pre-activated alkanethiols modified sensor chips. The antibodies of breast cancer biomarkers such as MCU-16, EpCAM, CD24, ErbB2, and CA19-9 were immobilized on the pre-activated alkanethiols surfaces without any activation steps. The purified exosomes were loaded onto each antibody surface. The affinity rank of the antibody surfaces was decided by the relative capture efficiency factors for the exosomes. In addition, an antibody with a relative capture efficiency close to 100% was tested with exosome concentration levels of 104/µl, 105/µl, and 106/µl for quantitative analysis.

Cure Reaction of Epoxy Resin System with MN/HQ (MN/HQ가 첨가된 에폭시 수지계의 경화반응 연구)

  • Chun, In-Sook;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.967-974
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    • 1994
  • We studied the cure kinetics of the DGEBA(Diglycidyl ether of bisphenol A)/MDA(4, 4' -methylene dianiline)/MN(Malononitrile)/HQ(Hydroquinone) system by Barrett method and Integral method with dynamic runs of differential scanning calorimetry(DSC). Kinetic parameters such as activation energy and pre-exponential factor were obtained and reaction order was estimated roughly supposing that present system was adjusted to nth order reaction. The MN(Malononitrile) was introduced as a chain extender and HQ(Hydroquinone) as a reactive accelerator or catalyst.

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Fabrication of SiCOI Structures Using SDB and Etch-back Technology for MEMS Applications (SDB와 etch-back 기술에 의한 MEMS용 SiCOI 구조 제조)

  • Jung, Su-Yong;Woo, Hyung-Soon;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.830-833
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    • 2003
  • This paper describes the fabrication and characteristics of 3C-SiCOI sotctures by SDB and etch-back technology for high-temperature MEMS applications. In this work, insulator layers were formed on a heteroepitaxial 3C-SiC film grown on a Si(001) wafer by thermal wet oxidation and PECVD process, successively. The pre-bonding of two polished PECVD oxide layers made the surface activation in HF and bonded under applied pressure. The wafer bonding characteristics were evaluated by the effect of HF concentration used in the surface treatment on the roughness of the oxide and pre-bonding strength. Hydrophilic character of the oxidized 3C-SiC film surface was investigated by ATR-FTIR. The strength of the bond was measured by tensile strengthmeter. The bonded interface was also analyzed by SEM. The properties of fabricated 3C-SiCOI structures using etch-back technology in TMAH solution were analyzed by XRD and SEM. These results indicate that the 3C-SiCOI structure will offers significant advantages in the high-temperature MEMS applications.

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The effects on academic of self-directed learning and in-depth interviewing program in engineering underachieved students (자기주도학습과 심층면담 프로그램이 이공계 학습부진학생의 학업에 미치는 영향 연구)

  • Kim, Hae-kyung;Choi, Wonyoung
    • Journal of Engineering Education Research
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    • v.18 no.1
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    • pp.54-60
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    • 2015
  • The purposes of the study are to investigate the effects on academic of the self-directed learning and in-depth interviewing program in engineering underachieved students. 17 students participated in program and the grade points average(GPA) of participants are less than 2.5. First, we focus on the change of academic achievement after the self-directed learning and in-depth interviewing program. According to results, it is very effective not only in improving academic achievement of the participation subject but also in increasing GPA. Second, the pre-survey and the post-survey were conducted to the participants. We found some facts from the difference between the pre and post surveys. The expectation and satisfaction about learning have improved after self-directed learning, and the participants' recognition showed the meaningful change in important factors about learning.

Effects of Transcranial Direct Current Stimulation with Aerobic Exercise on Lower Extremity Muscle Endurance for Elderly Women (경피 두개 직류 전류자극과 병행한 유산소운동이 노인 여성의 근지구력에 미치는 영향)

  • Cho, Namjeong;Kim, Suhyon
    • Journal of The Korean Society of Integrative Medicine
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    • v.6 no.2
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    • pp.117-123
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    • 2018
  • Purpose : The purpose of this study was to investigate the effect of increased brain activity on the muscle endurance and the effect of brain activation through the combination of transcranial direct current stimulation and aerobic exercise on elderly woman. Methods : To investigate the effect of the muscle endurance on right leg, muscle endurance was evaluated by measuring the surface EMG of the muscles of the rectus femoris, biceps femoris, tibialis anterior, and gastrocnemius muscle. Results : There was a significant difference in the pre and post comparisons of muscle endurance on rectus femoris, biceps femoris, tibialis anterior muscle (p<.05). Difference of Combination of transcranial direct current stimulation and aerobic exercise group median frequency was smaller than control group (p<.05). There was not a significant difference in the pre and post comparisons of muscle endurance on biceps femoris, and gastrocnemius muscle. Difference of Combination of transcranial direct current stimulation and aerobic exercise group median frequency was showed a similar pattern. Conclusion : Through these results, It was found that increasing the brain activity by the transcranial direct current stimulation improves the exercise capacity on the elderly women. Combination of transcranial direct current stimulation and aerobic exercise maybe applied as an effective treatment for improving muscular endurance.

Anti-inflammatory Effects of Andrographis Herba MeOH Extract on LPS-induced Raw 264.7 Cells (천심련(穿心蓮) 메탄올 추출물의 항염증효과)

  • Jung, Ji Yun;Park, Chung A
    • Herbal Formula Science
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    • v.28 no.2
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    • pp.147-155
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    • 2020
  • PURPOSE : Andrographis Herba is used as a traditional herbal medicine in the Asian countries for the treatment common cold, fever, diabetes, hypertension, hepatitis, skin infections, snake bite, and other diseases. In this study, we investigated the anti-inflammatory effect of MeOH extract of Andrographis Herba (AHME) on LPS-activated Raw 264.7 cells. METHODS : Cell viability was determined by MTT assay. Nitric oxide (NO) production was determined by Griess reagent. Pro-inflammatory cytokines were detected by enzyme-linked immunosorbent assay. Expression levels of pro-inflammatory proteins were determined by Western blot analysis. RESULTS : Production of NO in LPS activated Raw 264.7 cells, was significantly decreased by pre-treatment with 3-30 ㎍/mL of AHME. Production of pro-inflammatory mediators such as TNF-α and IL were significantly decreased by AHME 30 ㎍/mL pre-treatment. AHME significantly decreased p-IκB and NF-κB expression. CONCLUSION : The results of this study indicate that AHME could inhibit the acute inflammatory response, via modulation of NF-κB activation.