• Journal of Environmental Science International
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• v.29 no.12
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• pp.1213-1222
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• 2020

In the current study, a Cu2O/TiO2 photoinduced nanocomposite materials prepared by ultrasonification method was evaluated the photocatalytic oxidation efficiency of volatile organic compounds (BTEX) under visible-light irradiation. The results of XRD confirmed the successful preparation of photoinduced nanocomposite materials. However, diffraction peaks belonging to TiO2 were not confirmed for the Cu2O/TiO2. The possible reason for the absence of Cu2O peak is their low content and small particle size. The result of uv-vis spectra exhibited that the fabricated Cu2O/TiO2 can be activated under visible light irradiation. The FE-SEM/EDS and TEM showed the formation of synthesized nanocomposites and componential analysis in the undoped TiO2 and Cu2O/TiO2. The photocatalytic oxidation efficiencies of benzene, toluene, ethylbenzene, and o-xylene with Cu2O/TiO2 were higher than undoped TiO2. According to light sources, the average oxidation efficiencies for BTEX by Cu2OT-0.5 were exhibited in the orer of 8 W day light > violet LEDs > white LEDs. However, the photocatalytic oxidation efficiencies normalized to supplied electric power were calculated to be in the following order of violet LEDs > white LEDs > 8 W day light, indicating that the LEDs could be a much more energy efficient light source for the photo-oxidation of gaseous BTEX using Cu2O/TiO2.

• Current Photovoltaic Research
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• v.8 no.4
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• pp.107-113
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• 2020

Here we report the long-term stability of polymer:nonfullerene solar cells which were stored under dark and indoor light condition. The polymer:nonfullerene solar cells were fabricated using bulk heterojunction (BHJ) layers of poly[(2,6-(4,8-bis(5-(2-ethylhexyl) thiophen-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5',7-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(6-methyl-2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). To investigate their long-term stability, the PBDB-T:IT-M solar cells were stored in an argon-filled glove box. One set of the fabricated solar cells was completely covered with an aluminum foil to prevent any effect of light, whereas another set was exposed to indoor light. The solar cells were subjected to a regular performance measurement for 40 weeks. Results revealed that the PBDB-T:IT-M solar cells underwent a gradual decay in performance irrespective of the storage condition. However, the PBDB-T:IT-M solar cells stored under indoor light condition exhibited relatively lower power conversion efficiency (PCE) than those stored under the dark. The inferior stability of the solar cells under indoor light was explained by the noticeably changed optical absorption spectra and dark spot generation, indicative of degradations in the BHJ layers.

• Nuclear Engineering and Technology
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• v.54 no.1
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• pp.374-385
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• 2022

In order to investigate the application of 3D base-seismic isolation system in nuclear power plants (NPPs), comprehensive analysis of constitution and design theory for 3-dimensional combined isolation bearing (3D-CIB) was presented and derived. Four different vertical stiffness of 3D-CIB was designed to isolate the nuclear island (NI) building. This paper aimed at investigating the isolation effectiveness of 3D-CIB through modal analysis and dynamic time-history analysis. Numerical results in terms of dynamic response of 3D-CIB, relative displacement response, acceleration and floor response spectra (FRS) of the superstructure were compared to validate the reliability of 3D-CIB in mitigating seismic response. The results showed that 3D-CIB can significantly attenuate the horizontal acceleration response, and a fair amount of the vertical acceleration response reduction of the upper structure was still observed. 3D-CIB plays a significant role in reducing the horizontal and vertical FRS, the vertical FRS basically do not vary with the floor height. The smaller the vertical stiffness of 3D-CIB is, the better the vertical isolation effectiveness is, whereas, it will increase the displacement and the rocking effect of superstructure. Although the advantage of 3D-CIB is that the vertical stiffness can be flexibly adjusted, it should be designed by properly accounting for the balance between the isolation effectiveness and displacement control including rocking effect. The results of this study can provide the technical basis and guidance for the application of 3D-CIB to engineering structure.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.125-125
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• 2020

European Space Agency's Sentinel-1 has an improved spatial and temporal resolution, as compared to previous satellite data such as Envisat Advanced SAR (ASAR) or Advanced Scatterometer (ASCAT). Thus, the assumption used for low-resolution retrieval algorithms used by ENVISAT ASAR or ASCAT is not applicable to Sentinel-1, because a higher degree of land surface heterogeneity should be considered for retrieval. The assumption of homogeneity over land surface is not valid any more. In this study, considering that soil roughness is one of the key parameters sensitive to soil moisture retrievals, various approaches are discussed. First, soil roughness is spatially inverted from Sentinel-1 backscattering over Yanco sites in Australia. Based upon this, Artificial Neural Networks data (feedforward multiplayer perception, MLP, Levenberg-Marquadt algorithm) are compared with Fractal approach (brownian fractal, Hurst exponent of 0.5). When using ANNs, training data are achieved from theoretical forward scattering models, Integral Equation Model (IEM). and Sentinel-1 measurements. The network is trained by 20 neurons and one hidden layer, and one input layer. On the other hand, fractal surface roughness is generated by fitting 1D power spectrum model with roughness spectra. Fractal roughness profile is produced by a stochastic process describing probability between two points, and Hurst exponent, as well as rms heights (a standard deviation of surface height). Main interest of this study is to estimate a spatial variability of roughness without the need of local measurements. This non-local approach is significant, because we operationally have to be independent from local stations, due to its few spatial coverage at the global level. More fundamentally, SAR roughness is much different from local measurements, Remote sensing data are influenced by incidence angle, large scale topography, or a mixing regime of sensors, although probe deployed in the field indicate point data. Finally, demerit and merit of these approaches will be discussed.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.25 no.3
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• pp.147-153
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• 2013

There exist various types of the WEC (Wave Energy Converter), and among them, the point absorber is the most popularly investigated type. However, it is difficult to find examples of systematically measured data analysis for the design of the point absorber type of power buoy in the world. The study investigates the wave load acting on the point absorber type resonance power buoy wave energy extraction system proposed by Kweon et al. (2010). This study analyzes the time series spectra with respect to the three-year wave data (2002.05.01~2005.03.29) measured using the pressure type wave gage at the seaside of north breakwater of Hupo harbor located in the east coast of the Korean peninsula. From the analysis results, it could be deduced that monthly wave period and wave height variations were apparent and that monthly wave powers were unevenly distributed annually. The average wave steepness of the usual wave was 0.01, lower than that of the wind wave range of 0.02-0.04. The mode of the average wave period has the value of 5.31 sec, while mode of the wave height of the applicable period has the value of 0.29 m. The occurrence probability of the peak period is a bi-modal type, with a mode value between 4.47 sec and 6.78 sec. The design wave period can be selected from the above four values of 0.01, 5.31, 4.47, 6.78. About 95% of measured wave heights are below 1 m. Through this study, it was found that a resonance power buoy system is necessary in coastal areas with low wave energy and that the optimal design for overcoming the uneven monthly distribution of wave power is a major task in the development of a WEF (Wave Energy Farm). Finding it impossible to express the average spectrum of the usual wave in terms of the standard spectrum equation, this study proposes a new spectrum equation with three parameters, with which basic data for the prediction of the power production using wave power buoy and the fatigue analysis of the system can be given.

• 전자공학회논문지 IE
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• v.43 no.4
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• pp.1-7
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• 2006

In this paper, two types of blue organic light-emitting device were designed. We have analyzed the characteristics of Type I device without a hole blocking layer, and analyzed the characteristics of Type II device using a hole blocking layer of BCP or BAlq materials with 30 ${\AA}$ thickness. We obtained the ITO having the work function value of 5.02 eV using $N_2$ plasma treatment method with the plasma power 200 W. Type I device structure was ITO/2-TNATA/$\alpha$-NPD/DPVBi/$Alq_3$/LiF/Al:Li, and type II device structure was ITO/2-TNATA/$\alpha$-NPD/DPVBi/HBL/$Alq_3$/LiF/Al:Li. We have analyzed the characteristics of Type I and Type II device. The characteristics of the device were most efficiency on occasion of using a hole blocking layer of BAlq material with 30 ${\AA}$ thickness. Current density was 226.75 $mA/cm^2$, luminance was 10310 $cd/m^2$, Current efficiency was 4.55 cd/A, power efficiency was 1.43 lm/W at an applied voltage of 10V. The maximum EL wavelength of the fabricated blue organic light-emitting device was 456nm. The full-width at half-maximum (FWHM) for the EL spectra was 57nm. CIE color coordinates were x=0.1438 and y=0.1580, which was similar to NTSC deep-blue color with CIE color coordinates of x=0.14 and y=0.08.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.33 no.3
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• pp.159-169
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• 2020

Acceleration amplification factors, which are variables used in the seismic design of power facilities installed inside substation structures, are presented in the seismic design standards of the United States (US), Japan, and Korea. Unlike the coefficients presented in the design standards of the US and Japan, those presented in domestic design standards can be obtained only by performing dynamic analysis when the substation structure has more than four floors. Because most substation structures in Korea have 4-5 stories, the existing acceleration amplification factor is insufficient to be applied to actual substation structures. To suggest an acceleration amplification factor suitable for domestic substation structure types, the acceleration amplification factor was evaluated for seven representative substation structures. The acceleration amplification factors were evaluated by constructing in-structure response spectra based on a study of far-field and near-fault earthquakes. In general, the acceleration amplification coefficients α_J and α_A according to the US and Japan seismic design criteria tend to be overestimated compared with the acceleration amplification factors obtained through dynamic analysis based on the study of near-fault and far-field earthquakes.

• Korean Journal of Materials Research
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• v.20 no.11
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• pp.586-591
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• 2010

Solar cells have been more intensely studied as part of the effort to find alternatives to fossil fuels as power sources. The progression of the first two generations of solar cells has seen a sacrifice of higher efficiency for more economic use of materials. The use of a single junction makes both these types of cells lose power in two major ways: by the non-absorption of incident light of energy below the band gap; and by the dissipation by heat loss of light energy in excess of the band gap. Therefore, multi junction solar cells have been proposed as a solution to this problem. However, the $1^{st}$ and $2^{nd}$ generation solar cells have efficiency limits because a photon makes just one electron-hole pair. Fabrication of all-silicon tandem cells using an Si quantum dot superlattice structure (QD SLS) is one possible suggestion. In this study, an $SiO_x$ matrix system was investigated and analyzed for potential use as an all-silicon multi-junction solar cell. Si quantum dots with a super lattice structure (Si QD SLS) were prepared by alternating deposition of Si rich oxide (SRO; $SiO_x$ (x = 0.8, 1.12)) and $SiO_2$ layers using RF magnetron co-sputtering and subsequent annealing at temperatures between 800 and $1,100^{\circ}C$ under nitrogen ambient. Annealing temperatures and times affected the formation of Si QDs in the SRO film. Fourier transform infrared spectroscopy (FTIR) spectra and x-ray photoelectron spectroscopy (XPS) revealed that nanocrystalline Si QDs started to precipitate after annealing at $1,100^{\circ}C$ for one hour. Transmission electron microscopy (TEM) images clearly showed SRO/$SiO_2$ SLS and Si QDs formation in each 4, 6, and 8 nm SRO layer after annealing at $1,100^{\circ}C$ for two hours. The systematic investigation of precipitation behavior of Si QDs in $SiO_2$ matrices is presented.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.17-18
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• 2011

Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1081-1088
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• 2013

Two new metal-free organic dyes bridged by anthracene-mediated ${\pi}$-conjugated moieties were successfully synthesized for use in a dye-sensitized solar cell (DSSC). A N,N-diphenylthiophen-2-amine unit in these dyes acts as an electron donor, while a (E)-2-cyano-3-(thiophen-2-yl)acrylic acid group acts as an electron acceptor and an anchoring group to the $TiO_2$ electrode. The photovoltaic properties of (E)-2-cyano-3-(5-((10-(5-(diphenylamino)thiophen-2-yl)anthracen-9-yl)ethynyl)thiophen-2-yl)acrylic acid (DPATAT) and (E)-2-cyano-3-(5'-((10-(5-(diphenylamino)thiophen-2-yl)anthracen-9-yl)ethynyl)-2,2'-bithiophen-5-yl)acrylic acid (DPATABT) were investigated to identify the effect of conjugation length between electron donor and acceptor on the DSSC performance. By introducing an anthracene moiety into the dye structure, together with a triple bond and thiophene moieties for fine-tuning of molecular configurations and for broadening the absorption spectra, the short-circuit photocurrent densities ($J_{sc}$), and open-circuit photovoltages ($V_{oc}$) of DSSCs were improved. The improvement of $J_{sc}$ in DSSC made of DPATABT might be attributed to much broader absorption spectrum and higher molecular extinction coefficient (${\varepsilon}$) in the visible wavelength range. The DPATABT-based DSSC showed the highest power conversion efficiency (PCE) of 3.34% (${\eta}_{max}$ = 3.70%) under AM 1.5 illumination ($100mWcm^{-2}$) in a photoactive area of $0.41cm^2$, with the $J_{sc}$ of $7.89mAcm^{-2}$, the $V_{oc}$ of 0.59 V, and the fill factor (FF) of 72%. In brief, the solar cell performance with DPATABT was found to be better than that of DPATAT-based DSSC.