• 한국정밀공학회지
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• 제18권6호
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• pp.121-126
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• 2001

Currently, potentiometric method has been employed to measure fuel amount for automobile. However, potentiometer could be malfunctioned or damaged due to the additives or dirt in fuel because a variable electric resistor is immersed in fuel. Therefore, a device employing strain sensor is designed and tested to verify the possibility as an alternative of the conventional fuel sender. Existing fuel tank has irregular cross section. Therefore, buoyancy is not increased linearly as fuel amount is increased. We design a floater that can compensate the irregular cross section of fuel tank and make buoyancy to increase linearly with increasing fuel amount. New fuel sender, comprising of strain gages on circular membrane, the above commented floater and the cover to prevent the disturbance due to sudden acceleration and deceleration, is designed and tested to replace current fuel sender. On the other hand, we are developing strain sensor that has strain gage deposited directly on the circular membrane with cantilever beam.

• Bulletin of the Korean Chemical Society
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• 제23권11호
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• pp.1635-1639
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• 2002

A new solvent polymeric membrane sensor based on tetra(p-chlorophenyl)porphyrinato manganese (III) acetate is described which demonstrates excellent selectivity toward the triiodide ion. The electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-2}$ M and 7.0 ${\times}$$10^{-6}$M with a Nernstian slope of $-59.6{\pm}1$ mV per decade and a detection limit of 5.0 ${\times}$$10^{-6}$M. The proposed sensor revealed good selectivities for triiodide over a wide variety of other anions and could be used in a pH range 2-9. The electrode can be used for at least two months without any considerable divergence in potential. It was applied as indicator electrode in potentiometric titration of the triiodide and As(III) ions.

• Bulletin of the Korean Chemical Society
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• 제20권5호
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• pp.556-558
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• 1999

Lead-selective PVC membrane electrodes based on newly synthesized bis(crown ether)s containing 18-crown-6 moiety was prepared using standard PVC membrane composition. In order to monitor lead in environmental samples by lead sensor, especially good selectivity over alkali and alkaline earth metals has to be obtained. Thus, responses of the PVC membrane prepared with new bis(crown ether)s and Fluka ionophore V (crown ether) base to various cations include lead, alkali and alkaline earth metal ions were investigated for their use as a lead sensor. The polymeric liquid membrane based on trans-1 8-crown-6 ether exhibits the best overall potentiometric performances as a lead-selective electrode in terms of a wide linear dynamic range (between 10-6 and 10-2 M, Pb2+), excellent detection limit (less than 10-6 M) and good durability within limited error. The preferences of lead over other cations, such as Ag+, Hg2+, Na+, Ca2+ and even K+ in the aforementioned electrode are much better than the Fluka ionophore V system.

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1418-1422
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• 2006

In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

• Journal of Biosystems Engineering
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• 제32권5호
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• pp.348-353
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• 2007

A solid state ion sensor module has been developed and evaluated for hydroponic nutrients analysis. The sensor module consisted of five ion-selective electrodes (ISE) fabricated by screen-printing technology. The electrochemical responses of ion sensors for nitrate, ammonium, potassium, calcium, and pH were measured with specially designed 7-channel low voltage signal transducers. The analytical characteristics of the sensors were comparable with those of conventional ISE sensors. The solid state ion sensors exhibit linear relationships over five concentration decades. Detection limit of the sensors were $5.6{\times}10^{-5}{\sim}1.6{\times}10^{-7}M$ depends on ions. Performance test results showed that relative errors of measured ion concentrations were less than 5% for $NO_3{^-},\;K^+,\;Ca^{2+}$ ion, and pH. The concentration of $NO_3{^-},\;NH_4{^+},\;K^+,\;Ca^{2+}$, and pH ion in standard solution and nutrient solutions could be determined by direct potentiometric measurements without any conditioning before measurements.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.177-181
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• 2004

A PVC membrane electrode for silver ion based on a new cone shaped calix[4]arene (CASCA) as membrane carrier was prepared. The electrode exhibits a Nernstian response for $Ag^+$ over a wide concentration range ($1.0{\times}10^{-1}-8.0{\times}10^{-6}$M) with a slope of 58.2 {\pm}$ 0.5 mV per decade. The limit of detection of the sensor is $5.0{\times}10^{-6}$M. The sensor has a very fast response time (~5 s) in the concentration range of ${\leq}=1.0{\times}10^{-3}$ M, and a useful working pH range of 4.0-9.5. The proposed sensor displays excellent discriminating ability toward $Ag^+$ ion with respect to common alkali, alkaline earth, transition and heavy metal ions. It was used as an indicator electrode in potentiometric titration of $Ag^+$ with EDTA and in direct determination of silver ion in wastewater of silver electroplating.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.3088-3092
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• 2013

A novel PVC membrane sensor for perindopril based on perindopril-phosphotungstate ion pair complex was prepared. The influence of membrane composition (i.e. percent of PVC, plasticizer, ion-pair complex, and kind of plasticizer), inner solution, pH of test solution and foreign cations on the electrode performance was investigated. The optimized membrane demonstrates Nernstian response ($30.9{\pm}1.0$ mV per decade) for perindopril cations over a wide linear range from $9.0{\times}10^{-7}$ to $1{\times}10^{-2}$ M at $25^{\circ}C$. The potentiometric response is independent of the pH in the range of 4.0-9.5. The proposed sensor has the advantages of easy preparation, fast response time. The selectivity coefficients indicate excellent selectivity for perindopril over many common cations (e.g., $Na^+$, $K^+$, $Mg^{2+}$, $Cu^{2+}$, $Ni^{2+}$, rhamnose, maltose, glycine and benzamide. The practical applications of this electrode was demonstrated by measuring the concentrations of perindopril in pure solutions and pharmaceutical preparations with satisfactory results.

• 공업화학
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• 제30권6호
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• pp.737-741
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• 2019

본 연구에서는 스크린 프린팅 공정을 이용하여 저렴하고 유연한 칼륨 이온(K⁺) 센서를 제작하였다. 전도성 잉크의 균일한 코팅은 주사 전자 현미경 및 광학 현미경 측정에 의해 입증되었다. K⁺ 센서는 높은 감도, 빠른 응답 시간, 낮은 검출 한계를 보여주었다. 제조된 K⁺ 센서의 감도는 기계적으로 구부러진 상태에도 여전히 유지되었다. 히스테리시스 효과가 없는 우수한 반복성과 우수한 장기 안정성이 K⁺ 센서의 전기화학적 특성 분석에서 관찰되었다. 또한, K⁺ 센서는 다른 간섭 양이온이 존재하는 경우에도 정확하게 K⁺ 농도를 측정 할 수 있어 우수한 선택성을 증명하였다. 또한, 실제 스포츠 음료 샘플에서 K⁺ 농도의 성공적인 측정은 K⁺ 센서의 K⁺ 농도 값과 상용 K⁺ 미터를 비교하여 증명되었다.

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1601-1608
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• 2010

A scandium(III) porphyrin-based fluoride-selective potentiometric sensor and its application in the analysis of hydrofluoric acid is described. Scandium(III) octaethylporphyrin, an ionophore recently developed for the optical fluoride sensor, was employed as a host molecule for the selective binding with fluoride in the plasticized PVC membrane. Nernstian response for $F^-$ between $10^{-4.6}$ to $10^{-1}$ M was observed at a glycine-phosphate buffer (pH 3.0). The selectivity pattern was observed as $F^-$, salicylate $\gg$ $SCN^-$ > $Cl^-$, $Br^-$, $NO_3{^-}$, $ClO_4{^-}$, which is consistent with the binding constant data measured in the plasticized PVC membrane based on a sandwich membrane method. This highly selective and reversible fluoride-sensitive electrode was employed for the analysis of hydrofluoric acid (HF). A disposable differential-type HF sensor was fabricated on the screen-printed electrode and demonstrated its ability to detect the neutral HF in the acidic solution.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2303-2308
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• 2009

A thiocyanate poly(vinyl chloride) (PVC) membrane electrode based on [1,2-bis(diphenylphosphino)ethane]dihalopalladium( II), [(dppe)$PdX_2$, X = Cl ($L^1$), X = I ($L^2$)] as active sensor has been developed. The diiodopalladium complex, [(dppe)$PdI_2](L^2$) displays an anti-Hofmeister selectivity sequence: $SCN^-\;>\;I^-\;>\;{ClO_4}^-\;>\;Sal^-\;>\;Br^-\;>\;{NO_2}^-\;>\;{HPO_4}^-\;>\;AcO^-\;>\;{NO_3}^-\;>\;{H_2PO_4}^-\;>\;{CO_3}^{2-}$. The electrode exhibits a Nernstian response (-59.8 mV/decade) over a wide linear concentration range of thiocyanate ($(1.0\;{\times}\;10^{-1}\;to\;5.0\;{\times}\;10^{-6}$ M), low detection limit ($(1.1\;{\times}\;10^{-6}$ M), fast response $(t_{90%}$ = 24 s), and applicability over a wide pH range (3.5∼11). Addition of anionic sites, potassium tetrakis[p-chlorophenyl] borate (KTpClPB) is shown to improve potentiometric anion selectivity, suggesting that the palladium complex may operate as a partially charged carrier-type ionophore within the polymer membrane phase. The reaction mechanism is discussed with respect to UV-Vis and IR spectroscopy. Application of the electrode to the potentiometric titration of thiocyanate ion with silver nitrate is reported.