• Title/Summary/Keyword: polyurethane

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Removal of VOC compounds in the vent of a pharmaceutical plant using a pilot-scale biofilter (Pilot-scale 바이오필터를 이용한 제약공정 배출가스의 처리)

  • Ryu, Hee-Wook;Lee, Tae-Ho;Park, Chang-Ho
    • KSBB Journal
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    • v.23 no.6
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    • pp.470-473
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    • 2008
  • A pilot-plant biofilter ($1750\;m\;W{\times}2750\;mm\;L{\times}2000\;mm\;H$) packed with polyurethane foam ($20\;m\;W{\times}20\;mm\;L{\times}20\;mm\;H$) was installed in an pharmaceutical plant emitting gas streams containing n-hexane and alcohols. The biofilter was successfully operated for 74 days under highly fluctuating incoming concentrations at a residence time of 12.8-24.8 sec. Alcohols and n-hexane were removed by more than 90% from 5 and 20 days after start up, respectively. Malodor was also removed more than 95% from 20 days after start up.

The Preparation and Property of Carbon Foams from Carbon Black Embedded Pitch Using PU Template (카본블랙이 내첨된 핏치로부터 폴리우레탄 조공제를 이용한 탄소 폼의 제조 및 특성)

  • Lee, Sangmin;Kim, Ji-Hyun;Jeong, Euigyung;Lee, Young-Seak
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.268-273
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    • 2016
  • To improve mechanical strength of carbon foams, the carbon black (CB) added carbon foams were fabricated by impregnating different contents of carbon black (CB) and mesophase pitch using polyvinyl alcohol (PVA) solution into polyurethane foam and being followed by heat treatment. The cell wall-thicknesses of carbon foams were controlled by adding amounts of CB, and it was confirmed that the compressive strength of carbon foams was increased as increasing cell wall-thickness. The compressive strength had the highest value of $0.22{\pm}0.05MPa$ with the highest bulk density of $0.44g/cm^3$ when adding 5 wt% CB in carbon foam. However, the thermal conductivity was decreased by adding CB in carbon foam. The results indicated that the thermal conductivities of carbon foams were reduced by increased interlayer spacing ($d_{002}$) with the addition of CB in carbon foams.

Synthesis of Bishydroxyethyl Ether of Bisphenol A(BHE-BPA) Through the Depolymerization of Polycarbonate (폴리카보네이트 해중합을 이용한 Bisphenol A계 Bishydroxyethyl Ether 화합물 생성 특성)

  • Heo, Miseon;Kim, Beomsik;Park, Youin;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.164-171
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    • 2010
  • Recently, the waste of Polycarbonate(PC) is increase with the increase in demand of a polycarbonate. It is concerned with producing a new material and diol monomer, bishydroxyethyl ether of bisphenol A(BHE-BPA) through depolymerization of the polycarbonate waste at recycling. BHE-BPA can be used as a good raw material for the synthesis of polycarbonate type polyurethane. PC particles were depolymerized with base-catalyst NaOH, solvent EG, and ethylene carbonate(EC) was formed during the PC depolymerziation. EC was added to promote the conversion from bispenol-A to BHE-BPA. The characteristics of depolymeraion of polycarbonate as well as conversion of bispenol-A to BHE-BPA were investigated. BHE-BPA yield of 92% was obtained at temperature $220^{\circ}C$, 10% catalyst/PC mole ratio, 20 mmol of EC. BHE-BPA purity of better than 99% was achieved by crystallization of BHE-BPA.

On the Leakage Safety Analysis of Membrane LNG Storage Tank With Thermal Resistance Effects (열저항 효과를 고려한 멤브레인식 LNG 저장탱크의 누설 안전성에 관한 연구)

  • Kim C.K.;Cho S.H.;Suh H.S.;Hong S.H.;Lee S.R.;Kim Y.G.;Kwon B.K.
    • Journal of the Korean Institute of Gas
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    • v.8 no.4 s.25
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    • pp.1-7
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    • 2004
  • In this paper, the FE analysis has been presented for the leakage safety of the membrane LNG storage tank based on the thermal resistance effects between the insulation panel and prestressed concrete structure. The FEM calculated results show that the leakage safety of plywood and polyurethane materials does not guarantee any more due to a strength failure of the insulation structure. But the PC structure of outer tank may delay leaked LNG of 10 days even though the inner tank and insulation structure are simultaneously failed. This means that the membrane LNG storage tank may be safe because of the stiffness of the outer tank.

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Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum (재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구)

  • Ha, Joo-Yeon;Shin, Hyun-Gyoo;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.431-437
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    • 2019
  • The purpose of this study is to develop an organic-inorganic hybrid insulation materials which has an economic feasibility of organic level and excellent adiabatic performance and fire stability by impregnating organic materials with inorganic binder solutions. The organic base was commercial polyurethane sponge, and the inorganic binder slurry was prepared by mixing water and additives into recycled gypsum byproducts. As a result of evaluation of the developed materials, it was confirmed that it not only has excellent insulation performance of a thermal conductivity of 0.051 W/mK or less but also it is a semi-non-combustible materials specified in the Ministry of Land, Infrastructure and Transport Notice No. 2015-744. The developed materials can also be controlled for thermal conductivity and flame retardance according to density control during manufacturing process, and thus it can be applied to various insulation materials.

The Effects of Kaolin Addition on the Properties of Reticulated Porous Diatomite-kaolin Composites (고령토의 첨가가 3차원 망상 구조를 가지는 다공성 규조토-고령토 복합재의 기본 특성에 미치는 영향)

  • Lee, Chae-Young;Lee, Sujin;Ha, Jang-Hoon;Lee, Jongman;Song, In-Hyuck;Moon, Kyoung-Seok
    • Journal of Powder Materials
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    • v.27 no.4
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    • pp.325-332
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    • 2020
  • In this study, the effects of kaolin addition on the properties of reticulated porous diatomite-kaolin composites are investigated. A reticulated porous diatomite-kaolin composite is prepared using the replica template method. The microstructure and pore characteristics of the reticulated porous diatomite-kaolin composites are analyzed by controlling the PPI value (45, 60, and 80 PPI) of the polyurethane foam (which are used as the polymer template), the ball-milling time (8 and 24 h), and the amount of kaolin (0-50 wt. %). The average pore size decreases as the amount of kaolin increases in the reticulated porous diatomite-kaolin composite. As the amount of kaolin increases, it can be determined that the amount of inter-connected pore channels is reduced because the plate-shaped kaolin particles connect the gaps between irregular diatomite particles. Consequently, a higher kaolin percentage affects the overall mechanical properties by improving the pore channel connectivity. The effect of kaolin addition on the basic properties of the reticulated porous diatomite-kaolin composite is further discussed with characterization data such as pore size distribution, scanning electron microscopy images, and compressive strength.

Study on the Applicability of the Air Cushion Material for Impact Relief through Thermal Bonding of High Strength Fabrics (고강력 직물의 열융착 라미네이팅을 통한 충격 완화용 에어쿠션 소재로의 적용 가능성 검토 연구)

  • Kim, Ji Yeon;Kim, Hun Min;Min, Mun Hong
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.176-183
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    • 2020
  • In order to study wearable air cushion materials capable of responding to massive impact in high-altitude fall situation, high tenacity woven fabrics were bonded by heat only depending on various type of thermoplastic films and then mechanical properties were measured. Tensile strength, elongation, and 100% modulus measurement results for 4 types of films show that TPU-2 has higher impact resistance and easier expansion than PET-1. After thermal bonding, the combination with the highest tensile strength was a material with a TPU-2 film for nylon and a PET-2 film for PET, so there was a difference by type of fabric. The tear strength of the bonded materials were increased compared to the fabric alone, which shows that durability against damage such as tearing can be obtained through film adhesion. All of the peel strengths exceeded the values required by automobile airbags by about 5 times, and the TPU-2 bonded fabric showed the highest value. The air permeability was 0 L/dm2 /min. For both the film and the bonded material, which means tightness between the fabric and the film through thermal bonding. It is expected to be applied as a wearable air cushion material by achieving a level of mechanical properties similar to or superior to that of automobile airbags through the method of bonding film and fabric by thermal bonding.

A Characteristic Study of Inorganic Insulation Using Balloon Pearlite (발룬 펄라이트를 사용한 무기단열재의 특성 연구)

  • Jeon, Chanki;Park, Jongpil;Chung, Hoon;Lee, Jaeseong;Shim, jaeyeong
    • Journal of the Society of Disaster Information
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    • v.12 no.3
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    • pp.292-299
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    • 2016
  • The insulation in buildings is very important. Insulation used in the building is largely divided into organic and inorganic insulation by its insulation material. Organic insulations material which are made of styrofoam or polyurethane are extremely vulnerable to fire. On the other hand, inorganic insulation such as mineral-wool and glass-wool are very week with moisture while they are non-flammable so that its usage is very limited. In this study, inorganic heat insulating material developed and the properties of thermal conductivity evaluated. The thermal conductivity and the water absorption of the sample in less than 50mm thickness of the board is less than 0.05W/mk, 3.0%. Bending strength and the water repellency is more than $25N/cm^2$, 98%.

Effects of the Mechanical Stretch on Aligned Multi-Layered Nanofibrous Scaffolds Seeded with Smooth Muscle Cells (기계적 자극이 다층 구조의 나노파이버 지지체의 평활근 세포에 미치는 영향)

  • Shin, Ji-Won;Kim, Dong-Hwa;Heo, Su-Jin;Kim, Su-Hyang;Kim, Young-Jick;Shin, Jung-Woog
    • Journal of Biomedical Engineering Research
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    • v.29 no.1
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    • pp.52-58
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    • 2008
  • The object of this study is to investigate the effects of intermittent cyclic stretching on the smooth muscle cells (SMCs) seeded onto aligned multi-layered fibrous scaffold. To make multi-layered fibrous scaffold, polyurethane (PU) and poly(ethylene oxide) (PEO) were electrospun alternatively, then were immersed into distilled water to extract PEO. Various types of scaffolds were fabricated depending on fiber directions, i.e., aligned or randomly oriented. The direction of stretching was either parallel or vertical to the fiber direction for the aligned scaffolds. The stretching was also applied to the randomly aligned scaffolds. The duration of stretching was 2 min with 15 min resting period. During the stretching, the maximum and minimum strain was adjusted to be 10 and 7%, respectively with the frequency of 1 Hz. The bioactivities of cells on the scaffolds were assessed by quantifying DNA, collagen, and glycosaminoglycan (GAG) levels. And the cell morphology was observed by staining F-actin. SMCs under parallel stretching to the fiber direction responded more positively than those in other conditions. From the results, we could explain the morphological effect of a substrate on cellular activities. In addition the synergistic effects of substrate and mechanical stimuli effects were confirmed.

Morphology Formation and Application of Interpenetrating Polymer Network (IPN) Materials (Interpenetrating Polymer Network(IPN)의 모폴로지 형성과 그 응용)

  • Kim, Sung-Chul
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.1-7
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    • 2005
  • Interpenetrating polymer network (PN) is a mixture of network polymers. The characteristics of IPN material is the control of morphology during the IPN synthesis. By controlling the relative kinetics of chemical reaction (as well as gellation) and phase separation, the morphology of IPN can be controlled to obtain materials with nano-scale domain and also the co-continuous phase. Other important advantage is the fact that the morphology is permanent due to the presence of the physical interlocking between the networks. The combination of hydrophilic polyurethane and hydrophobic polystyrene in IPN form provides enhanced blood compatibility due to the co-existence of the hydrophilic and hydrophobic domains in nano-scale on the surface. The reaction temperature, reaction pressure and the degree of crosslinking were varied during the IPN synthesis and the morphology and blood compatibility of the resulting IPN materials were studied.