• 공업화학
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• 제10권8호
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• pp.1136-1140
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• 1999

폴리아마이드6(PA6)와 무수말레산이 그라프트된 폴리프로필렌(PP-g-MA)의 용융혼합된 블렌드계를 제조하고, 이 블렌드계의 인장, 굴곡, 충격, 동적기계적열 특성 및 상구조의 변화를 조사하였다. 인장강도와 인장탄성율은 두 조성물의 혼합에 따른 상승효과가 나타났고, 굴곡특성의 경우는 두 조성물의 산술평균값을 유지함을 알 수 있었다. 그리고 충격강도의 경우는 PA6/PP-g-MA 50/50 wt % 조성에서 최대값을 보였다. Tan ${\delta}$결과로부터, 두 조성물간의 반응에 의해 혼화성이 증가되었음을 확인하였다. 또한 상구조와 충격강도의 결과로부터, 본 블렌드계는 PA6 매트릭스에 PP-g-MA가 $2{\mu}m$정도 크기로 고르게 분산되어진 경우에 우수한 내충격성을 갖음을 알 수 있었다.

• Rapid Communication in Photoscience
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• 제1권2호
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• pp.27-29
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• 2012

Noble diamine monomers containing thiophene moiety were prepared, such as 2,5'''-diamino-2, 2':5', 2'':5'', 2'''-quaterthiophene (4TDA) and 2, 5'''''-diamino-3'', 4'''-dihexyl-2,2':5', 2'':5'', 2''':5''', 2'''':5'''', 2'''''-sexithiophene (6TDA). Then, these monomers were utilized to prepare polyimides with 3,6-diphenylpromellitic dianhydride (DPPMDA), 3,6-di(4'-trifluoro-methylphenyl) pyromellitic dianhydride (6FPMDA) or 3,6-di(3',5'-bis (trifluoromethyl)phenyl) pyromellitic dianhydride (12FPMDA) via a conventional two-step process. The polyimides were characterized by FT-IR, TGA and DSC, and then subjected CV, UV-vis and PL measurements. The polyimides containing thiophene moiety exhibited high glass transition temperatures ($280{\sim}310^{\circ}C$) and excellent thermal stability (> $420^{\circ}C$) in air as well as green emission (535~586 nm).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.266-266
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• 2013

We show a set-up of poly (4,4'-aminotriphenylene hexafluoroisopropylidenediphthalimide) (6F-TPA PI)/Al sample in which holes are injected by photoelectron emission process instead of direct charge carrier injection via metal electrode. In this process, an irreversible electrical phase transition of 6F-TPA PI is found in contrast to the Al/6F-TPA PI/Al structure, leading to a write-once-readmany behavior. The photoelectron spectroscopy results measured before and after the switching process revealed that the irreversible electrical phase transition of 6F-TPA PI is attributed to the chemical modification of the carbonyl group in phthalimide moiety.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권4호
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• pp.161-168
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• 2001

Organic thin film transitors(TFTs) are of interest for use in broad area electronic applications. For example, in active matrix liquid crystal displays(AMLCDs), organic TFTs would allow the use of inexpensive, light-weight, flexible, and mechanically rugged plastic substrates as an alternative to the glass substrates needed for commonly used hydrogenated amorphous silicon(a-Si:H). Recently pentacene TFTs with carrier field effect, mobility as large as 2 $cm^2V^{-1}s^{-1}$ have been reported for TFTs fabricated on silicon substrates, and it is higher than that of a-Si:H. But these TFTs are fabricated on silicon wafer and $SiO_2$ was used as a gate insulator. $SiO_2$ deposition process requires a high insulator which is polyimide and photo acryl. We investigated trasfer and output characteristics of the thin film transistors having active layer of pentacene. We calculated field effect mobility and on/off ratio from transfer characteristics of pentacene thin film transistor, and measured IR absorption spectrum of polymide used as the gate dielectric layer. It was found that using the photo acryl as a gate insulator, threshold voltage decreased from -12.5 V to -7 V, field effect mobility increased from 0.012 $cm^2V^{-1}s^{-1}$ to 0.039 $cm^2V^{-1}s^{-1}$ , and on/off current ratio increased from $10^5\;to\;10^6$. It seems that TFTs using photo acryl gate insulator is apt to form channel than TFTs using polyimide gate insulator.

• 폴리머
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• 제32권2호
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• pp.125-130
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• 2008

A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

• 한국진공학회지
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• 제6권3호
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• pp.187-193
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• 1997

상온에서 polyimide 위에 증착한 Cu의 초기성장 과정과 Cu/polyimide의 계면의 형 태에 관하여 XPS를 이용하여 관찰하였다. Polyimide 위에 Cu가 증착됨에 따라, 초기단계에 는 강한 결합의 Cu-N-O complex가 주가 되어 Cu/polyimide 계명을 형성하고, Cu의 증착 두께가 증가함에 따라, 약한 결합의 Cu산화물에서 서서히 metallic Cu로서 성장하는 것을 볼 수 있었다. 이상이 결과들을 통해, Cu/polyimide의 계면은 Cu-N-O complex와 Cu산화물 이 혼합되어 있는 형태이며 polyimide 표면에 가까울수록 Cu-N-O complex가 주가 되고, Cu쪽에 가까울수록 Cu산화물이 주가 되는 형태를 이루고 있다는 것을 알 수 있었다.

• 한국전기전자재료학회논문지
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• 제11권4호
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• pp.306-313
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• 1998

To elucidate the liquid crystal(LC) molecules alignment mechanism, it is important to determine the molecular orientation of the rubbed polymer surface molecules that directly contact with LC molecules. In this work, the molecular orientation on a rubbed surface of polyimide (SE-3310, Nissan) film has been studied by polarized FTIR absorption spectroscopy. It has been found that molecular chain on the rubbed surface of polymide film are oriented along the rubbing direction and are tilted up on an average by 5.0$^{\circ}$. In the SHG(Second Harmonic Generation) measurement, the pretilt angle of molecular chain on the poylmide fim was 4.6$^{\circ}$ fro, the surface plane. And the pedit angle of liquid crystal (ZLI-2293, Merck) molecules measured by crystal rotation method was 5.4$^{\circ}$in the same rubbing condition.

• Journal of Photoscience
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• 제6권3호
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• pp.109-115
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• 1999

Intense excimer laser irradiation of polymer films results in expansion and the following contraction , recovering ithe initial flat surface. The morphological dynamics is meausred directly by nanosecond time-resolved interferometry for polystyrene(PS), polyurethane, and polyimide films. The expansion proceeds with a speed of a few nm/ns , while the contraction depends upon the polymer ; very low contraction for PS, rapid 2 component shrinking for polyurethane, and rapid monotonous decay for polymide. These characteristic behavior are considered from viewpoints of interpenetrating structures of polymers, glass-rubber phase transitioni, thermal diffusion, and photothermal mechanism.

• Journal of Photoscience
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• 제6권3호
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• pp.103-108
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• 1999

We present recent results on ablation mechanism, single-pulse laser micropatterning , pulsed-laser deposition(PLD) and particulates formation accompanying laser ablation, with special emplasis on polymers, in particular polymide, (PI), and polytetrafluoroethylene, (PTFE). Ablation of polymers is described on the basis of photothermal bond breaking within the bulk material. Here, we assume a first order chemical reaction, which can be described by an Arrhenius law. Ablation starts when the density of broken bonds at the surface reaches a certain critical value. Single-pulse laser ablation of polyimide shows a clear-length dependence of the threshold fluence. This experimental result strongly supports a thermal ablation model. We discuss the various possibilities and drawbacks of PLD and describe the morphology, physical properties and applications of PTFE films.

• 한국재료학회지
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• 제9권4호
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• pp.355-361
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• 1999

가용성 폴리이마드 주쇄에 Disperse-Red 1 크로모포를 공유결합 시킨 옆사술계 비선형 전기광학 고분자를 합성하였다. 합성된 고분자의 유리전이온도 빛 열분해온도 는 각각 $225^{\circ}C, 310^{\circ}C$이었으며 광통신 파장에서 광학적으로 투명하였다. $100 V/\mu\textrm{m}$의 전기장으로 폴링했을 때, 유전상수는 10 kHz에서 3.37이며, 파장 1300 nm에서, 굴절률은 $n_{TE} 및 n_{TM}$ 모두 1.631로같았으며, 전기광학계수는 4.6 ~ 9.2 pm/V이였다. 폴링한 후 $180^{\circ}C$에서 1시간 동안 유지시킨 시편의 전기광학계수의 값은 감소되지 않 았으며, 장기적인 관점에서 $90^{\circ}C$에서 500 시간 동안 유지시킨 시편의 전기광학계수도 변함이 없었다.