Laser Ablation : Fundamentals and applications in Micropatterning and Thin Film Formation

  • J. Heitz (Jonannes-Kepler-Universitat Linz) ;
  • D. Bauerle (Jonannes-Kepler-Universitat Linz) ;
  • E. Arenholz (Jonannes-Kepler-Universitat Linz) ;
  • N. Arnold (Jonannes-Kepler-Universitat Linz) ;
  • J.T. Dickinson (Washington State University)
  • Published : 1999.05.01

Abstract

We present recent results on ablation mechanism, single-pulse laser micropatterning , pulsed-laser deposition(PLD) and particulates formation accompanying laser ablation, with special emplasis on polymers, in particular polymide, (PI), and polytetrafluoroethylene, (PTFE). Ablation of polymers is described on the basis of photothermal bond breaking within the bulk material. Here, we assume a first order chemical reaction, which can be described by an Arrhenius law. Ablation starts when the density of broken bonds at the surface reaches a certain critical value. Single-pulse laser ablation of polyimide shows a clear-length dependence of the threshold fluence. This experimental result strongly supports a thermal ablation model. We discuss the various possibilities and drawbacks of PLD and describe the morphology, physical properties and applications of PTFE films.

Keywords

References

  1. Laser Processing and Chemistry Bauerle, D.
  2. Appl. Phys. A v.68 Model for laser-induced thermal degradation and ablation of polymers Arnold, N.;N. Bityurin
  3. Appl. Phys. Lett. v.73 Single-pulse ultraviolet laser-induced surface modification and ablation of polyimide Piglmayer, K.;E. Arenholz;C. Ortwein;N. Arnold;D. Bauerle
  4. Appl. Surf. Sci. v.125 Pulsed-laser deposition of crystalline Teflon (PTFE) films Li, S. T.;E. Arenholz;J. Heitz;D. Bauerle
  5. Appl. Phys. Lett. v.73 Charge stability of pulsed-laser deposited polytetrafluoroethylene film electrets Schwodiauer, R.;S. Bauer-Gogonea;S. Bauer;J. Heitz;E. Arenholz;D. Bauerle
  6. Appl. Spec. v.51 Characterization of particulates accompanying laser ablation of NaNo3 Webb, R. L.;J. T. Dickinson;G. J. Exarhos
  7. Appl. Phys. A v.68 Characterization of particulates accompanying laser ablation of pressed polytetrafluorethylene (PTFE) targets Heitz, J.;T. Dickinson
  8. Appl. Phys. A v.56 Threshold behavior in polyimide photoablation: single-shot rate measurements and surface-temperature modeling Kuper, S.;J. Brannon;K. Brannon
  9. Nucl. Instrum. Meth. B v.122 UV-laser ablation of polyimide: from long to ultra-short laser pulses Luk'yanchuk, B.;N. Bityurin;M. Himmelbauer;N. Arnold
  10. Proc. SPIE v.2802 Photophysical mechanism of UV-laser action: the role of stress transients Bityurin, N.;A. Malyshev;B. Luk'yanchuk;S. Anisimov;D. Bauerle
  11. Appl. Phys. A v.63 Single-shot UV-laser ablation of polyimide with variable pulse lengths Himmelbauer, M.;E. Arenholz;D. Bauerle
  12. Appl. Phys. Lett. v.43 Direct etching of polymeric materials using a XeCl laser Andrew, J. E.;P. E. Dyer;D. Forster;P. H. Key
  13. Appl. Phys. v.58 Excimer laser etching of polyimide Brannon, J. H.;J. R. Lankard;A. I. Baise;F. Burns;J. Kaufman
  14. J. Appl. Phys. v.57 Excimer laser ablation and thermal coupling efficiency to polymer films Dyer, P. E.;J. Sidhu
  15. Appl. Phys. A v.68 Uniform target ablation in pulsed-laser deposition Arnold, N.;D. Bauerle
  16. J. Polym. Sci. B: Polym. Phys. Pulsed-Laser-Deposited and Plasma-Polymerized Polytetrafluoroethylene (PTFE)-Like Thin Films: A Comparative Study on PTFE-Specific Properties Schwodiauer, R.;J. Heitz;E. Arenholz;S. Bauer-Gogonea;S. Baurer;W. Wirges
  17. Appl. Phys. B v.52 Time-resolved UV absorption of polyimied Frisoli, J. K.;Y. Hefetz;T. F. Deutsch