• Title/Summary/Keyword: polymeric material

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New polymeric host material for efficient organic electro phosphorescent devices

  • Jung, Choong-Hwa;Park, Moo-Jin;Eom, Jae-Hoon;Shim, Hong-Ku;Lee, Seong-Taek;Yang, Nam-Choul;Liand, Duan;Suh, Min-Chul;Chin, Byung-Doo;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.843-845
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    • 2009
  • A polymeric host for triplet emitters composed of N-alkylcarbazole and tetramethylbenzene units was successfully synthesized. Efficient energy transfer was observed between this polymeric host and green phosphorescent dyes. The device fabricated using 5 wt% green 1 in the polymeric host as the emitting layer showed the best performance. Thin films of this host-guest system, exhibiting clear stripe patterns could be prepared through the LITI process. The patterned films were then used to fabricate electrophosphorescent devices, which show performance characteristics similar to those of spin-coated devices. The new host material is a good candidate to be used in polymer-based full-color electrophosphorescent light-emitting displays.

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Elastic-Damage Constitutive Model for Nonlinear Tensile Behavior of Polymeric Foam (폴리머 폼의 비선형 인장거동을 모사하기 위한 기공이 고려된 손상 탄성 구성방정식)

  • Kwon, Sun-Beom;Lee, Jae-Myung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.4
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    • pp.191-197
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    • 2018
  • This paper details the development of an isotropic elastic-damage constitutive model for polymeric foam based on irreversible thermodynamics to consider the growth and coalescence of voids. The constitutive equations describe the material behavior sustaining unilateral damage. To facilitate finite element analysis, the material properties for specific types of polymeric foams are applied to the developed model; the model is then implemented in ABAQUS as a user-defined material subroutine. To validate the developed damage model, the simulated results are compared to the results of a series of tensile tests on various polymeric foams. The proposed damage model can be utilized to further research on continuum damage mechanics and finite element analysis of polymeric foams in computational engineering.

A Study on Combustion Gases Toxicity Evaluation of Polymeric Material (고분자재료의 연소가스 독성평가에 관한 연구)

  • 박영근
    • Fire Science and Engineering
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    • v.15 no.3
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    • pp.7-13
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    • 2001
  • In this paper, we had analyzed comsbustion gases according to pyrolysis $600^{\circ}c$, $800^{\circ}c$ and $1000^{\circ}c$ for polymeric material using a GASTEC colorimetric gas detector tube in order to combustion gases toxicity evaluation for flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam of polymeric material. As a result, comsbustion gases producted from small specimens of polymeric material had reached fatal to man at a 30 minute exposure time that had possesed toxicity index. Toxicity index at pyrolysis $800^{\circ}c$ of flexible polyvinyl chloride was 31.74. Flexible polyvinyl chloride was the highest toxicity index of flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam. The comsbustion gases producted commonly no concern with pyrolysis temperature had analyzed carbon dioxide($CO_2$) and carbon monoxide(CO). Toxicity index had investigated differently according to pyrolysis temperature even a similar materal.

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The Comparison of EPDM and Silicone in Housing Materials of Polymeric Suspension Insulators (EPDM 및 실리콘 재질의 폴리머현수애자의 특성 비교)

  • Lee, Byung-Sung;Lee, Jae-Bong;Song, Il-Keun;Han, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05e
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    • pp.6-10
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    • 2003
  • In our country, the housing materials of polymeric outdoor insulators have mainly been used EPDM or silicone rubber. EPDM housing materials had been widely used in the field for the first time. The reason why silicone has the high cost of production. But recently, most of the manufacturers that newly developed polymeric insulators make its choice of silicone housing. EPDM showed a good resistance to tracking. We compared the various characteristics for EPDM and silicone insulators that have similar type and design. Silicone insulators have more performance in flashover voltage test and leakage current measurement because of a good water repellent than EPDM ones. Also, the property of EPDM compared with silicone insulators greatly decreased after aging test in combined acceleration ageing facilities for 1000 hours.

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Measurement of Material Property of Thin Film and Prediction of Residual Stress using Laser Scanning Method (레이저 주사법을 이용한 박막 물성 측정 및 잔류응력 예측)

  • Lee, Sang-Soon
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.49-53
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    • 2004
  • Polymeric materials are widely used in the electronic industry as a common dielectric material or adhesive. The polymeric layer coated on Si substrate can be subjected to thermal stresses due to difference in thermal expansion coefficients. The mismatch in thermal properties between the polymeric layer and the substrate results in significant residual stresses. In this study, the thermal deformation is measured by a curvature measurement method using laser scanning, and the elastic modulus is calculated by an analytic model.

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Study on a design and characteristics tests of polymeric insulators for subway (지하철 고분자 지지애자의 설계 및 특성 평가)

  • Han, Se-Won;Cho, Han-Goo;Song, Hong-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.514-517
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    • 2003
  • Polymeric suspended insulators for subway and electrical track line had been designed and manufactured. The main elements to design polymeric insulators were the insulation ability and the optimal structure. To get the insulation ability, electrical and mechanical tests according to standards had done on housing rubbers and FRP cores and selected the sample with best properties as a insulator. The insulator shape and fitting parts with minimum electrical stress was simulated by FEM electrical field analysis program. The manufactured insulator set had been tested and estimated the electrical and mechanical according to ES and KS, and showed good characteristics in these tests.

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Physico-chemical Behavior of Polymeric Hydrogels

  • Soh, Dae-Wha;Mun, G.A.;Nam, Irina;Nurkeeva, Z.S.;Shaikhutdinov, E.M.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.592-595
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    • 2002
  • New polymeric hydrogels based on vinyl ethers have been synthesized by the ${\gamma}$-initiated polymerization method. Their physical chemistry and physical mechanical properities have been studied. It has been shown that structure and swelling behavior of the hydrogels can be regulated by the changing of synthesis conditions nature of monomers. Novel stimuli-sensitive polymers have been synthesized by the varying of macrochains hydrophilic-hydrophobic balance. The some biomedical aspects of application of hydrogels in capacity of drain aging polymeric materials in ophthalmology surgery, implants in plastic surgery as well as drug delivery systems have been investigated.

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Analysis of Electric Field Distribution of High Voltage Polymeric Bushing with Structure (초고압 폴리머 부싱의 구조에 따른 전계분포 해석)

  • Cho, Han-Goo;Yoo, Dae-Hoon;Kang, Hyung-Kyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.489-490
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    • 2008
  • This paper describes the analysis of electric field distribution of high voltage polymeric bushing with structure. The high voltage bushing consists of FRP tube and housing made of LSR. The field control can be achieved by means of the design of such internal field shaper and top corona ring as grading electrodes. In accordance, the optimized design uses both internal and external elements for electric stress grading at critical parts of the bushing. Maxwell 2D simulator based on the boundary element method was also introduced in order to verify the reliability of the polymeric bushing.

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A Study on Countermeasures and Tracking Phenomena of Polymer (절연용(絶緣用) 고분자재료(高分子材料)의 Tracking현상(現象)과 방지대책(防止對策)에 관한 연구(硏究))

  • Jeon, Young -Jun;Seo, Dong-Chul;Yoo, Jae-Il;Kim, Jin-Woo;Jung, Woo-Kyo;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1235-1238
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    • 1995
  • Electrical property of polymeric insulating plays a key role in the trend of making power apparatus high voltage, and reliability and safety of apparatus in the long term depend on it. There is a recent trend of applying polymeric material to insulating material for outdoor, and particularly it is expected that it may be used partly as a pin insulator. Using as an alternate of insulating material for outdoor, however, it has still many problems to be solved in the field of material such as resistances of environment and tracking. It has been given attention to that the silicon rubbers and the epoxy have recently been used. but the the reliability in the viewpoint of material property becomes an issue. The polymeric materials such as EPDM, Epoxy and PVC have also been used as an insulating materials for outdoor. In this point of view, we studied each tracking phenomenon with test material such as rubber for pin, PVC for powercable used as an insulating material for outdoor, and Epoxy etc. The characteristics of anti tracking shows EPDM>Epoxy>PVC in order in the results. We also know that there is an close relationship between properties of tracking and thermegravimetry.

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Study on UV degradation in Polymeric Insulating Materials for Use in Outdoor Insulators by Corona-Charging (코로나 대전을 통한 옥외용 고분자 절연재료의 자외선 열화특성 연구)

  • Youn, Bok-Hee;An, Jong-Sik;Lee, Sang-Yong;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.106-109
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    • 2001
  • In this paper, we have investigated the degradation of shed materials of outdoor insulators by UV-radiation by using corona-charging and XPS analysis. The accumulated charges on polymeric surface having intrinsic hydrophobic property have a negative impact on retaining its hydrophobicity. Therefore, shorter decay times of surface charges are preferred. The surface voltage decay on UV-treated silicone rubber and EPDM show a different decay trend with UV treated time. From the XPS analysis, the oxidized groups of silica-like structure in silicone rubber increase with UV treatment time. For EPDM, the oxidized carbon groups of C=O, O=C-O increase as elapse of UV radiation time. These oxidized surface for each material have different electrostatic characteristics, so deposited charges may be expected to have different impacts on their surface hydrophobicity. The degradation mechanism based on our results is discussed.

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