• Title/Summary/Keyword: polymer-LED

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Flexural Strength of Polysiloxane-Derived Strontium-Doped SiOC Ceramics

  • Eom, Jung-Hye;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.61-65
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    • 2015
  • The effect of Sr addition on the flexural strength of bulk SiOC ceramics was investigated in polymer-derived SiOC ceramics prepared by conventional hot pressing. Crack-free, dense SiOC discs with a 30 mm diameter were successfully fabricated from commercially available polysiloxane with 1 mol% strontium isopropoxide derived Sr as an additive. Agglomerates formed after the pyrolysis of polysiloxane led to the formation of domain-like structures. The flexural strength of bulk SiOC was strongly dependent on the domain size formed and Sr addition. Both the minimization of the agglomerate size in the starting powders by milling after pyrolysis and the addition of Sr, which reinforces the SiOC structure, are efficient ways to improve the flexural strength of bulk SiOC ceramics. The typical flexural strength of bulk Sr-doped SiOC ceramics fabricated from submicron-sized SiOC powders was ~209 MPa.

Color Tuning of PLED based on Poly(fluorene)s

  • Lee, Jeong-Ik;Do, Lee-Mi;Chu, Hye-Yong;Kim, Sung-Hyun;Zyung, Tae-Hyoung
    • Journal of Information Display
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    • v.6 no.1
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    • pp.33-36
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    • 2005
  • To obtain various colors from the blue emitting poly(fluorene)s, two different approaches are introduced. One is copolymerization with low band gap comonomers and the other is molecular doping with various dyes. As fast and efficient exciton migration and trapping and/or energy transfer between the chromorphoric segments or doped dyes in conjugated polymers can shift the emission to longer wavelengths, these phenomena can be utilized to obtain various colors from the intrinsically blue light emitting poly(fluorene)s.

A Study on the Sensor for Measuring Near-distance Variation by using Ultrasonic Transducer (초음파 트랜스듀서를 사용한 근접거리변동 측정용 센서개발에 관한 연구)

  • Yang, Yun-Suk;Shin, Young-Lok;Kim, Chul-Han;SaGong, Geon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.175-178
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    • 2000
  • In this study, the ultrasonic transducer was fabricated with piezoceramic-polymer 1-3 type composites. Pulse-echo response of that transducer in water was investigated with variable water-level. Output of LED was under the control of the signal, which was analyzerd by the self-made Electric Unit. This paper represents automatically water-detecting system with variable water level. There was in good agreement water level between the virtual level and output signal by using the self-made water-detecting system.

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Effect of Surface Modificaion on the Rheology and Property of CNTs/Epoxy Nanocomposites (표면 개질된 탄소나노튜브/에폭시 나노복합재료의 유변학적 거동과 물성)

  • Kim Jin Ah;Seong Dong Gi;Youn Jae Ryoun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.43-46
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    • 2004
  • Multi-walled carbon nanotubes (MWNTs) produced by chemical vapor deposition were treated with acidic solution for purification and oxidization of CNTs. The surface modification of the oxidized CNTs was achieved by amine treatment and oxygen plasma treatment. The functionalized CNTs were embedded in the epoxy resin by sonication method and the resulting composite was investigated by FESEM. Rheological and mechanical properties of nanocomposites were measured by AR2000 and Instron. The rheological properties and dispersion of modified CNTs/epoxy composites were improved as CNTs were modified, because the modification of CNTs led to a improvement interaction between the CNTs and the epoxy resin. In addition to this, mechanical properties are also improved because of the effective stress transfer between the CNTs and the polymer.

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Color tunable electroluminescence with polymer blends composed of PVK and copolymer containing SiPh-PPV and MEH-PPV unit

  • Oh, Gwang-Chae;Yun, Je-Jung;Park, Su-Mi;Son, Sung-Hee;Han, Eun-Mi;Jin, Sung-Ho;Gu, Hal-Bon;Choi, Hyun-Chual
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.736-739
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    • 2002
  • We report on white light emission from a light emitting diode(LED) prepared by blending a red emitting copolymer, m-SiPh PPV-co-MEH PPV, and a blue emitting polyvinylcarbazole (PVK). White light emission was realized when the weight ratio of the m-SiPh PPV-co-MEH PPV : PVK equals to 1 : 30, in which the commission Internationale de L'Eclairage coordinates were x=0.3266 and y=0.3438.

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A Study on the Synthesis and Mechanical Characteristics of NATM Resin (HATM 수지의 합성 및 기계적 특성에 관한 연구)

  • Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.22 no.4
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    • pp.355-361
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    • 2005
  • The physical characteristics of polyurethane were examined by SEM, FT-IR tensile strength and mole % [NCO/OH]. Growing concerns in the environment-friendly architecture and public works have led to the development of solvent-free formulations that can be cured and foamed in air. Compared with general packing materials, this resin is much stronger in intensity and much longer in durability. Polyurethane foam resins were mainly composed of polyol, MDI, silicone surfactant, fillers, catalyst and blowing agent. The rigid foam of polyurethane in mechanical characteristics were due to chain extender and the increase of mole % [NCO/OH]. The change in the microstructure of polyurethane should be taken into account when considering the process of construction and durability through the polyurethane polymer resin in lots of industries.

Infinite 1-D and 3-D Nets with Two Different Zinc and Terbium Coordination Polymers.

  • 민동원;이연경;이순원
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.31-31
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    • 2002
  • The hydrothermal reaction of Zn(NO₃)₂6H₂O with benzene-1,3-dicarboxylic acid (or isophthalic acid, 1,3-BDCH₂) and pyridine led to the formation of a 1-dimensional coordination polymer with the empirical formula of [Zn₄(1,3-BDC)₃(Py)₂(O/sup 2-/)] (1). On the other hand, the hydrothermal reaction of Tb(NO₃)₃5H₂O with benzene-1,3-dicarboxylic acid (or isophthalic acid, 1,3-BDCH₂) and pyridine gave a 3-D compound [Tb₃(1,3-BDC)₂(H₂O₃] (2). The structures of both compounds have been determined by X-ray diffraction. 1 crystallizes in the monoclinlc space group P2₁/n, a = 10.344(3) Å, b = 18.030(3) Å, c = 18.033(3) Å, = 90.46(2)°, V = 3363.1(13) ,ų, Z = 4. 2 crystallizes in the monoclinic space group C2/n, a = 22.253(5) Å, b = 18.672(4) Å, c = 11.5812 Å, = 101.40(2)°, V = 4717.3(21) ų, Z = 8.

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Preparation and characterization of polyethersulfone microfiltration membrane by 2-methoxy ethanol nonsolvent additive

  • Shin, Se-Jong;Kim, Hyung-Sik;Min, Byoung-Ryul
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.166-169
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    • 2004
  • Microfiltration membranes were prepared from aromatic polyethersulfone (PES) polymer, using aprotic solvent (N-methyl-2-pyrrolidone, NMP) and non-solvent additive (2-methoxy ethanol, 2-ME) by the phase inversion co-process of the vapor-induced phase inversion (VIPI) and the nonsolvent-induced phase inversion (NIPI). According to the change of the additive amount, the solvent amount and the relative humidity, membrane characterization was studied. The non-solvent additive in casting solution played an important role in membrane morphology. During the vapor-induced phase inversion, the relative humidity led to water sorption on the surface of casting dope at which pore formation was generated. The prepared membranes were characterized by scanning electron microscope observations, measurements of capillary flow porometer and pure water flux (PWP). Also the thermodynamic and kinetic properties of membrane-forming system were studied through coagulation value, light transmittance and viscosity.

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Simulation of injection-compression molding for thin and large battery housing

  • Kwon, Young Il;Lim, Eunju;Song, Young Seok
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1451-1457
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    • 2018
  • Injection compression molding (ICM) is an advantageous processing method for producing thin and large polymeric parts in a robust manner. In the current study, we employed the ICM process for an energy-related application, i.e., thin and large polymeric battery case. A mold for manufacturing the battery case was fabricated using injection molding. The filling behavior of molten polymer in the mold cavity was investigated experimentally. To provide an in-depth understanding of the ICM process, ICM and normal injection molding processes were compared numerically. It was found that the ICM had a relatively low filling pressure, which resulted in reduced shrinkage and warpage of the final products. Effect of the parting line gap on the ICM characteristics, such as filling pressure, clamping force, filling time, volumetric shrinkage, and warpage, was analyzed via numerical simulation. The smaller gap in the ICM parting line led to the better dimensional stability in the finished product. The ICM sample using a 0.1 mm gap showed a 76% reduction in the dimensional deflection compared with the normal injection molded part.

Water droplet behavior on a solid-infused surface cured with commercial Gentoo polymer (상용 Gentoo 폴리머가 경화된 고체주입표면에서 물방울 거동)

  • Hyeongwon Kim;Jeong-Hyun Kim
    • Journal of the Korean Society of Visualization
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    • v.22 no.1
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    • pp.61-67
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    • 2024
  • In this study, the behavior of water droplets on a solid-infused surface was evaluated by quantifying a water droplet's contact angle, sliding angle, and terminal velocity. The contact angle hysteresis and sliding angle of water on the solid-infused surface were measured to be lower than those of the hydrophobic PTFE surface. It led to the enhancement of the initiation of the water droplet's movement. When the capillary number was lower than Ca < 0.004, the terminal velocity of the water droplet on the solid-infused surface was higher than the PTFE surface due to the low contact line resistance. However, the transition of the droplet morphology from a hemispherical shape to a streamlined teardrop shape beyond Ca > 0.004 lost the effect of reducing frictional resistance on the solid-infused surface.