• 제목/요약/키워드: polymer modification

검색결과 478건 처리시간 0.033초

Regulation of precursor solution concentration for In-Zn oxide thin film transistors

  • Chen, Yanping;He, Zhongyuan;Li, Yaogang;Zhang, Qinghong;Hou, Chengyi;Wang, Hongzhi
    • Current Applied Physics
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    • 제18권11호
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    • pp.1300-1305
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    • 2018
  • The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

Temperature Dependence of Thermo-Mechanical Properties of Banana Fiber-Reinforced Polyester Composites

  • Shaktawat, Vinodini;Pothan, Laly A.;Saxena, N.S.;Sharma, Kananbala;Sharma, T.P.
    • Advanced Composite Materials
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    • 제17권1호
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    • pp.89-99
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    • 2008
  • Using a Dynamic Mechanical Analyzer (DMA), mechanical properties like modulus and phase transition temperature of polyester composites of banana fibers (treated and untreated) are measured simultaneously. The shifting of phase transition temperature is observed in some treatments. The performance of the composite depends to a large extent on the adhesion between polymer matrix and the reinforcement. This is often achieved by surface modification of the matrix or the filler. Banana fiber was modified chemically to achieve improved interfacial interaction between the fiber and the polyester matrix. Various silanes and alkalies were used to modify the fiber surface. Chemical modification was found to have a profound effect on the fiber/matrix interaction, which is evident from the values of phase transition temperatures. Of the various chemical treatments, simple alkali treatment with 1% NaOH was found to be the most effective.

Characterization of Antibacterial Activity and Synergistic Effect of Cationic Antibacterial Peptide-resin Conjugates

  • Kim, Jeong-Min;Jang, Su-Jung;Yang, Mi-Hwa;Cho, Hyeong-Jin;Lee, Keun-Hyeung
    • Bulletin of the Korean Chemical Society
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    • 제32권11호
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    • pp.3928-3932
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    • 2011
  • We synthesized peptide-resin conjugates (1 and 2) by immobilizing ${\beta}$-sheet antibacterial peptide and ${\alpha}$ helical antibacterial peptide on PEG-PS resin, respectively. Conjugate 1 showed considerable antibacterial activity in various conditions, whereas conjugate 2 did not exhibit antibacterial activity. The growths of various bacteria were inhibited by conjugate 1 even at lower concentrations than MIC. Conjugate 1 killed bacteria at MIC and had a potent synergistic effect with current antibacterial agents such as vancomycin and tetracycline, respectively. Overall results indicate that polymer surface modification using antibacterial ${\beta}$ sheet peptide is a powerful way to prevent microbial contamination on polymer surfaces.

Chemical Modification of Chitosan as Gene Carriers In Vitro and In Vivo

  • Kim, Tae-Hee;Jin, Hua;Kim, Hyun-Woo;Cho, Myung-Haing;Nah, Jae-Woon;Cho, Chong-Su
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.178-178
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    • 2006
  • Chitosan has been investigated as a non-viral vector because it has several advantages such as biocompatibility, biodegradability and low toxicity with high cationic potential. However, low specificity and low transfection efficiency of chitosan as a DNA carrier need to be overcome for clinical trials. In this study, chemical modification for enhancement of cell specificity and transfection efficiency was investigated. Also, the chitosan derivative formulations in vivo were included.

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Preparation and Physical Properties of Poly(lactic acid) Bio-Composites using Surface Modified Microfibriled Celluloses

  • Yeo, Jun-Seok;Seong, Dong-Wook;Hwang, Seok-Ho
    • Elastomers and Composites
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    • 제50권1호
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    • pp.62-67
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    • 2015
  • The surface modification of microfibriled cellulose (MFC) was carried out through the hydrolysis-condensation reaction using (3-aminopropyl)triethoxysilane (APS) and 3-glycidyloxypropyltriethoxysilane (GPS) and then the modified cellulose was compounded with bio-degradable poly(lactic acid) (PLA). Also, pristine MFC was compounded with PLA as a control groups. The confirmation of surface modification for the pristine MFC was characterized by FT-IR and SEM/EDX. The thermal and mechanical properties of the PLA/MFC composites depended on the content of MFC and the type of silane coupling agents. From the thermal, morphological and mechanical behaviors of the PLA/MFC composites, it was found that GPS-MFC was more successful to improve the interface adhesion between PLA matrix and the surface of MFC than that of APS-MFC.

Preparation of PET Nanocomposites: Dispersion of Nanoparticles and Thermal Properties

  • Her, Ki-Young;Kim, Dae-Heum;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • 제9권4호
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    • pp.71-73
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    • 2008
  • The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.

Performance Improvement of Polymer Light Emitting Diodes by Insertion of a Silane Layer

  • Lee, Jun-Yeob
    • Journal of Information Display
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    • 제8권3호
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    • pp.1-4
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    • 2007
  • The influence of a silane layer on the performances of polymer light emitting diode(pLED)s has been studied. Glycidoxypropyltrimethoxysilane(GPS) with an epoxy functional group was used as a surface modifier for ITO substrates. The GPS layer was inserted between an ITO and a poly(3,4)-ethylenedioxythiophene/polystyrenesulfonate(PEDOT) by wet process and the performances of PLEDs were investigated. The introduction of GPS layer increased the brightness and efficiency of PLEDs by 30%. In addition, the lifetime of PLEDs was also improved considerably by using GPS as a surface modifier.

콘크리트 보호용 그래핀/에폭시 도료개발을 위해 표면개질한 그래핀 나노플레이트의 유기용매 분산특성 (Dispersion Characteristics of Surface-Modified Graphene Nanoplate in Organic Solvent for Development of Graphene / Epoxy Paint to Protect Concrete)

  • 서원우;김규용;윤민호;이상규;황의철;손민재
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.244-245
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    • 2017
  • This study aims to develop high durability graphene / epoxy paint for durability improvement of construction structure. For the development of graphene / epoxy coatings, first, graphene must remain stable in the polymer. Second, the integrity of graphene and polymer should be ensured. Accordingly, in order to obtain dispersibility, surface modification of graphene nanoplate(GnP) with CH and COOH functional groups and its dispersibility in organic solvents were investigated. Also, Fourier Transform Infrared Spectroscopy(FT-IR) analysis and Atomic Force Microscope(AFM) analysis were performed to confirm whether the functional groups were synthesized by surface modification. As a result, FT-IR and AFM analysis did not confirm the surface modification, but GnP was found to be stable when dispersed in an organic solvent.

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