• Macromolecular Research
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• v.15 no.6
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• pp.491-497
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• 2007

NPT Monte Carlo simulations were performed to calculate the molecular properties of syndiotactic poly(vinyl chloride) (PVC) and syndiotactic poly(vinyl alcohol) (PVA) melts using the configurational bias Monte Carlo move, concerted rotation, reptation, and volume fluctuation. The density, mean square backbone end-to-end distance, mean square radius of gyration, fractional free-volume distribution, distribution of torsional angles, small molecule solubility constant, and radial distribution function of PVC at 0.1 MPa and above the glass transition temperature were calculated/measured, and those of PVA were calculated. The calculated results were compared with the corresponding experimental data and discussed. The calculated densities of PVC and PVA were smaller than the experimental values, probably due to the very low molecular weight of the model polymer used in the simulation. The fractional free-volume distribution and radial distribution function for PVC and PVA were nearly independent of temperature.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2001.04a
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• pp.28-33
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• 2001

Screw conveyors are used extensively in industrial for conveying and elevating materials. Despite their apparent simplicity, the mechanics of the conveying action is very complex. so many engineers depend on experiential data. Capacities of screw are pumping, steady flow of polymer melts, steady volumetric throughput etc. they are affected by geometry of screw, heat flux, pressure on inside barrel, rotating velocity, friction coefficient at screw surface etc. by computation volumetric efficiency increases as rotating velocity increases and decreases as friction coefficient increases. also it decreases with short pitch length. and double flight screw is more effective than single flight screw. The temperature of polymer melts by heating pad and injection pressure play a very important role in the injection molding machine. so in this paper we analyze thermal distortion and stress of screw includes pressure and temperature distributions by finite element analysis to understand what design factors influence on volumetric throughput efficiency of the screw and thermo-mechanical characteristics of screw.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2001.06a
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• pp.248-256
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• 2001

Capacities of screw are pumping, steady flow of polymer melts, volumetric efficiency, steady volumetric throughout etc. they are affected by geometry of screw, heat flux, pressure on inside barrel, rotating velocity, friction coefficient at screw surface etc. Also the temperature of polymer melts by heating pad and injection pressure play a very important role in the injection molding machine. by computation volumetric efficiency increases as rotating velocity increases, flight number increses, and decreases as friction coefficient increases. but volumetric throughout is different :s flight number increases with helix angle variability. so in this paper we analyze thermal distortion and stress of screw includes pressure and temperature distributions by finite element analysis to understand what design factors influence on thermo-mechanical characteristics of screw.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2008.11a
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• pp.239-240
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• 2008

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2007.06a
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• pp.213-214
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• 2007

• Proceedings of the Korean Society of Rheology Conference
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• 2002.05a
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• pp.97-100
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• 2002

• Korea-Australia Rheology Journal
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• v.18 no.4
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• pp.199-207
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• 2006

Measurements by Luap et al. (2005) of elongational viscosity and birefringence of two nearly monodisperse polystyrene melts with molar masses $M_{w}$ of $206,000g{\cdot}mol^{-1}$ (PS206k) and $465,000g{\cdot}mol^{-1}$ (PS465k) respectively are reconsidered. At higher elongational stresses, the samples showed clearly deviations from the stress optical rule (SOR). The elongational viscosity data of both melts can be modeled quantitatively by the MSF model of Wagner et al. (2005), which is based on the assumption of a strain-dependent tube diameter and the interchain pressure term of Marrucci and Ianniruberto (2004). The only nonlinear parameter of the model, the tube diameter relaxation time, scales with $M_{w}^{2}$. In order to get agreement with the birefringence data, finite chain extensibility effects are taken into account by use of the $Pad\'{e}$ approximation of the inverse Langevin function, and the interchain pressure term is modified accordingly. Due to a selfregulating limitation of chain stretch by the FENE interchain pressure term, the transient elongational viscosity shows a small dependence on finite extensibility only, while the predicted steady-state elongational viscosity is not affected by non-Gaussian effects in agreement with experimental evidence. However, deviations from the SOR are described quantitatively by the MSF model by taking into account finite chain extensibility, and within the experimental window investigated, deviations from the SOR are predicted to be strain rate, temperature, and molar mass independent for the two nearly monodisperse polystyrene melts in good agreement with experimental data.

• Korea-Australia Rheology Journal
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• v.11 no.3
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• pp.197-218
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• 1999

Rheological techniques are frequently used to characterize particulate suspensions and polymer systems. Experimental data frequently show that similar trends and characteristics are found in both systems. Using common examples and illustrations of the rheological behaviour, we attempt to bring together these separate fields and investigate the common links in the different systems. In many cases the similar rheological behaviour observed in these different systems can be related to the same basic physical principles.

• Transactions of Materials Processing
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• v.18 no.1
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• pp.20-25
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• 2009

A finite element analysis was carried out for a 4:1 planar contraction die for polymer melts using the viscoelastic constitutive equation of Leonov. Viscoelastic fluids showed significant differences in pressure drop and birefringence in contraction and expansion flows. The pressure drop was higher and the birefringence smaller in expansion than in contraction flow. The difference increased with increasing flow rate. The nonlinear Leonov model was shown to describe the viscoelastic effects observed in experiments.

• 한국전산유체공학회:학술대회논문집
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• 2008.08a
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• pp.32.5-32.5
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• 2008