• Title/Summary/Keyword: polymer interface

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Analysis of Thermal Expansion of Latex-Modified Concrete (라텍스개질 콘크리트의 열팽창 특성 분석)

  • Choi, Seong-Yong;Lee, Joo-Hyung;Lim, Hong-Beom;Yun, Kyong-Ku
    • Journal of Industrial Technology
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    • v.23 no.A
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    • pp.157-163
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    • 2003
  • The properties of mechanics and durability of LMC have been performed actively. However, little studies on analysis and properties of thermal expansion has been on the temperature variation. Especially, the low of bonding strength and tensile cracking are caused by difference of thermal expansion between LMC and the substrate concrete. Therefore, this study focused on effect of thermal expansion behavior and properties of LMC according to temperature variation. To identify the property of thermal expansion of LMC, tests of modulus of thermal expansion were carried out at 28 days after casting specimen, subjected to temperature variation between $10^{\circ}C$ and $60^{\circ}C$. The results of this study showed the modulus of elastic of LMC was similar to that of ordinary portland concrete(OPC). It means that stresses caused by difference of modulus of elastic did not occur on interface between LMC and existing concrete. The modulus of thermal expansion of LMC had a little smaller than that of OPC. The modulus of thermal expansion of polymer modified concrete is generally larger than OPC, but the result of this test is disagree with the fact, which may be due to the humidity evaporation difference and aggregate properties.

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A Study on the Nonlinear Viscoelastic Properties of PBXs (복합화약의 비선형 점탄성 특성 연구)

  • Shim Jung-Seob;Kim Hyoun-Soo;Lee Keun-Deuk;Kim Jeong-Kook
    • Journal of the Korea Institute of Military Science and Technology
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    • v.7 no.2 s.17
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    • pp.100-108
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    • 2004
  • Nitramine-polymer composites suffer from a problem known as dewetting. Dewetting adversely affects the performance and the sensitivity characteristics of an explosive composition. Voids, which are generated between explosive particles and binder on dewetting, act as initiation sites. For a PBXs as well as propellants, where good adhesion and mechanical properties are of great importance, dewetting therefore must be prevented by strong adhesion between the filler and the binder. The surface energy of materials is measured by Wilhelmy plate and wicking method. The interfacial energy between the filler and the binder is calculated from the disperse phase and the polar phase of surface energy. Time dependent compressive properties of composite explosives have been determined by stress-strain curves obtained at different strain rates and temperatures. The interfacial state of the PBX was observed through SEM. It was found from the result that the interface between the explosive and the binder becomes better adhesion with decreasing interfacial tension and increasing work of adhesion. The result clearly shows that the castable PBX has good adhesion more than the pressable PBX.

Dielectric Properties of Complex Cconcentration in IMI-0 Thin Films (IMI-O 초박막의 착체농도에 대한 유전 특성)

  • 정상범;유승엽;박재철;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.345-348
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    • 1999
  • The monolayer behaviors at the air-water interface and the dielectric properties of MI-0 LB films for complex concentration were investigated by the surface pressure-area ($\pi$-A) isotherms and dielectric constant. The molecular area was expanded with increase of metal ions concentration. It is considered that the expansion of molecular area is due to electrostatic repulsion between the polymer chains andhydrophobic increase of ionic strength. In the frequency-dependent complex dielectric constant at room temperature, the real part of dielectric constant($\varepsilon'$) is about 6.0~10.0 in the low-frequency range and is decreasing slowly upto $1O^4$Hz. It decreased abruptly near $1O^5Hz$. It seems to be dielectric dispersion in this frequency range. Also, the imaginary part of dielectric constant ($\varepsilon"$) shows a peak in $1O^5$~$1O^6Hz$. It seems to be dielectric absorption in this frequency range.ange.

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Solution-processible corrugated structure and scattering layer for enhanced light extraction from organic light-emitting diodes

  • Hyun, Woo Jin;Im, Sang Hyuk;Park, O Ok;Chin, Byung Doo
    • Journal of Information Display
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    • v.13 no.4
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    • pp.151-157
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    • 2012
  • A simple method of fabricating out-coupling structures was demonstrated via solution-processing to enhance light extraction from organic light-emitting diodes (OLEDs). Scattering layers were easily obtained by spin-coating an $SiO_2$ sol solution that contained $TiO_2$ particles. By introducing the scattering layer and the solution-processible corrugated structure as internal and external extraction layers, the OLEDs showed increased external quantum efficiency without a change in the electroluminescence spectrum compared to conventional devices. Using these solution-processible out-coupling structures, nearly all-solution-processed OLEDs with enhanced light extraction could be fabricated. The light extraction enhancement is attributed to the suppression by the out-coupling structures of the light-trapping that arose at the interface of the glass substrate and the air.

Characterization of Spironaphthooxazine Derivative Thin Films for Optical Memory

  • Kang, Young-Soo;An, Sang-Do;Jang, Ju-Seog;Kim, Byung-Kyu;Kim, Yong-Joo
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.49-52
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    • 2001
  • The derivatives of spironaphthooxazine gause photoisomerization when they are illuminate with UV light. We investigated the photoisomerization of spironaphthooxazine derivatives for holographic memory. Langmuir-Blodgett (LB) films contain amphiphile spironaphthooxazine derivatives which can be applied in molecular devices by a change of molecular level energy and a refractive index. In order to investigate the photoisomerization of spironaphthooxazine derivatives at the air/water energy and a refractive index. In order to investigate the photoisomerization of spironaphthooxazine derivatives at the air/water interfaces, spironaphthooxazine derivatives with side alkyl chains were synthesized. The films of the spironaphthooxazine derivatives were characterized by the measurement of UV/vis spectroscopy, Brewster Angle Microscopy (BAM) and Atomic Force Microscopy (AFM). The monolayers of the spironaphthooxazine derivatives mixed with stearic acid were stable at the air/water interface and visualized by the measurement of BAM. The spironaphthooxazine derivative monolayers on the glass surface showed the maximum efficiency of diffraction as 0.99% by the measurement of holography.

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Wearable Tactile Display Based on Soft Actuator (유연한 구동기를 이용한 착용 가능한 촉각 제시 장치 개발)

  • Koo, Ig-Mo;Jung, Kwang-Mok;Park, Jong-Kil;Koo, Ja-Choon;Lee, Young-Kwan;Nam, Jae-Do;Choi, Hyouk-Ryeol
    • The Journal of Korea Robotics Society
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    • v.1 no.1
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    • pp.89-101
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    • 2006
  • Tactile sensation is one of the most important sensory functions for human perception of objects. Recently, there have been many technical challenges in the field of tactile display as well as tactile sensing. In this paper, we propose an innovative tactile display device based on soft actuator technology with ElectroActive Polymer(EAP). This device offers advantageous features over existing devices with respect to intrinsic flexibility, softness, ease of fabrication and miniaturization, high power density, and cost effectiveness. In particular, it can be adapted to various geometric configurations because it possesses structural flexibility, so it can be worn on any part of the human body such as finger, palm, and arm etc. It can be extensively applied as a wearable tactile display, a Braille device for the visually disabled, and a human interface in the future. A new design of the flexible actuator is proposed and its basic operational principles are discussed. In addition, a wearable tactile display device with $4{\times}5$ actuator array(20 actuator cells) is developed and its effectiveness is confirmed.

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Evaluation of the characteristics of polymer LB multi-layer (고분자 LB막의 누적 특성 평가)

  • Kim, Ki-Young;Kim, Chul-Hong;Shin, Hoon-Kyu;Chang, Sang-Mok;Kwon, Young-Soo;Lee, Bun-Jong
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1203-1205
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    • 1993
  • The use of preformed polymers and their cross-linking have been attempted in order to improve the intrinsic fragility of monolayers and Langmuir-Blodgett(LB) films. The evaluation of the characteristics of LB multi-layer by using AT-cut quartz crystal have been also attempted. From this study, it reveals that the polyether pendants of 2C18VE3 lie at the air-water interface at low surface pressures and are forced down into the subphase when the monolayers are compressed. This caracteristic behavoir of the pendant polyethers is much clear on aqueous PAA and also observed on saturated aqueous NaCl. And the characteristics of LB multi-layers could be evaluated by using AT-cut quartz crystal in situ.

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Effects of Thermal Imidization and Annealing on Liquid Crystal Alignment ever Rubbed Polyimide Layers: Change in the Pretilt Angle

  • Paek, Sang-Hyon
    • Macromolecular Research
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    • v.9 no.6
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    • pp.303-312
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    • 2001
  • The fabrication of liquid crystal display (LCD) panels involves several thermal processes such as imidization of the alignment layer (AL) and annealing of the rubbed polyimide AL. The nature of these processes on the LC alignment, especially on the pretilt angle (Θ$\_$p/) has been systematically studied, employing various types of polyimide structures. The imidization effect depends on the nature of polyimid precursors; Θ$\^$p/ increases with the degree of the imidization for the main-chain type of ALs, due to the decrease in the surface polarity, but this relation is not applicable to the alkylated ones in which the steric effect at the AL surface by the aliphatic side chains is dominant. Annealing of the rubbed polyimide AL deteriorates its rubbing-induced molecular orientation and subsequently the overlying LC alignment, resulting in the decrease in Θ$\_$p/. Especially, annealing of the LC cell affects the LC-AL interaction as well as the AL orientation and thus its effect on LC alignment depends sensitively on the nature of LC-polyimide interface; aromatic moiety in the polyimide structure gives better thermal stability of LC alignment while fluorinated polyimide ALs induce the less stable alignment.

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Modelling of the interfacial damping due to nanotube agglomerations in nanocomposites

  • Jarali, Chetan S.;Madhusudan, M.;Vidyashankar, S.;Lu, Y. Charles
    • Smart Structures and Systems
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    • v.19 no.1
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    • pp.57-66
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    • 2017
  • Nanocomposites reinforced with carbon nanotube fibers exhibit greater stiffness, strength and damping properties in comparison to conventional composites reinforced with carbon/glass fibers. Consequently, most of the nanocomposite research is focused in understanding the dynamic characteristics, which are highly useful in applications such as vibration control and energy harvesting. It has been observed that those nanocomposites show better stiffness when the geometry of nanotubes is straight as compared to curvilinear although nanotube agglomeration may exist. In this work the damping behavior of the nanocomposite is characterized in terms of loss factor under the presence of nanotube agglomerations. A micro stick-slip damping model is used to compute the damping properties of the nanocomposites with multiwall carbon nanotubes. The present formulation considers the slippage between the interface of the matrix and the nanotubes as well as the slippage between the interlayers in the nanotubes. The nanotube agglomerations model is also presented. Results are computed based on the loss factor expressed in terms of strain amplitude and nanotube agglomerations. The results show that although-among the various factors such as the material properties (moduli of nanotubes and polymer matrix) and the geometric properties (number of nanotubes, volume fraction of nanotubes, and critical interfacial shear stresses), the agglomeration of nanotubes significantly influences the damping properties of the nanocomposites. Therefore the full potential of nanocomposites to be used for damping applications needs to be analyzed under the influence of nanotube agglomerations.

Experimental investigations and FE simulation of exterior BCJs retrofitted with CFRP fabric

  • Halahla, Abdulsamee M.;Rahman, Muhammad K.;Al-Gadhib, Ali H.;Al-Osta, Mohammed A.;Baluch, Mohammed H.
    • Earthquakes and Structures
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    • v.17 no.4
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    • pp.337-354
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    • 2019
  • This paper presents the results of experimental and numerical studies conducted to investigate the behavior of exterior reinforced concrete beam column joints (BCJ) strengthened by using carbon fiber reinforced polymer (CFRP) sheets. Twelve reinforced concrete beam-column joints (BCJ) were tested in an experimental program by simulating the joints in seismically deficient old buildings. One group of BCJs was designed to fail in flexure at the BCJ interface, and the second group was designed to ensure joint shear failure. One specimen in each set was -retrofitted with CFRP sheet wrapped diagonally around the joint. The specimens were subjected to both monotonic and cyclic loading up to failure. 3D finite element simulation of the BCJs tested in the experimental program was carried out using the software ABAQUS, adopting the damage plasticity model (CDP) for concrete. The experimental results showed that retrofitting of the shear deficient, BCJs by CFRP sheets enhanced the strength and ductility and the failure mode changed from shear failure in the joints to the desired flexural failure in the beam segment. The FE simulation of BCJs showed a good agreement with the experimental results, which indicated that the CDP model could be used to model the problems of the monotonic and cyclic loading of beam-column reinforced concrete joints.