• Title/Summary/Keyword: polymer film

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Fabrication and Properties of Conductive Carbon Fiber/Polyethylene Composite Films Fabricated under High Intensity Electric Fields : Effect of Polymer Sublayer (고전기장을 이용한 도전성 탄소섬유/폴리에틸렌 복합필름의 제조 및 특성 연구 : 고분자 점착하층의 영향)

  • Park, Min;Kim, Jun-Kyung;Lim, Soon-Ho;Ko, Moon-Bae;Choe, Chul-Rim;Mironov, V.S.;Bang, Hyo-Jae;Lee, Kwang-Hee
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.268-275
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    • 2000
  • We investigated the effect of polymer sublayer on volumetric resistivity and tensile strength of carbon fiber (CF)/polyethylene composite films fabricated under high intensity electric fields. The dependence of volumetric resistivity and tensile strength of the films on the polymer sublayer thickness or mass part exhibited complex behavior according to CF content and CF layer density in the films. As the thickness of polymer sublayer increases, two groups of processes at thermo-mechanical forming stage would take effects in the properties of the films. The first group comprises the increase of polymer layer thickness having reduced CF content compared with central or upper part of the film and insufficient wetting of CF resulting in the loosened structure near upper film side. The second group, on the other hand, is the improvement of mobility of molten sublayer leading to better distribution of CF throughout the film thickness and the formation of more compact structure. The different degree of contribution of these two competing processes at varied CF content and CF layer density could explain complex dependence of the film properties on the polymer sublayer. These results are important to optimize the electrical and mechanical properties of highly conductive polymer films, which can be used as electromagnetic interference shielding materials.

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Fabrication and Characterization of Gate Insulator Thin Films prepared by Plasma Polymerization (플라즈마 중합법에 의한 게이트 절연박막의 제작 및 특성)

  • Son, Young-Do;Hwang, Myung-Whan;Lim, Jae-Sung;Shin, Paik-Kyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.12
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    • pp.48-53
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    • 2011
  • Polymer thin films were prepared by capacitively coupled plasma polymerization process for application of gate insulator. The polymer thin films revealed to form polymer layers with original properties of the monomer. Among the plasma polymer thin films, the styrene polymer having large number of phenyl sites revealed higher dielectric constant of k=3.7 than that of conventional polymer. The plasma polymerized styrene thin film revealed no hysteresis characteristics and low leakage current density of $1{\times}10^{-8}[Acm^{-2}]$ at field strength of $1[MVcm^{-1}]$, which measured by I-V and C-V measurements using MIM and MIS devices.

Effect of Film Processing Conditions on the Dimensional Stability of Triacetyl Cellulose Film (필름 가공조건이 트리아세틸 셀룰로오스 필름의 치수안정성에 미치는 영향)

  • Kim, Hyo-Gap;Kim, Hong-Suk;Kim, Han-Sung;Cho, Jin-Sik;Kim, Yong-Won;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.133-136
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    • 2010
  • Effect of solution film processing conditions on the dimensional stability of TAC film which is used as protection film of liquid crystal display (LCD) has been studied under hot and humid environmental condition (65 $^{\circ}C$, 90%). In addition, the mechanical and optical property changes due to the dimensional instability were also investigated. It was found that the fast solvent evaporation due to the increasing of methylene chloride content in solvent mixtures and decreasing dope concentration caused the lowering of dimensional stability under hot and humid condition. This dimensional stability change also affected the mechanical and optical properties of TAC films as well.

Measurement of the Third Order Nonlinear Optical Susceptibility of the Conducting Polymer Film by Maker Fringe Method (Maker fringe 방법에 의한 전도성 박막의 3차 비선형 광학 감수율의 측정)

  • 이건준;유성규;김동호
    • Korean Journal of Optics and Photonics
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    • v.5 no.1
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    • pp.18-24
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    • 1994
  • We have investigated a method to measure the refractive index, coherence length, and the third order nonlinear optical susceptibility ($x^{(3)}$) of the conducting polymer film. ($x^{(3)}$) of polymer film was obtained, by comparing Maker fringe of polymer film with that of fused quartz, and by calculating the correction factor due to the linear refractive index. The linear refractive index of polymer film was determined from the envelopes of the maxima and minima in the transmission spectrum. Poly ((1,4-phenylenevinylene$)_{0.34}$-co-(2-methoxy-1,4-phen ylene vinylene$)_{0.66}$) [PP$V_{0.34}$-PMP$V_{0.66}$] thin film was prepared by spin coating method. From transmission spectrum and Maker fringe data, we found that the refractive index, coherence length, and the third order nonlinear optical susceptibility ($x^{(3)}$) of the [PP$V_{0.34}$-PMP$V_{0.66}$] are 1.786, 17.86 ${\mu}m$ and 5.8${\times}10^{-12}$esu, respectively.

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The Crystallization of Polycarbonate Film Using Methylene Chloride/1,3-Dioxolane as a Solution Casting Co-Solvent (Methylene Chloride/1,3-Dioxolane 혼합 용매에 의한 용액 가공 폴리카보네이트 필름의 결정화)

  • Kim, Whan-Ki;Kim, Jae-Hyun;Kim, Sung-Do;Han, Joon-Hee;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.483-488
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    • 2008
  • The effect of methylene chloride/1,3-dioxolane co-solvent on the crystallization in the optical polycarbonate film was investigated. Increasing 1,3-dioxolane content in co-solvent resulted in the crystallization due to the lowering of solvent evaporation rate during film drying process. The crystallization in PC film could be minimized by either controlling of solvent composition and increasing solvent drying temperature. It was found that the surface roughness of solution casting PC film was affected by both crystallization and solvent evaporation rate. This morphological effect by alternative solvent is ascribed to a large decrease in light transmissivity on the optical PC film.

The Enhanced Thermoforming Stability of ITO Transparent Electrode Film by Using the Conducting Polymer Thin-Film (전도성 고분자 박막을 이용한 ITO 투명 전극 필름의 열성형 안정성 향상 연구)

  • Seo Yeong Son;Seong Yeon Park;Sangsub Lee;Changhun Yun
    • Membrane Journal
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    • v.33 no.5
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    • pp.248-256
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    • 2023
  • Indium tin oxide (ITO) transparent electrode film has been widely adopted for the various applications such as display and electric vehicle. In this paper, we studied how to enhance the thermoforming stability of ITO film by applying the highly conductive Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) thin layer. Based on the change of sheet resistance value, the influence of the additional solvent with different boiling point was investigated for the PEDOT:PSS coating solution. In addition, by analyzing optical transmittance and Raman spectrum, we confirmed the key mechanism which determine the final electrical conductivity of the PEDOT:PSS on ITO film using an ethylene glycol solvent. The final ITO transparent electrode coated with PEDOT:PSS performed the outstanding endurance of electrical conduction even in 126% stretching condition.

Enhancement of cover-layer surface properties using dielectric protective layer (유전체 보호층을 이용한 NFR 미디어 커버층의 표면 특성 향상)

  • Kim, Jin-Hong;Lim, Jung-Shik;Lee, Jun-Seok;Seo, Jeong-Kyo
    • Transactions of the Society of Information Storage Systems
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    • v.4 no.1
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    • pp.13-18
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    • 2008
  • Scratches are observed on a polymer cover-layer of near-field recording (NFR) media after a servo test with rotating disc. The scratches are formed by the collision of a solid immersion lens (SIL)-media. One of the possible ways to avoid the scratch problem is to coat a dielectric protective film on the polymer cover-layer which enhances the hardness of the surface. The surface with hard characteristics in the surface reduces the scratch problem in the cover-layer. Not only the mechanical properties but also the optical properties should be controlled. Specifically, the refractive index of the dielectric protective film should be matched with the polymer cover-layer not to lose light at the interface due to the difference of the refractive index. The refractive index of the dielectric film can be tailored by controlling process parameters during sputtering and matched with that of the polymer cover-layer.

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Measurement of Water Vapor Permeability of Bio-polymer Films (생고분자 필름의 투습도 측정)

  • Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.5 no.1
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    • pp.37-46
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    • 1999
  • Water vapor permeability of films is commonly calculated from the water vapor transmission rate of the film measured using a permeability cup method which is essentially a gravimetric method. This method was originally developed for petroleum based plastic films with low water vapor permeability. In the case of hydrophilic bio-polymer films, the resistance caused by a stagnant air layer, which is developed between the underside of the film mounted on the cup and the surface of the desiccant saturated salt solution or distilled water, can be significant and, if neglected, ran lead to underestimation of water vapor transmission rates. Therefore, it is necessary to correct water vapor transmission rate data to accurately estimate the water vapor permeability of bio-polymer films.

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Low-voltage Organic Thin-film Transistors with Polymeric High-k Gate Insulator on a Flexible Substrates (고유전율 절연체를 활용한 저 전압 유연 유기물 박막 트랜지스터)

  • Kim, Jae-Hyun;Bae, Jin-Hyuk;Lee, In-ho;Kim, Min-Hoi
    • Journal of Sensor Science and Technology
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    • v.24 no.3
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    • pp.165-168
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    • 2015
  • We demonstrated low-voltage organic thin-film transistors (OTFTs) with bilayer insulators, high-k polymer and low temperature crosslinkable polymer, on a flexible plastic substrate. Poly (vinylidene fluoridetrifluoroethylene) (P(VDF-TrFE)) and poly (2-vinylnaphthalene) are used for high-k polymer gate insulator and low temperature crosslinkable polymer insulators, respectively. The mobility of flexible OTFTs is $0.17cm^2/Vs$ at gate voltages -5 V after bending operation.

Improvement in Adhesion of the Indium Zinc Oxide (IZO) Thin Films on Organic Polymer Films

  • Lee, Yeong-Beom;Kim, Kyong-Sub;Ko, Min-Jae;Kim, Kyung-Seop
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.537-539
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    • 2009
  • We report the improvement in adhesion of IZO thin films through oxygen ($O_2$) plasma treatment of organic polymer film. In conclusion, the $O_2$ plasma treatment of an organic polymer film was accomplished with improving ca. 1.8 times in adhesion than that of the only general etch treatment on the same organic polymer film.

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