• Polymer(Korea)
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• v.35 no.3
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• pp.232-237
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• 2011

The relaxation spectra of polyacrylonitrile-poly(vinyl chloride) copolymer filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of relaxation spectrum. The theoretical equation of relaxation spectrum was derived from the Ree-Eyring and Maxwell model. The experimental of stress relaxation was carried out using a tensile tester with a solvent chamber. The determination of relaxation spectra was performed by computer calculation. From the relaxation spectra, the fine structures, viscoelastic properties and hole volumes of solid polymers were studied. It was observed that the relaxation spectra of these samples were directly related to the distribution of molecular weights and self diffusions of flow segments.

• Journal of Fashion Business
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• v.12 no.1
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• pp.120-128
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• 2008

Rayon fiber as clothing material has silk-like property which relates to other synthetic fibers. It has many advantages that is required to women's clothes. However rayon has many shortcomings. Therefore this research is to spin rayon-like polyester which has high contraction property to be synthesized by previous research to solve those shortcomings and to maintain advantages of rayon. The contraction ratio of regular polyester is 30% and the contraction ratio of this synthesized polyester is over 60%. The spinning temperature of regular polyester ranges from $285^{\circ}C$ to $300^{\circ}C$. However, this copolymer is set range from $270^{\circ}C$ to $290^{\circ}C$, which is $10^{\circ}C$ less than regular polyester due to decreasing melting temperature. The spinning velocity effects the tensile strength and elongation of yarn magnificently. The high velocity of spinning makes yarn highly oriented, increases the tensile strength and decreases the elongation. This research defines the condition as following; draw ratio 2.734, First roller temperature $85^{\circ}C$, Slit heater temperature $175^{\circ}C$.

• Computers and Concrete
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• v.33 no.4
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• pp.385-398
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• 2024

As concrete dominates the construction industry, alternatives to traditionally used steel reinforcement are being sought. This study explored the suitability of carbon fiber-reinforced polymer (CFRP) as a substitute within rigid frames, focusing on its impact on section ductility and overall structural durability against seismic events. However, current design guidelines address quasi-static loads, leaving a gap for dynamic or extreme circumstances. Our approach included multiscale simulations, parametric study, and energy dissipation analyses, drawing upon a unique adaptation of modified compression field theory. In our efforts to optimize macro and microparameters to improve yield strength, manage brittleness, and govern failure modes, we also recognized the potential of CFRP's high corrosion resistance. This characteristic of CFRP could significantly reduce the frequency of required repairs, thereby contributing to enhanced durability of the structures. The research reveals that CFRP's durability and seismic resistance are attributed to plastic joints within compressed fibers. Notably, CFRP can impart ductility to structural designs, effectively balancing its inherent brittleness, particularly when integrated with quasi-brittle materials. This research challenges the notion that designing bendable components with carbon fiber reinforcement is impractical. It shows that creating ductile bending components with CFRP in concrete is feasible despite the material's brittleness. This funding overturns conventional assumptions and opens new avenues for using CFRP in structural applications where ductility and resilience are crucial.

• Polymer(Korea)
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• v.32 no.2
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• pp.131-137
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• 2008

We have fabricated polystyrene (PS) nanofibrous scaffold for hepatocyte culture by electrospinning method and subsequently coated with specific ligand of Poly[N-p-vinylbenzyl-O-$\beta$-D-galactopyranocyl-($1{\rightarrow}4$)-D-gluconamide](PVLA) to enhance hepatocytes attachment. Rat hepatocytes behavior on the PVLA-coated and non-coated PS nanofibrous matrices have been investigated. Electrospun PS nanofiber structures revealed randomly aligned fibers with average diameter of 500 nm. It is observed that PS nanofibrous matrix could incorporate many cells into the interior of the matrix probably due to the suitable pore size. Cell viabilities cultured on PVLA-coated PS nanofibrous mats were maintained for 3 weeks, while it was decreased rapidly on PVLA-coated PS dishes. High hepatic functions especially for albumin secretion and ammonia removal were maintained at least for 2 weeks on nanofibrous mats but rapidly decreased on flat PS dishes. These results indicate that nanofibrous structure enabled 3-D culture with high level of cell-cell contact results in providing cell-cell communications and subsequent long-term maintenance of specific cell functions.

• Journal of the Korean Ceramic Society
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• v.47 no.4
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• pp.343-352
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• 2010

A zirconia gel/polymer hybrid nanofiber was produced in a nonwoven fabric mode by electrospinning a sol derived from hydrolysis of zirconium butoxide with a polyvinyl butyral. Results indicated that the hydroxyl groups on the vinyl alcohol units in the backbone of the polymer were involved in the hydrolysis as well as grafting the hydrolyzed zirconium butoxide. In addition, use of acetic acid as a catalyst resulted in further hydrolysis and condensation in the sol, which led to the growth of -Zr-O-Zr- networks among the polymer chains. These networks gradually transformed into a crystalline zirconia structure upon heating. The as-spun fiber was smooth but partially wrinkled on the surface. The average fiber diameter was $690{\pm}110\;nm$. The fiber exhibited a strong but broad blue photoluminescence with its maximum intensity at a wavelength of ~410 nm at room temperature. When the fiber was heat-treated at $400^{\circ}C$, the fiber diameter shrunk to $250{\pm}60\;nm$. Nanocrystals which belonged to a tetragonal zirconia phase and were ~5 nm in size appeared. A strong white photoluminescence was observed in this fiber. This suggests that oxygen or carbon defects associated with the formation of the nanocrystals play a role in generating the photoluminescence. Further heating to $800^{\circ}C$ resulted in a monoclinic phase beginning to form In the heat-treated fibers, coloring occurred but varied depending on the heating temperature. Crystallization, coloring, and phase transition to the monoclinic structure influenced the photoluminescence. At $600^{\circ}C$, the fiber appeared to be fully crystallized to a tetragonal zirconia phase.

• Magazine of the Korea Concrete Institute
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• v.5 no.4
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• pp.145-155
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• 1993

The results of an experimental study on the manufacture and the mechanical properties of fiber reinforced fly ash$\cdot$lime$\cdot$gypsum composites are presented in this paper. 'The composites using fly ash, lime, and gypsum were prepared with various fibers (PAN-derived and Pitch-derived carbon fiber, alkali-resistance glass fiber) and a small amount of polymer emulsion-styrene butadiene rubber latex (SBR). As the test results show, the manufacturing process technology of fly ash$\cdot$lime$\cdot$gypsum composites was developed and its optimum mix proportions were successfully proposed. And the flexural strength and toughness of fiber reinforced fly ash$\cdot$lime $\cdot$gypsum composites were increased remarkably by fiber contents, but the compressive strength of the composites were influenced by the kinds fiber more than by the fiber contents. Also, the addition of a polymer emulsion to the composites decreased the bulk specific gravity, but the compressive and flexural strength, and the toughness of the composites were not influenced by it, but were considerably improved by increasing fiber contents.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.967-972
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• 2004

The role of transfer films formed during sliding of polymer composites against steel counterfaces was studied in terms of the tribological behaviors of composites. Four kinds of composites were included in this study: (1) unfilled PPS, (2) PPS+2%CuO, (3) PPS+2%CuO+5% carbon fiber (CF), and (4) PPS+2%CuO+15%Kevlar. The filler material CuO was in nanoscale particulate form and the reinforcing material was in the form of short fibers. The composites were prepared by compression molding at $310^{\circ}C$ and sliding tests were run in the pin-on-disk sliding configuration. The counterface was made of tool steel hardened to 55-60 HRC and finished to a surface roughness of 0.09-0.10 ${\mu}m$ Ra. Wear tests were run for 6 hrs at the sliding speed of 1 m/s and contact pressure of 0.65 MPa. Transfer films formed on the counterfaces during sliding were investigated using AFM and SEM. The results showed that as the transfer film became smooth and uniform, wear rate decreased. PPS+2%CuO+15%Kevlar composite showed the lowest steady state wear rate in this study and its transfer film showed the smoothest and the most uniform characteristics. The examination of worn surfaces of PPS+2%CuO composite using X-ray area scanning (dot mapping) showed back-transfer of steel counterface material to the polymer pin surface. This behavior is believed to strengthen the polymer pin surface during sliding thereby contributing to the decrease in wear rate.

• Elastomers and Composites
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• v.49 no.4
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• pp.293-304
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• 2014

Rubber air spring (RAS) is a special suspension device for the industries of automobile, railroad car and other transportation. A RAS serves as a spring component with the elastic effect of compression and expansion of air in a composite rubber bag. The main component of RAS is the rubber sleeve. Rubber sleeve is the composite which is made up of combination of chloroprene rubber (CR) and nylon 6 cord, and the adhesive strength between CR and nylon 6 cord is very important. In this study, considering the effects of additives in rubber sleeve, various physical properties were tested to find the optimal combination of composition and conditions. Further, in order to select the optimum orientation of the reinforcing fibers, numerical analysis was performed using the finite elements method. After assembling all components of RAS, it was mounted on an actual vehicle, and then it was tested air leakage, fatigue life and fundamental properties.

• Macromolecular Research
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• v.16 no.3
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• pp.212-217
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• 2008

PVDF ($Kynar^{(R)}$ 761) nanofibers were made by electrospinning with an external voltage of 6-10 kV, a traveling distance of 7-15 cm and a flow rate of 0.4-1 mL/h. Although the mean diameter of the fibers has not changed significantly, the conditions affected the change in diameter distribution. This was attributed to interactions, both attraction and repulsion, between the positive charges on the polymer solutions and the electrically grounded collector. Higher voltages and traveling distance increased the level of attraction between the positive charge on the polymer solution and the electrically grounded collector, resulting in a narrow diameter distribution, In addition, a high flow rate allowed a high population of uniformly charged solutions to travel to the grounded collector, which resulted in a narrow diameter distribution. The optimum conditions for electrospinning of PVDF in DMAc/acetone (3/7 by wt) were a collector voltage of 6 kV, a syringe tip to collector of 7 cm, a flux rate of 0.4 mL/h and 10 kV, 10 cm, 1 mL/h, Since PVDF is widely used as a filtration membrane, it was electrospun on a PET support with a rotating drum as a grounded collector. Surprisingly, some straight nanofibers were separated from the randomly deposited nanofibers. The straight nanofiber area was transparent, while the randomly deposited nanofiber area was opaque. Both straight nanofibers and aligned nanotibers could be obtained by manipulating the PET drum collector. These phenomena were not observed when the support was changed to an Al sheet. This suggests that a pseudo dual collector was generated on the PET sheet. No negative charge was created because the PET sheet was not a conductive material. However, less charge was created when the sheet was not perfectly attached to the metal drum. Hence, the nanotibers jumped from one grounded site to the nearest one, yielding a straight nanofiber.

• Composites Research
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• v.19 no.2
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• pp.7-12
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• 2006

Graphite particle/carbon fiber hybrid conductive polymer composites were fabricated by the compression molding technique. Graphite particles were mixed with an epoxy resin to impart the electrical conductivity in the composite materials. In this study, graphite reinforced conductive polymer composites with high filler loadings were manufactured to accomplish high electrical conductivity above 100S/cm. Graphite particles were the main filler to increase the electrical conductivity of composites by direct contact between graphite particles. While high filler loadings are needed to attain good electrical conductivity, the composites becomes brittle. So carbon fiber was added to compensate weakened mechanical property. With increasing the carbon fiber loading ratio, the electrical conductivity gradually decreased because non-conducting regions were generated in the carbon fiber cluster among carbon fibers, while the flexural strength increased. In the case of carbon fiber 20wt.% of the total system, the electrical conductivity decreased 27%, whereas the flexural strength increased 12%.