• Title/Summary/Keyword: polymer fibers

Search Result 577, Processing Time 0.028 seconds

Preparation and Properties of Poly(ethylene terephthalate)(PET)/Polyamide-6(PA6) Alloy Fibers using Epoxy as a Reactive Compatibilizer: I. Effect of Epoxy on the Phase Separation of PET/PA6 Alloys (에폭시를 반응성 상용화제로 사용하여 제조한 폴리에틸렌테레프탈레이트와 폴리아미드-6 알로이 섬유의 구조와 성질: 1. 알로이의 상분리에 미치는 에폭시의 효과)

  • Zhou, Jing;Min, Byung-Gil;Lim, Mok-Keun;Lee, Kwang-Sang;Yu, Yeong-Chool;Han, Jae-Sung
    • Textile Coloration and Finishing
    • /
    • v.24 no.2
    • /
    • pp.145-151
    • /
    • 2012
  • Polymer alloys of poly(ethylene terephthalate)(PET) and nylon6(PA6) which were not miscible each other by themselves were successfully prepared through melt compounding using a twin-screw extruder by utilizing epoxy as reactive compatibilizer. At the epoxy(DGEBA) amount of 0.5~2wt%, the domain size(average diameter) of the discontinuous phase could be reduced up to 0.2${\mu}m$ from 1-5${\mu}m$ that of the simple blend without epoxy. The reaction was presumed to happen mostly at interphase from the result of maximum increase of melt viscosity at the middle range of PET/PA6 blend ratio. It is expected that alloy fibers of PET/epoxy/PA6 with enough mechanical strength for use can be prepared.

Swelling and Fibrillation of Lyocell Fibers in Water and NaOH Solution (Lyocell 섬유소재의 알칼리 팽윤과 피브릴화 거동)

  • Min, Byung-Ghyl;Jeong, Young-Jin;Kim, Chang-Whan;Oh, Young-Sae
    • Fashion & Textile Research Journal
    • /
    • v.1 no.1
    • /
    • pp.56-61
    • /
    • 1999
  • Swelling and fibrillation of two kinds of lyocell, $Tencel^{(R)}$ and $Lyocell^{(R)}$, were investigated using polarizing and scanning electron microscope (SEM). $Tencel^{(R)}$ of a representative lyocell showed that loop tenacity which is related to wrinkle and resilience of fiber does not show significant reduction in wet state. Two kinds of lyocell exhibited surprising degree of swelling in aqueous NaOH solution under free tension. Diameters of $Tencel^{(R)}$ and $Lyocell^{(R)}$ swelled up to 670% and 830%, respectively in the range of around 10% NaOH concentration. Molecular orientation estimated by birefringence also reduced remarkably in alkaline solution. Moreover, diameter and birefringence which changed in alkaline solution did not recovered to original level even after washing and drying. Fibrillation of $Lyocell^{(R)}$ fiber observed by SEM seems to be easier than that of $Tencel^{(R)}$. In order to understand the difference between $Tencel^{(R)}$ and $LyoceJl^{(R)}$, further study on the structure of the two fibers will be followed.

  • PDF

Morphological and Physical Properties of ONP Treated by CaCO3 In-situ Precipitation Method (탄산칼슘 in-situ precipitation 처리된 신문고지의 형태와 물성변화)

  • Lee, Young Ho;Jung, Jae Kwon;Lee, Ki Seung;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.45 no.6
    • /
    • pp.44-54
    • /
    • 2013
  • Replacing OMG (old magazine) to ONP (old newspaper) by raising optical property through $CaCO_3$ in-situ precipitation method in white duplex board presents cost reduction and possible drying energy saving. The strength property impairment by the presence of $CaCO_3$ could be supplemented by the fiber furnish treatment or strength polymer addition. In $CaCO_3$ in-situ precipitation of ONP, it was found from morphological study using FlowCAM, an image analyzer, that most of calcium carbonate were formed on the fines, and made the size of the fines larger. For the case of forming calcium carbonate only on the fractionated fines, the size of the fines were the biggest, and there were more clean surface areas available for bonding for the fractionated long fibers when fractionated fibers and fines were regrouped to make paper.

Modelling of the interfacial damping due to nanotube agglomerations in nanocomposites

  • Jarali, Chetan S.;Madhusudan, M.;Vidyashankar, S.;Lu, Y. Charles
    • Smart Structures and Systems
    • /
    • v.19 no.1
    • /
    • pp.57-66
    • /
    • 2017
  • Nanocomposites reinforced with carbon nanotube fibers exhibit greater stiffness, strength and damping properties in comparison to conventional composites reinforced with carbon/glass fibers. Consequently, most of the nanocomposite research is focused in understanding the dynamic characteristics, which are highly useful in applications such as vibration control and energy harvesting. It has been observed that those nanocomposites show better stiffness when the geometry of nanotubes is straight as compared to curvilinear although nanotube agglomeration may exist. In this work the damping behavior of the nanocomposite is characterized in terms of loss factor under the presence of nanotube agglomerations. A micro stick-slip damping model is used to compute the damping properties of the nanocomposites with multiwall carbon nanotubes. The present formulation considers the slippage between the interface of the matrix and the nanotubes as well as the slippage between the interlayers in the nanotubes. The nanotube agglomerations model is also presented. Results are computed based on the loss factor expressed in terms of strain amplitude and nanotube agglomerations. The results show that although-among the various factors such as the material properties (moduli of nanotubes and polymer matrix) and the geometric properties (number of nanotubes, volume fraction of nanotubes, and critical interfacial shear stresses), the agglomeration of nanotubes significantly influences the damping properties of the nanocomposites. Therefore the full potential of nanocomposites to be used for damping applications needs to be analyzed under the influence of nanotube agglomerations.

Stress Relaxation and Nonlinear Viscoelastic Model of PAN-PVC Copolymers (PAN-PVC 공중합체의 응력완화와 비선형 점탄성 모델)

  • Kim, Nam-Jeong
    • Elastomers and Composites
    • /
    • v.45 no.4
    • /
    • pp.250-255
    • /
    • 2010
  • From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.

Change of Mechanical Properties of Injection-Molded Glass-Fiber-Reinforced Plastic (GFRP) According to Temperature and Water Absorption for Vehicle Weight Reduction (차량 경량화를 위한 사출성형 유리섬유강화플라스틱의 온도 및 수분 흡수에 따른 기계적 물성 변화)

  • Chun, Doo-Man;Ahn, Sung-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.37 no.2
    • /
    • pp.199-204
    • /
    • 2013
  • Owing to the global energy crisis, studies have strongly focused on realizing energy savings through vehicle weight reduction using light metal alloys or polymer composites. Polymer composites afford many advantages including enabling the fabrication of complex shapes by injection molding, and glass and carbon fibers offer improved mechanical properties. However, the high temperature in an engine room and the high humidity during the rainy season can degrade the mechanical properties of the polymer. In this study, the mechanical properties of injection-molded glass-fiber-reinforced polymer were assessed at a temperature of $85^{\circ}C$ and the maximum moisture absorption conditions. The result showed a 23% reduction in the maximum tensile strength under high temperature, 30% reduction under maximum moisture absorption, and 70% reduction under both heat and moisture conditions. For material selection during the design process, the effects of high temperature and high humidity should be considered.

Application of Concentrated FRP Bars to Enhance the Capacity of Two-Way Slabs (2방향 슬래브의 성능 향상을 위한 집중 배근된 FRP 바의 적용)

  • Lee, Joo-Ha;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
    • /
    • v.19 no.6
    • /
    • pp.727-734
    • /
    • 2007
  • The influence of the differences in the physical and mechanical properties between fiber-reinforced polymer (FRP) and conventional steel, concentrated reinforcement in the immediate column region, as well as using steel fiber-reinforced concrete (SFRC) in the slab near the column faces, on the punching behavior of two-way slabs were investigated. The punching shear capacity, stiffness, ductility, strain distribution, and crack control were investigated. Concentrating of the slab reinforcement and the use of SFRC in the slab enhanced the punching behavior of the slabs reinforced with glass fiber-reinforced polymer (GFRP) bars. In addition the test results of the slabs with concentrated reinforcement were compared with various code equations and the predictions proposed in the literature specifically for FRP-reinforced slabs. An appropriate method for determining the reinforcement ratio of slabs with a banded distribution was also investigated to allow predictions to properly reflect the benefit of the slab reinforcement concentration.

Interfacial Characteristics of Polymeric Composite Materials (고분자 복합재료의 계면특성)

  • Park Soo-Jin;Seo Min-Kang
    • Polymer(Korea)
    • /
    • v.29 no.3
    • /
    • pp.221-230
    • /
    • 2005
  • Interfacial interactions and interphases played a key role in multicomponent materials irrespectively of the number and type of their components or their actual structure. They were equally important in particulate filled polymer, polymer blends, fibers-reinforced advanced composites, nanocomposites or biomimetic materials. Recognition of the role of the main factors influencing interfacial adhesion and proper surface modification could lead to significant progress in many fields of research and development, as well as in related technologies. Although the role and importance of interfaces and interphases were the same for all multicomponent materials, the surface modification could be always selected according to the objectives targeted, as well as to the characteristics of the particular system. In this wort therefore, several types of surface modification were performed to improve the interfacial interactions between two components in composite system and their results for the composites were investigated.

Thermophysical Properties of 4D Carbon/Carbon Composites with Preform Architectures (프리폼 구조에 따른 4방향성 탄소/탄소 복합재의 열물리적 특성)

  • Kim, Zeong-Baek;Lee, Ki-Woong;Park, Jong-Min;Joo, Hyeok-Jong
    • Applied Chemistry for Engineering
    • /
    • v.18 no.6
    • /
    • pp.580-586
    • /
    • 2007
  • In this study, 4 directional carbon/carbon composites with different preform architectures were manufactured and their thermophysical properties are studied. Carbon fiber preforms are fabricated with fiber bundles using four different spaces. The density of the fabricated preforms were increased through pressure impregnation and carbonizing process. The increased density of the composites was graphitized at $2300^{\circ}C$. Microstructures of these composite were observed under scanning electron microscope. This was to understand the effect the preform architectures has on the thermophysical properties of carbon/carbon composites. Also, the behavior of thermal conduction and heat expansion was investigated and studied in association with the factors of the reinforced direction of fibers and unit cell of preforms.

Fabrication of Nanofiber-Combined 3D Scaffolds using Dual-Head Deposition Technology (듀얼헤드 적층 기술을 이용한 나노섬유로 결합된 3D 인공지지체 제작)

  • Sa, Min-Woo;Lee, Chang-Hee;Kim, Jong Young
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.17 no.1
    • /
    • pp.108-115
    • /
    • 2018
  • In bone tissue engineering, polycaprolactone (PCL) is one of the most widely used biomaterials to manufacture scaffolds as a synthetic polymer with biodegradability and biocompatibility. The polymer deposition system (PDS) with four axis heads, which can dispense bio-polymers, has been used in scaffold fabrication for tissue engineering applications. A dual-head deposition technology of PDS is an effective technique to fabricate 3D scaffolds. The electrospinning technology has been widely used to fabricate porous and highly interconnected polymer fibers. Thus, PDS can fabricate nanofiber-combined hybrid scaffolds using fused deposition modeling (FDM) and electrospinning methods. This study aims to fabricate nanofiber-combined scaffolds with uniform nanofibers using PDS. The PCL nanofibers were fabricated and evaluated according to the fabrication process parameters. PCL nanofibers were successfully fabricated when the applied voltage, tip-to-collector distance, flow rate, and solution concentration were 5 kV, 1 cm, 0.1 ml/h, and 8 wt%, respectively. The cell proliferation was evaluated according to the electrospinning time. Scanning electron microscopy was used to acquire images of the cross-sectioned hybrid scaffolds. The cell proliferation test of the PCL and nanofiber-combined hybrid scaffolds was performed using a CCK-8 assay according to the electrospinning time. The result of in-vitro cell proliferation using osteosarcoma MG-63 cells shows that the hybrid scaffold has good potential for bone regeneration.