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http://dx.doi.org/10.5764/TCF.2012.24.2.145

Preparation and Properties of Poly(ethylene terephthalate)(PET)/Polyamide-6(PA6) Alloy Fibers using Epoxy as a Reactive Compatibilizer: I. Effect of Epoxy on the Phase Separation of PET/PA6 Alloys  

Zhou, Jing (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Min, Byung-Gil (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Lim, Mok-Keun (Rhodia Korea)
Lee, Kwang-Sang (Rhodia Korea)
Yu, Yeong-Chool (Rhodia Korea)
Han, Jae-Sung (Korea Textile Development Institute)
Publication Information
Textile Coloration and Finishing / v.24, no.2, 2012 , pp. 145-151 More about this Journal
Abstract
Polymer alloys of poly(ethylene terephthalate)(PET) and nylon6(PA6) which were not miscible each other by themselves were successfully prepared through melt compounding using a twin-screw extruder by utilizing epoxy as reactive compatibilizer. At the epoxy(DGEBA) amount of 0.5~2wt%, the domain size(average diameter) of the discontinuous phase could be reduced up to 0.2${\mu}m$ from 1-5${\mu}m$ that of the simple blend without epoxy. The reaction was presumed to happen mostly at interphase from the result of maximum increase of melt viscosity at the middle range of PET/PA6 blend ratio. It is expected that alloy fibers of PET/epoxy/PA6 with enough mechanical strength for use can be prepared.
Keywords
PET; nylon6; blend; alloy; epoxy; reactive compatibilizer;
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