• Title/Summary/Keyword: polymer alloy

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Effects of Aluminium Alloy on the Oxidative Stability of Frying Oil

  • Jong-Youn Son;Soo
    • The Korean Journal of Food And Nutrition
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    • v.7 no.4
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    • pp.318-322
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    • 1994
  • Aluminium alloy, comprising water, silicone manganese and porous aluminium carrier added into soybean oil in order to investigated its effect on polar lipid content, polymer content, conjugated dienoic acid and free fatty acid value during deep-fat frying at 185$^{\circ}C$. Increase rates of polar lipid and polymer content of the frying ell were reduced about one thirds of the oil without aluminium alloy during deep-fat frying. The aluminium alloy, however, have no significantly effect to inhibit the increase of conjugated dienoic acid and free fatty acid value. Treatment of the frying oil with aluminium alloy was found to be able to inhibit polymer and polar lipid formation.

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Thermally Crosslinked Polyimide Binders for Si-alloy Anodes in Li-ion Batteries

  • Chang, Hyeong-Seok;Ji, Sang-Gu;Rho, Miso;Lee, Byoung-Min;Kim, Sung-Soo;Choi, Jae-Hak
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.339-346
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    • 2022
  • Silicon (Si) has attracted considerable attention due to its high theoretical capacity compared to conventional graphite anode materials. However, Si-based anode materials suffer from rapid capacity loss due to mechanical failure caused by large volume change during cycling. To alleviate this phenomenon, crosslinked polymeric binders with strong interactions are highly desirable to ensure the electrode integrity. In this study, thermally crosslinked polyimide binders were used for Si-alloy anodes in Li-ion batteries. The crosslinked polyimide binder was found to have high adhesion strength, resulting in enhanced electrode integrity during cycling. Therefore, the Si-alloy anodes with crosslinked polyimide binder provide enhanced electrochemical performance, such as Coulombic efficiency, capacity retention, and cycle stability.

Effect of Silane Coupling Treatment on the Joining and Sealing Performance between Polymer and Anodized Aluminum Alloy

  • Lee, Sung-Hyung;Yashiro, Hitoshi;Kure-Chu, Song-Zhu
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.122-131
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    • 2021
  • In the fabrication of joined materials between anodized aluminum alloy and polymer, the performance of the metal-polymer joining is greatly influenced by the chemical properties of the oxide film. In a previous study, the dependence of physical joining strength on the thickness, structure, pore formation, and surface roughness of films formed on aluminum alloys is investigated. In this study, we investigated the effect of silane coupling treatment on the joining strength and sealing performance between aluminum alloy and polymer. After a two-step anodization process with additional treatment by silane, the oxide film with chemically modified nanostructure is strongly bonded to the polymer through physical and chemical reactions. More specifically, after the two-step anodization with silane treatment, the oxide film has a three-dimensional (3D) nanostructure and the silane components are present in combination with hydroxyl groups up to a depth of 150 nm. Accordingly, the joining strength between the polymer and aluminum alloy increases from 29 to 35 MPa, and the helium leak performance increases from 10-2-10-4 to 10-8-10-9 Pa ㎥ s-1.

Improvement of joining strength between aluminum alloy and polymer by two - step anodization

  • Lee, Sung-Hyung;Yashiro, Hitoshi;Kure-Chu, Song-Zhu
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.144-152
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    • 2020
  • In the manufacturing process of joining of aluminum alloy and polymer, the strength of the metal-polymer joining is greatly influenced by the nanostructure of the oxide film. In this study, we investigated the dependence of joining strength on the thickness, structure, pore formation and surface roughness of the formed film. After the two-step anodization process, the surface oxide layer became thinner and rougher resulting in higher joining strength with the polymer. More specifically, after the two-step anodization, the surface roughness, Ra increased from 2.3 to 3.2 ㎛ with pore of three-dimensional (3D) nanostructure, and the thickness of the oxide film was thinned from 350 to 250 nm. Accordingly, the joining strength of the aluminum alloy with polymer increased from 23 to 30 MPa.

Solid State Interfacial Phenomena of High Performance Two Phase Polymer System(I) -Preparation and Characteristics of Liquid Crystalline Polyester and Poly(ε-caprolactam) Alloy- (고기능 고분자 복합재의 고상계면 현상에 대한 연구(I) -액정 Polyester와 Poly(ε-caprolactam) Alloy의 제조와 그 특성)

  • Kang, Doo Whan;Kang, Ho Jong;Jung, Hyo Sung;Lee, Yong Moo
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.49-58
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    • 1997
  • LCP/PA alloy was prepared by blending poly(${\varepsilon}-caprolactam$) (PA) with liquid crystal polyester, Vectra (LCP) having high elasticity and strength. The alloy prepared amorphous PA with more than 10 parts of thermotropic LCP had poor compatibility. To increase the compatibility of the alloy, compatibilizing agent, poly(glycinylmaleimide-co-methylmetacrylate)[poly(GMI-co-MMA)] copolymer was prepared by copolymerizing N-glycinylmaleimide(GMI) with methylmetacrylate(MMA). And then, it was blended with LCP and PA to produce LCP/PA alloy having an excellent compatibility. The compatibility characteristics of the alloy prepared from LCP and PA using the poly(GMI-co-MMA) was determined by measuring the thermal characteristics of glass transition temperature of nematic LCP, and rheological properties, and also high rate impact and flexual characteristics of the alloy were determined.

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Fabrication and Sensorization of a Superelastic Alloy Microrobot Gripper using Piezoelectric Polymer Sensors (초탄성 마이크로 그리퍼의 제작 및 압전폴리머 센서를 이용한 센서화)

  • 김덕호;김병규;강현재;김상민
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.251-255
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    • 2003
  • This paper presents the design, fabrication, and calibration of a piezoelectric polymer-based sensorized microgripper. Electro discharge machining technology is employed to fabricate super-elastic alloy based micro gripper. It is tested to present improvement of mechanical performance. For integration of force sensor on the micro gripper, the sensor design based on the piezoelectric polymer PVDF film and fabrication process are presented. The calibration and performance test of force sensor integrated micro gripper are experimentally carried out. The force sensor integrated micro gripper is applied to perform fine alignment tasks of micro opto-electrical components. It successfully supplies force feedback to the operator through the haptic device and plays a main role in preventing damage of assembly parts by adjusting the teaching command.

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Design, Fabrication, and Performance Evaluation of a Sensorized Superelastic Alloy Microrobot Gripper (센서화된 초탄성 마이크로그리퍼의 설계, 제작 및 성능평가)

  • Kim, Deok-Ho;Kim, Byung-Kyu;Kang, Hyun-Jae;Kim, Sang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.10
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    • pp.1772-1777
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    • 2003
  • This paper presents the design, fabrication, and calibration of a piezoelectric polymer-based sensorized microgripper. Electro discharge machining technology is employed to fabricate super-elastic alloy based micro gripper. It is tested to present improvement of mechanical performance. For integration of force sensor on the micro gripper, the sensor design based on the piezoelectric polymer PVDF film and fabrication process are presented. The calibration and performance test of force sensor integrated micro gripper are experimentally carried out. The force sensor integrated micro gripper is applied to perform fme alignment tasks of micro opto-electrical components. It successfully supplies force feedback to the operator through the haptic device and plays a main role in preventing damage of assembly parts by adjusting the teaching command.

Annealing Effect on Magnetic Properties and Electromagnetic Absorption Behaviors for Fe-Cr Alloy Powder-Polymer Composites

  • Lee, Sung-Jae;Kim, Yoon-Bae;Lee, Kyung-Sub;Kim, Sang-Woo
    • Journal of Magnetics
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    • v.12 no.1
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    • pp.49-52
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    • 2007
  • We investigated annealing effect of microforged powders on magnetic properties and electromagnetic absorption behaviors for ferromagnetic Fe-Cr metal alloy powder-polymer composites. The coercive properties greatly decreased with annealing temperature and the magnetic permeability had significantly increased after microforging and subsequent annealing treatment, due to a reduction in lattice strain of the microforged powders. The power loss in the far field regime also had greatly increased after microforging and subsequent annealing treatment in frequency range from 50 MHz to 6 GHz. As a result, the electromagnetic absorption of ferromagnetic Fe-Cr alloy metal powder-polymer composites was highly improved because of the relaxation of the internal strain during annealing process.

Electromagnetic Wave Absorption Characteristics of Nanocrystalline FeCuNbSiB Alloy Flakes/Polymer Composite Sheets with Different Flake Thickness

  • Lee, Tae-Gyu;Kim, Ju-Beom;Noh, Tae-Hwan
    • Journal of Magnetics
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    • v.14 no.4
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    • pp.155-160
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    • 2009
  • This study examined the effects of a decrease in thickness of magnetic alloy flakes on the electromagnetic wave absorption characteristics of nanocrystalline $Fe_{73.5}Cu_1Nb_3Si_{15.5}B_7$ (at.%) alloy flakes/polymer composite sheets available for a quasi-microwave band. The thickness of FeCuNbSiB alloy flakes decreased to 1-2 $\mu$m with increasing milling time up to 24 h, and the composite sheet including alloy flakes milled for 24 h exhibited considerably enhanced power loss properties in the GHz range compared to the sheets having non-milled alloy powders. Although a considerable increase in loss factor upon milling was observed in the narrow frequency range of 4-6 GHz, there was no correlation between the complex permeability and flake thickness. However, the complex permittivity increased with increasing milling time, and there was good agreement between the milling time and the frequency dependences of the complex permittivity and power loss.