• Title/Summary/Keyword: polymer aerogel

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Characterization of Mechanical Property Change in Polymer Aerogels Depending on the Ligand Structure of Acrylate Monomer

  • Lee, Kyu-Yeon;Jung, Hae-Noo-Ree;Mahadik, D.B.;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.15-20
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    • 2016
  • In an effort to overcome the weakness of aerogel, polymer aerogels have been prepared by copolymerizing the different types of monomers through sol-gel process. Polymerizing the successive phase of a high internal phase emulsion, which has interconnected porous structure, porous polymer aerogel can be manufactured. In this paper, we use the styrene/divinylbenzene chain as a basic monomer structure, and additionally use 2-ethylhexyl methacrylate (2-EHMA) or 2-ethylhexyl acrylate (2-EHA) as monomers for distinguishing the visible mechanical properties of synthesized polymer aerogel. We can observe the different tendency of polymer aerogels by kinds of monomer or ratio. Flexibility and microstructure can be changed by the types of monomer. EHA polymer aerogel shows high flexibility and thin microstructure, and EHMA polymer aerogel shows high hardness and thick microstructure. EHA/EHMA polymer aerogel shows the intermediate nature between them. By utilizing the mechanical properties of three types of polymer aerogels to adequate situation or environment, polymer aerogels could be used as drug agent, ion exchange resin, oil filter and insulator, and so on.

Introduction to Thermal Insulating Materials and Silica Aerogels (열 차단 소재와 실리카 에어로젤 개요)

  • Hong, Jin-Ho;Kim, Il;Yun, Ju-Ho;Shim, Sang-Eun
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.29-36
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    • 2011
  • The term 'thermal insulating materials' describes a class of materials which can improve the thermal efficiency by reducing the thermal conduction, convention and radiation between the inside and outside of the system. As a thermal insulating material, numerous industrial applications are possible including the automobile, aerospace, aviation, and petrochemical. Especially, the silica aerogel, with their superior thermal insulating behavior, has been widely used as thermal insulating materials. Because the mechanical properties of the silica aerogel cannot meet the industrial demand, use of the silica aerogel is limited. This article aims to review the thermal insulating materials and silica aerogel, and to introduce the silica aerogel/polymer composites.

Surface Properties of the High Porous Carbon Aerogels (고다공성 카본 에어로젤(C-Aerogel) 표면 특성)

  • Kim, Ji-Hye;Lee, Chang-Rae;Jeong, Young-Soo;Kim, Yang-Do;Kim, In-Bae
    • Journal of the Korean institute of surface engineering
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    • v.41 no.3
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    • pp.114-120
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    • 2008
  • The pyrolysized carbon xerogel and aerogels were prepared from the sol-gel polymerization of resorcinol-formaldehyde(RF) followed by the dry process under ambient pressure and supercritical carbon dioxide condition respectively. The thermal behaviour of RF polymer xerogel was investigated with TGA analyzer to correspond with the pyrolysis process. The surface properties such as particle size, morphology and the point of zero charge of the pyrolysized porous carbon aerogels were studied for the precious metal catalyst supported media. It was found that the volume of the polymer aerogel decreased because of the significant linear shrinkage and weight loss of polymer gel during the carbonization. The point of zero charge of the carbon aerogel pyrolysized at $1050^{\circ}C$ under inert gas flow was about 10.

Polyurea Cross-linked Silica Aerogel with Improved Mechanical Strength by Applying a Precursor Having a Plurality of Amino Groups (복수의 아민기를 가지는 전구체를 적용하여 기계적 강도를 향상시킨 폴리우레아 가교 실리카 에어로겔)

  • Lee, Wonjun;Kim, Taehee;Choi, Haryeong;Kim, Jiseung;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.15-20
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    • 2022
  • Aerogel is a material having a nanopore structure based on a high porosity. Due to this high porosity, it has excellent properties not found in conventional materials, but its application has been limited due to low mechanical strength. Therefore, to improve the mechanical strength of the aerogel, polyurea crosslinking was introduced and a precursor having an amine group essential for polyurea polymer formation was selected to synthesize a polyurea crosslinked aerogel composite. In addition, the crosslinking of polyurea was adjusted according to the number of amine groups present in aminosilane. It was confirmed through various analyses that the nanopore structure of the aerogel was maintained to have mesopores. The aerogel thus formed was able to improve the mechanical strength by about two times, and it was confirmed through field emission scanning electron microscope analysis that a one-dimensional polymer was formed on the silica aerogel surface through the introduction of ethylene diamine. The one-dimensional polymer thus formed has improved mechanical properties, resulting in securing an elastic modulus of about 2.66 MPa.

A Study on Physical Characteristics of Silica Aerogel/Polymer Composite Materials (실리카 에어로겔/고분자 복합재의 물리적 특성에 관한 연구)

  • Park, Kyoungwoo;Lee, Yeon;Yoon, Jong-Kuk;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.9
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    • pp.1318-1323
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    • 2013
  • Thermal insulation material was prepared by cross-linking chemical reaction of silica aerogel and epoxy resin, which has a high porous and vacant properties. The structural, mechanical, and thermal properties were analyzed in order to verify its application for industrial and electrical applications. The thermal conductivities were changed from 115 mW/mK to 75 mW/mK by reducing the contents of nano-porous silica areogel powders. The compressive loading is also decreased by increasing the contents of silica aerogels by 20 wt% in aerogel/epoxy composites. It is concluded that the formulated composite materials can be applied to building materials, electronics parts, and heavy industries.

A Study on Properties of Thermal Insulation Board Prepared by Porous Silica Aerogel (다공성 실리카 에어로겔을 이용한 복합단열재의 특성에 관한 연구)

  • Yoon, Jong-Kuk;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.9
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    • pp.1362-1367
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    • 2012
  • High porous silica aerogel/polyurethane polymer composite was manufactured by cross-linking polymerization of polyurethane foaming process. The properties of microstructure, mechanical strength, and thermal properties were investigated for its various applications. The superhydrophobic silica aerogel powders were used for highly thermal insulation filler materials. The thermal conductivities can be resulted 0.07 W/mK to 0.13 W/mK, by decreasing the contents of silica aerogels in composite materials. It is found that the polymerization formulation by organic binders can be applied to heavy industires, building materials, and various industries.

Mechanical Behavior of Polymer Foam Reinforced with Silica Aerogel (실리카 에어로겔을 첨가한 폴리머 폼의 기계적 특성)

  • Ahn, Jae-Hyeok;Kim, Jeong-Hyeon;Kim, Jeong-Dae;Park, Sungkyun;Park, Kang Hyun;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.31 no.6
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    • pp.413-418
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    • 2017
  • In the present study, silica-aerogel-polyurethane foams were synthesized to improve the mechanical characteristics and insulation performance of the polyurethane foam applied to a liquefied natural gas carrier at a cryogenic temperature of $-163^{\circ}C$. A silica-aerogel-polyurethane foam bulk was prepared using a homogenizer by varying the weight ratio of the silica aerogel (0, 1, 3, and 5 wt%), while maintaining the contents of the polyol, isocyanate, and blowing agent constant. Compression tests were performed at room and cryogenic temperatures to compare the mechanical properties of the silica-aerogel polyurethane foams. The internal temperature of the universal testing machine was maintained through the cryogenic chamber. The thermal conductivity of the silica-aerogel-polyurethane foam was measured using a heat flow meter to confirm the insulation performance. In addition, the effect of the silica aerogels on the cells of the polyurethane foam was investigated using FE-SEM and FTIR. From the experimental results, the 1 wt% silica aerogel polyurethane foam showed outstanding mechanical and thermal performances.

Influence of Nitrogen moieties on CO2 capture of Carbon Aerogel

  • Jeon, Da-Hee;Min, Byung-Gak;Oh, Jong Gab;Nah, Changwoon;Park, Soo-Jin
    • Carbon letters
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    • v.16 no.1
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    • pp.57-61
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    • 2015
  • Carbon aerogel is a porous carbon material possessing high porosity and high specific surface area. Nitrogen doping reduced the specific surface area and micropores, but it furnished basic sites to improve the $CO_2$ selectivity. In this work, N-doped carbon aerogels were prepared with different ratios of resorcinol/melamine by using the sol-gel method. The morphological properties were characterized by scanning electron microscopy (SEM). Nitrogen content was studied by X-ray photoelectron spectroscopy (XPS) and the specific surface area and micropore volume were analyzed by $N_2$ adsorption-desorption isotherms at 77 K. The $CO_2$ adsorption capacity was investigated by $CO_2$ adsorption-desorption isotherms at 298 K and 1 bar. Melamine containing N-doped CAs showed a high nitrogen content (5.54 wt.%). The prepared N-doped CAs exhibited a high $CO_2$ capture capacity of 118.77 mg/g (at resorcinol/melamine = 1:0.3). Therefore, we confirmed that the $CO_2$ adsorption capacity was strongly affected by the nitrogen moieties.

Synthesis of Polyimide Crosslinked Silica-based Aerogel with Enhanced Mechanical Properties and Its Physico-chemical Properties (폴리이미드 가교로 기계적 강도가 향상된 실리카 기반 에어로겔의 합성 및 물리화학적 특성 분석)

  • Kim, Jiseung;Choi, Haryeong;Kim, Taehee;Lee, Wonjun;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.9-14
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    • 2022
  • Silica aerogel is a porous material with a very low density and high specific surface area. Still, its application is limited due to its weak mechanical properties due to structural features. To solve this problem, a method of complexing it with various polymers has been proposed. We synthesized polyimide cross-linked silica aerogel by the sol-gel process to obtain high mechanical properties. Tetraethyl orthosilicate (TEOS) was used as a precursor to make silica aerogel, and 3- aminopropyltriethoxysilane (APTES) was used as a coupling agent for cross-linking polyimide. Polyimide was synthesized using pyromellitic dianhydride and 3,5-diaminobenzoic acid, and mechanical properties were improved by crosslinking polyimide with 10 repeating units in the polyimide chain using the reaction formula ${\frac{n_1}{n_2}}={\frac{n}{n+1}}$ To realize silica aerogel, polyimide having various weight ratios was added before gelation, resulting in a 19-fold or greater increase in maximum compressive strength compared to pure silica aerogel. From this study, an enhancement of silica aerogel could be enhanced through polymer cross-linking bonds.

A review: synthesis and applications of graphene/chitosan nanocomposites

  • Yuan, Hui;Meng, Long-Yue;Park, Soo-Jin
    • Carbon letters
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    • v.17 no.1
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    • pp.11-17
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    • 2016
  • Recently, with continuous developments in the field of materials science, graphene oxide (GO) has emerged as a promising material with excellent electrical, thermal, mechanical, and optical properties, which play important roles in most fields. Researchers have achieved considerable progress with graphene. Chitosan (CS) is a natural polymer that has been studied intensively owing to its specific formation, high chemical resistance, and excellent physical properties. These outstanding properties have led to its universal use in applications such as textile fabrics, tissue engineering, medicine and health, coatings, and paints. By combining the advantages of GO and CS, different types of promising materials can be obtained. This review discusses the preparation of GO-CS fibers, hydrogel and aerogel, and the applications of GO-CS nanocomposites. In addition, directions for future research on graphene material composites are discussed.