• Proceedings of the Korean Society of Rheology Conference
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• 2006.06a
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• pp.191-194
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• 2006

• Journal of the Microelectronics and Packaging Society
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• v.26 no.4
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• pp.55-62
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• 2019

Stiffness-gradient stretchable electronic packages of the soft PDMS/hard PDMS/FPCB structure were processed using the polydimethylsiloxane (PDMS) as the base substrate and the more stiff flexible printed circuit board (FPCB) as the island substrate. The elastic characteristics of the stretchable packages were estimated and their long-term reliabilities on stretching cycles and bending cycles were characterized. With 0.28 MPa, 1.74 MPa, and 1.85 GPa as the elastic moduli of the soft PDMS, hard PDMS, and FPCB, respectively, the effective elastic modulus of the soft PDMS/hard PDMS/FPCB package was estimated as 0.6 MPa. The resistance of the stretchable packages varied for 2.8~4.3% with stretching cycles ranging at 0~0.3 strain up to 15,000 cycles and for 0.9~1.5% with 15,000 bending cycles at a bending radius of 25 mm.

• Journal of the Microelectronics and Packaging Society
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• v.26 no.4
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• pp.47-53
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• 2019

Stiffness-gradient stretchable electronic packages of the soft PDMS/hard PDMS/PTFE structure were processed using the polydimethylsiloxane (PDMS) as the base substrate and the more stiff polytetrafluoroethylene (PTFE) as the island substrate, and their stretchable deformation-resistance characteristics were characterized. The flip-chip joints, formed by bonding the chip bumps of 50 ㎛-diameter onto the PDMS/PTFE substrate pads, exhibited an average contact resistance of 96 mΩ. When the stretchable package of the soft PDMS/hard PDMS/PTFE structure was deformed to 30% elongation, the strain on the PTFE was restrained to 1%, resulting in a negligible resistance increase of 1% in the daisy-chain circuit formed on the PTFE island substrate. The circuit resistance increased for 1.7% after 2,500 cycles of 0~30% stretchable deformation.

• Journal of the Microelectronics and Packaging Society
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• v.25 no.4
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• pp.111-118
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• 2018

In order to develop a local stiffness-variant stretchable substrate with the soft PDMS/hard PDMS/FPCB configuration consisting of two stiffness-different polydimethylsiloxane (PDMS) parts and flexible printed circuit board, a FPCB was bonded to PDMS using the acrylic-silicone double-sided tape and the interfacial adhesion of the PDMS/FPCB was evaluated. The pull strength of the FPCB, which was bonded to the fully cured PDMS using the silicone adhesive of the double-sided tape, was 259 kPa and the delamination during the pull test occurred at the interface between the PDMS and the silicone adhesive. On the contrary, the bonding process, for which the FPCB was bonded using the silicone adhesive to the PDMS partially cured for 15~20 minutes at $60^{\circ}C$ and then the PDMS was fully cured for 12 hours at $60^{\circ}C$, exhibited the remarkably enhanced pull strength of 1,007~1,094 kPa. With the above mentioned bonding process, the delamination during the pull test was observed at the interface between the FPCB and the acrylic adhesive of the acrylic-silicone double sided tape.

• Polymer(Korea)
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• v.37 no.2
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• pp.167-176
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• 2013

Linear and cross-linked waterborne polyurethanes (WPUs) based on isophorone diisocyanate and mixed diols of poly(tetramethylene glycol)/hydroxyethyl-terminated polydimethylsiloxane (PDMS-OH) were synthesized with dimethylol propionic acid as an anionic component, trimethylolpropane as a cross-linking agent, and butanediol as a chain extender and characterized. The hydrophobicity, $T_g$, stress-strain behaviors of the linear or cross-linked siloxane-containing WPU (WPU-Si) films with different PDMS content were analyzed by using water contact shape analyzer, energy dispersive spectrometer, dynamic mechanical analyzer, and universal testing machine. The results reveal that as the PDMS content increased, the hydrophobicity of WPU-Si films increased, $T_g$ moved to higher temperature, the breaking stress increased, and the breaking strain decreased.

• Membrane Journal
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• v.9 no.1
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• pp.51-62
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• 1999

The recovery of trace volatile organic components from water by pervaporation was investigated. Permeation experiments through homogeneous polydimethylsiloxane(PDMS) membrane was carried out and the effect of feed concentrations and membrane thicknesses on the permeation characteristics were investigated. A solution-diffusion model is used to describe the pervaporation transport mechanism. In homogeneous PDMS membrane it appeared that the selectivities of MEK and toluene are constant, and that organic flux has a linear relationship with feed concentration. These results indicate that the coupling effects between organics were negligible. The selectivity of PDMS membranes is invariant with respect to the membrane thickness. The intrinsic membrane permeability of organic components determined by using a solution-diffusion model. Comparing with various composite type membrane, the membrane using PEG treated nonwoven fabric as sublayer showed the best performance in VOC recovery by pervaporation.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.8
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• pp.823-829
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• 2014

In the present study, simple models were proposed to predict the capillary-driven flow length in a surfactant-added poly(dimethylsiloxane) (PDMS) rectangular microchannel. Owing to the hydrophobic nature of PDMS, it is difficult to transport water in a conventional PDMS microchannel by means of the capillary force alone. To overcome this problem, microchannels with a hydrophilic surface were fabricated using surfactant-added PDMS. By measuring the contact angle change on the surfactant-added PDMS surface, the behavior was investigated to establish a simple model. In order to predict the filling length induced by the capillary force, the Washburn equation was modified in the present study. From the investigation, it was found that the initial rate-of-change of the contact angle affected the filling length. Simple models were developed for three representative cases, and these can be useful tools in designing microfluidic manufacturing techniques including MIcroMolding In Capillaries (MIMIC).

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.140-146
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• 1990

Polydimethylsiloxane(PDMS) containing [N, N'-bis (3- (salicylidene amino) propyl) amine Co(II)] (Co(saldpt)) as a fixed oxygen carrier was synthesized. UV-visible spectra of the membrane demonstrated that Co(saldpt) binded molecular oxygen specificaaly and reversibly. From time lag method experiment, it was found that both oxygen permeability and diffusibity increase with decreasing upstream pressure, while solubility maintain nearly constant. The maximum oxygen permeability and oxygen selectivity over nitrogen obtained was 18.6 barrer and 4, respectively, at 25 mmHg and $40^{\circ}C$ from the the PDMS membrane containing 1 wt% of Co(saldpt). Facilitation behavior was explained in terms of the dual sorption model.

• Journal of the Microelectronics and Packaging Society
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• v.24 no.3
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• pp.27-34
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• 2017

We investigated the feasibility of parylene F usage as an intermediate layer between a polydimethylsiloxane (PDMS) substrate and an Au thin-film interconnect as well as the swelling effect of PDMS substrate on the stretchable deformability of an Au thin film. The 150-nm-thick Au film, which was sputtered on a PDMS substrate without a parylene F layer, exhibited an initial resistance of $11.7{\Omega}$ and an overflow of its resistance at a tensile strain of 12.5%. On the other hand, the Au film, which was formed with a 150-nm-thick parylene F layer, revealed an much improved resistance characteristics: $1.21{\Omega}$ as its initial resistance and $246{\Omega}$ at its 30% elongation state. With swelling of PDMS substrate, the resistance of an Au film substantially decreased to $14.4{\Omega}$ at 30% tensile strain.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.257-257
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• 2013

In order to selectively remove oil and organic compound from water, silica nanoparticles with hydrophobic coating was used. Since silica nanoparticles are generally hydrophilic, removal efficiency of oil and organic compound, such as toluene, in water can be decreased due to competitive adsorption with water. In order to increase the removal efficiency of oil and toluene, hydrophobic polydimethylsiloxane (PDMS) was coated on silica nanoparticles in the form of thin film. Hydrophobic property of the PDMS-coated silica nanoparticles and hydrophilic silica nanoparticles were easily confirmed by putting it in the water, hydrophilic particle sinks but hydrophobic particle floats. PDMS coated silica nanoparticles were dispersed on a slide glass with epoxy glue on and the water contact angle on the surface was determined to be over $150^{\circ}$, which is called superhydrophobic. FT-IR spectroscopy was used to check the functional group on silica nanoparticle surface before and after PDMS coating. Then, PDMS coated silica nanoparticles were used to selectively remove oil and toluene from water, respectively. It was demonstrated that PDMS coated nanoaprticles selectively aggregates with oil and toluene in the water and floats in the form of gel and this gel remained floating over 7 days. Furthermore, column filled with hydrophobic PDMS coated silica nanoparticles and hydrophilic porous silica was prepared and tested for simultaneous removal of water-soluble and organic pollutant from water. PDMS coated silica nanoparticles have strong resistibility for water and has affinity for oil and organic compound removal. Therefore PDMS-coated silica nanoparticles can be applied in separating oil or organic solvents from water.