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http://dx.doi.org/10.7317/pk.2013.37.2.167

Synthesis and Characterization of Waterborne Polyurethanes Based on Isophorone Diisocyanate and Mixed Polyols of Poly(tetramethylene glycol)/Polydimethylsiloxane Diol  

Lee, Ji Hye (Department of Organic Materials and Fiber Engineering, Soongsil University)
Hong, Seongdon (Department of Organic Materials and Fiber Engineering, Soongsil University)
Kim, Young Ho (Department of Organic Materials and Fiber Engineering, Soongsil University)
Publication Information
Polymer(Korea) / v.37, no.2, 2013 , pp. 167-176 More about this Journal
Abstract
Linear and cross-linked waterborne polyurethanes (WPUs) based on isophorone diisocyanate and mixed diols of poly(tetramethylene glycol)/hydroxyethyl-terminated polydimethylsiloxane (PDMS-OH) were synthesized with dimethylol propionic acid as an anionic component, trimethylolpropane as a cross-linking agent, and butanediol as a chain extender and characterized. The hydrophobicity, $T_g$, stress-strain behaviors of the linear or cross-linked siloxane-containing WPU (WPU-Si) films with different PDMS content were analyzed by using water contact shape analyzer, energy dispersive spectrometer, dynamic mechanical analyzer, and universal testing machine. The results reveal that as the PDMS content increased, the hydrophobicity of WPU-Si films increased, $T_g$ moved to higher temperature, the breaking stress increased, and the breaking strain decreased.
Keywords
waterborne polyurethane (WPU); isophorone diisocyanate; poly(tetramethylene glycol); polydimethylsiloxane; hydrophobicity;
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1 E. Ayres, R. L. Oréfice, and M. I. Yoshida, Eur. Polym. J., 43, 3510 (2007).   DOI   ScienceOn
2 Y. Lu and R. C. Larock, Biomacromolecules, 9, 3332 (2008).   DOI   ScienceOn
3 M. M. Rahman, H. D. Kim, and W. K. Lee, J. Adhes. Sci. Tech., 23, 177 (2009).   DOI   ScienceOn
4 S. K. Lee and B. K. Kim, J. Colloid Interf. Sci., 336, 208 (2009).   DOI   ScienceOn
5 H. Chen, Q. Fan, and X. Yu, J. Appl. Polym. Sci., 79, 295 (2001).   DOI
6 T. K. Kim, S. J. Kim, and B. K. Kim, Polymer(Korea), 16, 604 (1992).
7 J. B. Ahn, H. K. Cho, C. N. Jeong, and S. T. Noh, J. Korean Ind. Eng. Chem., 8, 230 (1997).
8 M. M. Rahman and W. K. Lee, J. Appl. Polym. Sci., 114, 3767 (2009).   DOI   ScienceOn
9 Y. K. Yang, N. S. Kwak, and T. S. Hwang, Polymer(Korea), 29, 81 (2005).
10 C. C. M. Ma, F. Y. Wang, Y. C. Du, C. L. Wu, C. L. Chiang, and A. Y. C. Hung, J. Appl. Polym, Sci., 86, 962 (2002).   DOI   ScienceOn
11 Y. Kwon, B. S. Yim, J. M. Kim, and J. Kim, Microelectron. Reliab., 51, 819 (2011).   DOI   ScienceOn
12 R. Benrashid and G. L. Nelson, J. Polym. Sci. Part A: Polym. Chem., 32, 1847 (1994).
13 G. Socrates, Infrared and Raman Characteristic Group Frequencies, John Wiley & Sons, New York, Chap. 10-18 (2001).
14 S. L. Chai and M. M. Jin, J. Appl. Polym. Sci., 114, 2030 (2009).   DOI   ScienceOn
15 S. H. Son, I. H. Kim, H. J. Lee, and J. H. Kim, Polymer(Korea), 21, 375 (1997).
16 A. Takahara, J. Tashita, T. Kajiyama, and M. Takayanagi, J. Biomed. Mater. Res., 19, 13 (1985).   DOI   ScienceOn
17 C. H. Cho, H. D. Seo, B. H. Min, H. K. Cho, S. T. Noh, H. G. Choi, Y. H. Cho, and J. H. Kim, J. Korean Ind. Eng. Chem., 13, 825 (2002).
18 ASTM Standard D, 4187-82, American Society for Testing and Materials, USA, 1985.
19 R. S. Chen, C. J. Chang, and Y. H. Chang, J. Polym. Sci. Part A: Polym. Chem., 43, 3482 (2005).   DOI   ScienceOn
20 S. K. Rath, J. G. Chaven, S. Sasane, A. Srivastava, M. Patri, A. B. Samui, B. C. Chakraborty, and S. N. Sawant, Prog. Org. Coat., 65, 366 (2009).   DOI   ScienceOn
21 S. S. Pathak, A. Sharma, and A. S. Khanna, Prog. Org. Coat., 65, 206 (2009).   DOI   ScienceOn
22 Q. Fan, J. Fang, Q. Chen, and X. Yu, J. Appl. Polym. Sci., 74, 2552 (1999).   DOI   ScienceOn
23 S. K. Liao, S. C. Jang, and M. F. Lin, J. Polym. Res., 12, 103 (2005).   DOI
24 A. Saetung, L. Kaenhin, P. Klinpituksa, A. Rungvichaniwat, T. Tulyapitak, S. Munleh, I. Campistron, and J. F. Pilard, J. Appl. Polym. Sci., 124, 2742 (2012).   DOI   ScienceOn
25 M. Sultan, K. M. Zia, H. N. Bhatti, T. Jamil, R. Hussain, and M. Zuber, Carbohyd. Polym., 87, 397 (2012).   DOI   ScienceOn
26 H. T. Kim and M. C. Lee, J. Korean Ind. Eng. Chem., 16, 39 (2005).
27 C. S. Yoo and J. H. Chun, Polym. Sci. Technol., 10, 578 (1999).
28 F. M. B. Coutinho, M. C. Delpech, and L. S. Alves, J. Appl. Polym. Sci., 80, 566 (2001).   DOI   ScienceOn
29 J. E. Lee and H. J. Kim, Polymer(Korea), 29, 172 (2005).
30 J. Y. Kwon and H. D. Kim, Macromol. Res., 14, 373 (2006).   DOI   ScienceOn
31 P. Florian, K. K. Jena, S. Allauddin, R. Narayan, and K. V. S. N. Raju, Ind. Eng. Chem. Res., 49, 4517 (2010).   DOI   ScienceOn
32 E. Y. Shin and H. J. Kim, Polymer(Korea), 35, 171 (2011).