• Proceedings of the KIEE Conference
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• 1989.07a
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• pp.284-286
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• 1989

This paper describes the synthesis method of polyaniline and the characteristics of polyaniline/Zn and polyaniline/Li secondary batteries. Polyaniline was synthesized chemical or electrochemical method and then used as cathod active materials to investigate the characteristics of polyaniline/Zn and polyaniline/Li secondary batteries. Characteristics of polyaniline/Zn battery was affected by additives such as graphite powder and carbon black. Internal resistance, energy density and energy efficiency of polyaniline/Li secondary battery were $167{\Omega}$, 140.7 Wh/kg and 95.6%, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.144-148
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• 1997

We synthesized polyaniline films electrochemically under constant current conditions, which exhibited electric conductivity as high as 100 S/cm. By charge and discharge cycling of polyaniline films, we obtained specific discharge capacity as high as 195 mAH/g using HSO$_4$- doped polyaniline. For the polyaniline synthesized using H$_2$SO$_4$ and HClO$_4$ composite electrolyte. we also obtained specific discharge capacity as high as 134 mAHg which rivals inorganic electro- active materials.

• Korean Membrane Journal
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• v.6 no.1
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• pp.37-43
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• 2004

Comb-type graft hydrogels composed of alginate and poly(N-isopropylacrylamide) (PNIPAAm) were prepared to manifest rapid temperature and pH sensitivity. To appear the electro-sensitivity, the polyaniline, conducting polymer, was added into the matrix. The swelling kinetics and ratios were compared under the various compositions of polyaniline. The swelling behaviors revealed that conducting polymer/hydrogel composites could control the swelling ratio and kinetics. The addition of polyaniline in the matrix improved the thermal stability in comparison with that of the hydrogel without polyaniline. In temperature sensitivity, the adding the polyaniline into the matrix decreased the degree of change in the swelling ratio. The swelling ratios continuously increased with increasing pH values. The drug release rate from the hydrogel increased with the adding the polyaniline and the applying the direct voltage to the hydrogels.

• Electrical & Electronic Materials
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• v.10 no.7
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• pp.713-718
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• 1997

Polyaniline free standing films cast from N-methyl-2-pyrrolidinone(NMP) solution, camphorsulfonic acid(HCSA), dodecylbenzensulfonic acid(HDBSA), inorganic matter(carbon black, graphite) and metal(silver) were prepared by processings. The properties of these films such as crystallinity, near-infrared absorption spectra and conductivity were investigated. The HCSA and HDBSA doped polyaniline films cast from m-cresol and chloroform solvents showed the metallic property and high crystallinity, respectively. The value of conductivity in the HCSA doped polyaniline film obtained 180 S/cm. We have obtained the value of conductivity 200 S/cm in the metal(silver) doped polyaniline film, which is higher than that of the HCSA doped polyaniline film. The metal(silver) doped polyaniline film shows good properties as a electromagnetic shielding material.

• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.333-336
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• 1999

The polyaniline films with various insoluble parts are fabricated. The oxidation state (1-y) of these polyaniline is 0.53 and 0.54, respectively. To control the interchain and intrachain interaction of the polymer, the polyaniline films are stretched with appropriate ratio. The insoluble part of polyaniline synthesized at room temperature (low molecular weight) is 12%-76% and that of polyaniline synthesized at 0 'IC (intermediate molecular weight) is 65%-89%. The low molecular weight polyaniline films with various drawing ratios have amorphous structure. In the intermediate weight polyaniline films, the crystallinity of films increases with drawing ratio as well as insoluble part. The difference of the insoluble part affects electrical conductivity which is increased dramatically with draw ratio. In particular, the higher insoluble part caused greater increase in electrical conductivity.

• Korean Journal of Materials Research
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• v.13 no.9
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• pp.625-630
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• 2003

Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as Polyaniline(PANI). Polyaniline films were electrosynthesized by oxidation of aniline on cold rolled and weathering sheets using the potentiostatic mode from an aqueous oxalic acid medium. Potentiodynamic polarization curves were obtained for cold rolled and weathering sheets in the aqueous solution of 3% sodium chloride. The structure and properties of polyaniline film were elucidated using SEM, DSC, SST. A high corrosion resistance of polyaniline films were observed with a gain of the corrosion potential around 600-900 mV positive in the substrate covered with polyaniline than in the case without it.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1457-1459
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• 2003

Space charge distributions and behaviors of polystyrene/polyaniline conducting blends were investigated using a pulsed electroacoustic(PEA) method. It was found that positive charges were accumulated near the cathode with increasing polyaniline content in polystyrene/polyaniline when electric field was applied. Breakdown phenomena was investigated by breakdown test and it was observed that dielectric strength was diminished as polyaniline content was increased. By Scanning Electron Microscopy, corss-sectional views of polystyrene/polyaniline conducting blends were observed that the particles of polyaniline were well distributed in polystyrene.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1989.06a
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• pp.26-28
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• 1989

In this paper, The preparation and characteristics of polyaniline/Zn battery by (NH$_4$)$_2$S$_2$O$\sub$8/ and used as cathod active material to investigate the characteristics of polyaniline/Zn battery. Characteristics of polyaniline/Zn battery was affected of amounts of electrolytes and additives such as graphite and carbon black.

• KSTLE International Journal
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• v.7 no.1
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• pp.1-4
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• 2006

The electro rheological behavior of the hollow polyaniline pimelate suspension in silicone oil was investigated. Hollow polyaniline pimelate suspension showed a typical ER response (Bingham flow behavior) upon application of an electric field. The shear stress for the suspension exhibited the dependence with a factor equals to 0.84 power on the electric field. The experimental results for the hollow polyaniline pimelate suspension correlated with the conduction models of Tang et al., and this suspension behaved as an ER fluid.

• KSTLE International Journal
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• v.9 no.1_2
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• pp.36-38
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• 2008

The electrical and rheological behavior of the hollow polyaniline glutarate suspension in silicone oil was investigated. Hollow polyaniline glutarate suspension showed a typical ER response (Bingham flow behavior) under a DC electric field. The shear stress for the suspension exhibited the dependence with a factor equals to 0.95 power on the electric field. The experimental results for the hollow polyaniline glutarate suspension behaved as an ER fluid.