• Title/Summary/Keyword: poly paper

Search Result 882, Processing Time 0.022 seconds

Thermal Stability and Lifetime Prediction of PAG and POE Oils for a Refrigeration System

  • Park, Keun-Seo;Kang, Byung-Ha;Park, Kyoung-Kuhn;Kim, Suk-Hyun
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • v.15 no.2
    • /
    • pp.78-83
    • /
    • 2007
  • An experimental study has been carried out to analyze the thermal stability and to estimate the lifetime of refrigerating lubricants. PAG and POE oil are considered as test oils in this study. The viscosity of PAG and POE oil was measured by the vibration type viscometer while temperature is varied periodically in the range of $0^{\circ}C{\sim}100^{\circ}C$. In order to estimate lifetime of PAG and POE oil with temperature, the viscosity was measured while the test temperature of oils was maintained continuously at $180,\;200\;and\;220^{\circ}C$. The lifetime of oils is estimated as the decrease in viscosity change by 15%. The results indicate that the reduction rates of viscosity of PAG and POE oil are less than 5% after 510 temperature variation cycles. However, when the oils are kept at high temperature, it is found that the lifetimes of PAG oil is seen to be 244, 177 and 89 hours at the test temperature of $180,\;200\;and\;220^{\circ}C$, respectively, where as the lifetimes of POE oil are estimated to be 1,744, 1,007 and 334 hours at the temperature of $180,\;200\;and\;220^{\circ}C$, respectively. Thus, the lifetime of POE oil is found to be much longer than that of PAG oil. The lifetime correlations of PAG and POE oil are also obtained by Arrhenius's equation method in this paper.

Free Radical Polymerization Algorithm for a Thermoplastic Polymer Matrix : A Molecular Dynamics Study (무정형 열가소성 고분자의 자유 라디칼 중합 분자동역학 시뮬레이션 알고리즘)

  • Jung, Ji-Won;Park, Chan-Wook;Yun, Gun-Jin
    • Composites Research
    • /
    • v.32 no.3
    • /
    • pp.163-169
    • /
    • 2019
  • In this paper, we constructed a molecular dynamics (MD) polymer model of PMMA with 95% of conversion by using dynamic polymerization algorithm of a thermoplastic polymer based on free radical polymerization. In this algorithm, we introduced a united-atom level coarse-grained force field that combines the non-bonded terms from the TraPPE-UA force field and the bonded terms from the PCFF force field to alleviate the computation efforts. The molecular weight distribution and the average molecular weight of the polymer were calculated by investigating each chain generated from the free radical polymerization simulation. The molecular weight of the polymer was controlled by the number of initiator radicals presented in the initial state and molecular weight effect to the density, the glass transition temperature, and the mechanical properties were studied.

Extension of the Dynamic Range using the Switching Operation of In-Pixel Inverter in Complementary Metal Oxide Semiconductor Image Sensors

  • Seong, Donghyun;Choi, Byoung-Soo;Kim, Sang-Hwan;Lee, Jimin;Lee, Jewon;Lee, Junwoo;Shin, Jang-Kyoo
    • Journal of Sensor Science and Technology
    • /
    • v.28 no.2
    • /
    • pp.71-75
    • /
    • 2019
  • This paper proposes the extension of the dynamic range in complementary metal oxide semiconductor (CMOS) image sensors (CIS) using switching operation of in-pixel inverter. A CMOS inverter is integrated in each unit pixel of the proposed CIS for switching operations. The n+/p-substrate photodiode junction capacitances are added to each unit pixel. When the output voltage of the photodiode is less than half of the power supply voltage of the CMOS inverter, the output voltage of the CMOS inverter changes from 0 V to the power supply voltage. Hence, the output voltage of the CMOS inverter is adjusted by changing the supply voltage of the CMOS inverter. Thus, the switching point is adjusted according to light intensity when the supply voltage of the CMOS inverter changes. Switching operations are then performed because the CMOS inverter is integrated with in each unit pixel. The proposed CIS is composed of a pixel array, multiplexers, shift registers, and biasing circuits. The size of the proposed pixel is $10{\mu}m{\times}10{\mu}m$. The number of pixels is $150(H){\times}220(V)$. The proposed CIS was fabricated using a $0.18{\mu}m$ 1-poly 6-metal CMOS standard process and its characteristics were experimentally analyzed.

Azimuthal Angle Scan Distribution, Third Order Response, and Optical Limiting Threshold of the Bismarck Brown Y:PMMA Film

  • Fadhil Abass Tuma;Hussain Ali Badran;Harith Abdulrazzaq Hasan;Riyadh Chassib Abul-Hail
    • Current Optics and Photonics
    • /
    • v.7 no.6
    • /
    • pp.721-731
    • /
    • 2023
  • This paper studies various roughness parameters, besides waviness, texture, and nonlinear parameters of Bismarck brown Y (BBY)-doped Poly(methyl methacrylate) (PMMA) films based on the computed values of optical limiting (OL) threshold power and nonlinear refractive index. The films' morphology, grain size, and absorption spectra were investigated using atomic force microscopy in conjunction with ultraviolet-visible (UV-Vis) spectrophotometer. The particle size of the films ranged between 4.11-4.51 mm and polymer films showed good homogeneity and medium roughness, ranging from 1.11-4.58 mm. A polymer film's third-order nonlinear optical features were carried out using the Z-scan methodology. The measurements were obtained by a continuous wave produced from a solid-state laser with a 532 nm wavelength. According to the results, BBY has a nonlinear refractive index of 10-6 cm2/W that is significantly negative and nonlinear. The optical limiting thresholds are roughly 10.29, 13.52, and 18.71 mW, respectively. The shift of nonlinear optical features with the film's concentration was found throughout the experiment Additionally, we found that the polymer samples have outstanding capabilities for restricting the amount of optical power that may be transmitted through them. We propose that these films have the potential to be used in a wide variety of optoelectronic applications, including optical photodetectors and optical switching.

The characteristics of long- and short- chain PFCA and PFSA adsorption on granular activated carbon and surface-modified granular activated carbon (입상 활성탄 및 표면 개질 활성탄의 장·단사슬 PFCA와 PFSA 흡착 특성)

  • Jeongwoo Shin;Sangki Choi;Heejong Son;Byungryul An
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.38 no.4
    • /
    • pp.199-208
    • /
    • 2024
  • In this paper, the adsorption removal characteristic for 10 species of perfluoroalkyl and polyfluoroalkyl substances (PFAS) was investigated using GAC and modified GAC (GAC-Cu). After modification with Cu(II), the amount of copper was to 1.93 and 4.73 mg/g for GAC and GAC-Cu, respectively. The total amount of 10 species of PFAS per specific area was obtained to 0.548 and 0.612 ng/m2 for GAC and GAC-Cu, respectively. A series of batch test confirmed lower efficiency was observed with a smaller number of carbon chain length and the removal efficiency of PFCA (perfluoroalkyl carboxylic acids) was lower than that of PFSA (perfluoroalkyl sulfonic acids) with the same carbon chain length. Regarding the pH effect, the adsorption capacity was decreased with increase of pH due to the increase of electrostatic repulsion. According to pseudo first and second order (PFO and PSO) kinetic models, while the values of equilibrium uptake and time did not show significant difference, a difference in uptake was observed between 24-48h. Furthermore, based on correlation analysis, Log Kow and uptake have a high correlation with molecular weight (M.W.) and initial concentration, respectively. These results show that long-chain PFAS have higher removal efficiency due to their increased hydrophobicity.

pH에 따른 고분자 전해질의 거동

  • 최원희;신종호;박민태
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2002.05a
    • /
    • pp.108-108
    • /
    • 2002
  • 고분자전해질들은 제지공정에서 건조지력제, 습윤지력제, 정착제, 보류제 등으로 널리 사 용되어지고 있으며, 이러한 고분자전해질들이 보유하고 있는 관능기의 종류와 분자량에 따라 각각의 다른 특성을 발현하게 된다. 이중 관능기의 종류와 비율에 따라 결정되는 중요한 특성 중 한가지가 전하밀도이며, 이러한 전하밀도는 제지공정에 사용할 때 습부공정에서 매우 중요 한 인자라 할 수 있다. 전하밀도는 고분자전해질의 분자구조와 단량체의 종류에 따라 다르며, 적용 pH의 조건에 따라 변화하게 된다. 3급 아민과 4급 암모늄을 관능기로 가진 고분자전해질 의 경우 pH에 따른 전하밀도의 변화는 이미 잘 알려져 있는 바,3급 아민을 작용기로 가진 양이 온성 고분자전해질은 pH 9에 도달하면 양전하를 완전히 상실하고,4급 암모늄을 작용기로 가진 양이온성 고분자전해질은 pH의 변화에 상관없이 양전하가 변하지 않는다고 보고되어 있다. 본 연구에서는 양이온성과, 양쪽이온성 고분자전해질들 중 Cationic PAM, Amphoteric P PAM, PolyDADMAC, Epoxide polyamide resin, Epi-DMA copolymer 등을 시 료로 사용하였 으며, 양이온성 관능기의 종류가 다른 고분자 전해질을 이용하여 pH 변화에 따른 전하밀도의 변화를 검토하였다. 또한 일반적으로 중성 초지공정의 pH 조건은 7.0 - 8.0이며, 이 pH 조건에 서 고분자전해질의 거동은 매우 중요하다고 할 수 있다. 따라서 양이온 관능기의 종류에 따른 고분자전해질들을 pH 7.8에서 보관시간에 따른 전하밀도의 변화를 조사하였으며, 전하밀도가 변화하는 양상에 따라 양이온성 관능기의 분자구조의 변화를 검토하였다. p pH 변화에 따른 전하밀도의 변화 결과로부터 3급 아민을 포함한 양이온성 고분자전해질 뿐만 아니라,4급 암모늄을 포함한 일부의 양이온성 고분자전해질 또한 알카리 조건에서 전하 밀도가 감소하며, 강한 얄차리 조건에서는 음이온성 고분자전해질로 변화하는 현상을 관찰할 수 있었다. 이상의 결과들로부터 약 알카리(pH 7.5 - 8.0) 조건 하에서도 시간의 변화에 따라 4 급 암모늄을 포함하는 고분자전해질의 전하밀도가 변화할 것이라 예측하였으며, 실험을 통해 그 사실을 확인하였다. 알카리 조건에서 전하밀도가 변하지 않는 4급 암모늄 고분자전해질과, 전하밀도가 변하는 4급 암모늄 고분자전해질의 분자구조를 비교해 볼 때, 그 원인은 4급 암모늄 의 관능기가 고분자 연쇄로부터 가수분해 되어 나타나는 현상으로 판단된다.

  • PDF

A comparison of chlorhexidine release rate from three polymeric controlled release drug prototypes (제어방출형 소독제의 약물전달 체로 사용된 폴리머 유형에 따른 클로르헥시딘 제어 방출속도 비교)

  • Bok Young-Bin;Lee Doug-Youn;Lee Chang-Young;Kim Kyung-Nam;Kum Kee-Yeon
    • Restorative Dentistry and Endodontics
    • /
    • v.29 no.6
    • /
    • pp.548-552
    • /
    • 2004
  • Intracanal disinfection of infected root canal is one of important treatment procedure. This in vitro study aimed to evaluate whether the surface polymers of controlled release drug (CRD) can effectively control the release rate of chlorhexidine for root canal disinfection. Four CRD prototypes were prepared: Group A (n=12); The core device (absorbent paper point) was loaded with 40% CHX solution as control. Group B (n=12); same as group A, but the device was coated with chitosan. Group C (n=12); same as group A and then coated three times with 5% PMMA. Group D (n=12); same as group A and then coated three times with 3% PLGA. All CRD prototypes were soaked in 3 mL distilled water for experimental periods and the concentrations of released CHX from each CRD prototype were determined using a UV spectrophotometer. Results showed that release rate of CHX were the greatest in the non-coated group (control group), followed by the chitosan-coated group, the PLGA-coated group, and the PMMA-coated group (P < 0.05). This data indicate that surface polymers can control the release rate of CHX from the CRD prototypes.

Characteristics of Flexible Transparent Capacitive Pressure Sensor Using Silver Nanowire/PEDOT:PSS Hybrid Film (은나노와이어·전도성고분자 하이브리드 필름을 이용한 유연 투명 정전용량형 압력 센서의 특성)

  • Ahn, Young Seok;Kim, Wonhyo;Oh, Haekwan;Park, Kwangbum;Kim, Kunnyun;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.23 no.3
    • /
    • pp.21-29
    • /
    • 2016
  • In this paper, we developed a flexible transparent capacitive pressure sensor which can recognize X and Y coordinates and the size of force simultaneously by sensing a change in electrical capacitance. The flexible transparent capacitive pressure sensor was composed of 3 layers which were top electrode, pressure sensing layer, and bottom electrode. Silver nanowire(Ag NW)/poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) hybrid film was used for top and bottom flexible transparent electrode. The fabricated capacitive pressure sensor had a total size of 5 inch, and was composed of 11 driving line and 19 sensing line channels. The electrical, optical properties of the Ag NW/PEDOT:PSS and capacitive pressure sensor were investigated respectively. The mechanical flexibility was also investigated by bending tests. Ag NW/PEDOT:PSS exhibited the sheet resistance of $44.1{\Omega}/square$, transmittance of 91.1%, and haze of 1.35%. Notably, the Ag NW/PEDOT:PSS hybrid electrode had a constant resistance change within a bending radius of 3 mm. The bending fatigue tests showed that the Ag NW/PEDOT:PSS could withstand 200,000 bending cycles which indicated the superior flexibility and durability of the hybrid electrode. The flexible transparent capacitive pressure sensor showed the transmittance of 84.1%, and haze of 3.56%. When the capacitive pressure sensor was pressed with the multiple 2 mm-diameter tips, it can well detect the force depending on the applied pressure. This indicated that the capacitive pressure sensor is a promising scheme for next generation flexible transparent touch screens which can provide multi-tasking capabilities through simultaneous multi-touch and multi-force sensing.

Design and Hardware Implementation of High-Speed Variable-Length RSA Cryptosystem (가변길이 고속 RSA 암호시스템의 설계 및 하드웨어 구현)

  • 박진영;서영호;김동욱
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.27 no.9C
    • /
    • pp.861-870
    • /
    • 2002
  • In this paper, with targeting on the drawback of RSA of operation speed, a new 1024-bit RSA cryptosystem has been proposed and implemented in hardware to increase the operational speed and perform the variable-length encryption. The proposed cryptosystem mainly consists of the modular exponentiation part and the modular multiplication part. For the modular exponentiation, the RL-binary method, which performs squaring and modular multiplying in parallel, was improved, and then applied. And 4-stage CSA structure and radix-4 booth algorithm were applied to enhance the variable-length operation and reduce the number of partial product in modular multiplication arithmetic. The proposed RSA cryptosystem which can calculate at most 1024 bits at a tittle was mapped into the integrated circuit using the Hynix Phantom Cell Library for Hynix 0.35㎛ 2-Poly 4-Metal CMOS process. Also, the result of software implementation, which had been programmed prior to the hardware research, has been used to verify the operation of the hardware system. The size of the result from the hardware implementation was about 190k gate count and the operational clock frequency was 150㎒. By considering a variable-length of modulus number, the baud rate of the proposed scheme is one and half times faster than the previous works. Therefore, the proposed high speed variable-length RSA cryptosystem should be able to be used in various information security system which requires high speed operation.

A Design of a Reconfigurable 4th Order ΣΔ Modulator Using Two Op-amps (2개의 증폭기를 이용한 가변 구조 형의 4차 델타 시그마 변조기)

  • Yang, Su-Hun;Choi, Jeong-Hoon;Yoon, Kwang Sub
    • Journal of the Institute of Electronics and Information Engineers
    • /
    • v.52 no.5
    • /
    • pp.51-57
    • /
    • 2015
  • In this paper, in order to design the A / D converter with a high resolution of 14 bits or more for the biological signal processing, CMOS delta sigma modulator that is a 1.8V power supply voltage - were designed. we propose a new structure of The fourth order delta-sigma modulator that needs four op amps but we use only two op amps. By using a time -interleaving technique, we can re-construct the circuit and reuse the op amps. Also, we proposed a KT/C noise reduction circuit to reduce the thermal noise from a noisy resistor. We adjust the size of sampling capacitor between sampling time and integrating time, so we can reduce almost a half of KT/C noise. The measurement results of the chip is fabricated using a Magna 0.18um CMOS n-well1 poly 6 metal process. Power consumption is $828{\mu}W$ from a 1.8V supply voltage. The peak SNDR is measured as a 75.7dB and 81.3dB of DR at 1kHz input frequency and 256kHz sampling frequency. Measurement results show that KT/C noise reduction circuit enhance the 3dB of SNDR. FOM of the circuit is calculated to be 142dB and 41pJ / step.