• Journal of the Korean Society of Clothing and Textiles
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• v.12 no.2 s.27
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• pp.225-235
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• 1988

The effects of surface free energy of substrates on the soiling and on the detergency of the oily soil were studied. The surface tension consisted of dispersion force and polar force components of substrate, oily soil and surfactant solutions were calculated by extended Fowkes' equation. From these values, work of adhesion($W_a$), work of detergency($W_D$), ana residual work of detergency($W_{D,R}$) were calculated. The correlations between these theoretical values of the works and detergency were discussed. MAA grafted PET film was used as substrate, triolein as oily soil and nonylphenol polyoxyethylene ether(NPE) having various mole numbers of oxyethylene adducts and dodecylbenzene sulfonate (DBS) as surfactants. Detergency was estimated by means of radioactive tracer method using $C^{14}-triolein$. The results showed that $W_a$ was decreased with the increase of surface free energy of substrate. In water, $W_D\;and\;W_{D,R}$ were decreased and detergency of tiolein was increased with the increase of surface free energy of substrate. In surfactant solutions, the lower the surface free energy of substrate and the lower oxyethylene adducts of NPE were the more effective on detergency. The detergency of DBS solution was the lowest in the case of ungrafted PET film, but even small increase in surface free energy by grafting showed much increase in detergency.

• Elastomers and Composites
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• v.35 no.2
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• pp.122-131
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• 2000

In this work, the effect of chemical surface treatments on morphology of carbon blacks was investigated in terms of cure behavior and tearing energy ($G_T$) of carbon blacks/rubber composites. As experimental results, the polar or nonpolar chemical treatment led to a significant physical change of carbon black morphology. The cure activation energies (Ea) and frequency factor (A) obtained from Kissinger equation decreased with improving the dispersion of carbon flacks, resulting in high reactivity. However, a significant advantage of carbon black/rubber composites is gained by carbon blacks treated in basic (BCB) or nonpolar (NCB) chemical solution, resulting in increasing the tearing energy. These results could be explained by changes of dispersion, agglomerate, surface functional group, void volume, and cross-linking density of carbon black/rubber composites.

• Macromolecular Research
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• v.17 no.12
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• pp.976-986
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• 2009

With the study goal of firstly elucidating the anisotropic interactions between oriented polymer chain segments and liquid crystal (LC) molecules, and secondly of determining the contributions of the chemical components of the polymer segments to the film surface topography, LC alignment, pretilt, and anchoring energy, we synthesized three dianhydrides, 1,4-bis(4'-t-butylphenyl)pyromellitic dianhydride (BBPD), 1,4-bis(4'-trimethylsilylphenyl)pyromellitic dianhydride(BTPD), and 2,2'-bis(4"-tert-butylphenyl)-4,4',5,5'-biphenyltetracarboxylic dianhydride (BBBPAn), and a series of their organosoluble polyirnides, BBPD-ODA, BBPD-MDA, BBPD-FDA, BTPD-FDA, and BBBPAn-FDA, which contain the diamines 4,4'-oxydianiline (ODA), 4,4'-methylenediamine (MDA), and 4,4'-(hexafluoroisopropylidene)dianiline (FDA). All the polyimides were determined to be positive birefringent polymers, regardless of the chemical components. Although all the rubbed polyimide films exhibited microgrooves which were created by rubbing process, the film surface topography varied depending on the polyimides. In all the rubbed films, the polymer chains were unidirectionally oriented along the rubbing direction. However, the degree of in-plane birefringence in the rubbed film varied depending on the polyimides. The rubbing-aligned polymer chains in the polyimide films effectively induced the alignment of nematic LCs along their orientation directors by anisotropic interactions between the preferentially oriented polymer chain segments and the LCs. The azimuthal and polar anchoring energies of the LCs ranged from $0.45{\times}10^{-4}\;-\;1.37{\times}10^{-4}\;J/m^2$ and from $0.86{\times}10^{-5}\;-\;4.26{\times}10^{-5}\;J/m^2$, respectively, depending on the polyimides. The pretilt angles of the LCs were in the range $0.10-0.62^{\circ}$. In summary, the soluble aromatic polyimides reported here are promising LC alignment layer candidates for the production of advanced LC display devices.

• Journal of Digital Convergence
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• v.12 no.12
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• pp.581-588
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• 2014

The purpose of this study aims guarana ingestion to possibly be Ergogenic Aids(EA) for elite male athletes who do long time exercises. Participators who play long distance belong to H-university. They are measured HRmax by polar and treadmill, and they do run on the treadmill for 60 minutes with HRmax 70%. Participators ingest 200ml guarana and water for 5 times. They were drawn blood for 3 time such as before 30 minutes, after finish, and after 30 minutes later. Data processing was repeated of the measuring, two way repeated ANOVA, according to guarana ingestion, water ingestion, and treatment time. The result of this study identifies that guarana ingestion is more positive effect with glucose, Free fatty acid, and lactic acid than water. Hence, guarana ingestion is including function of EA to increase reserving energy on the body for rising kinetic ability.

• Journal of the Korean Vacuum Society
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• v.18 no.1
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• pp.1-8
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• 2009

Hydrophilic Surface modification of Polysarene (PS) was performed by Atmospheric Pressure Plasma (APP). Air or 0, gases were used for carrier gases and RF power was changed from 150 to 350 W. We controlled the treatment time as 1 time to 4 time passing through the plasma region. when the carrier gas was air, the water contact angle on the PS surface was decreased from $91^{\circ}$ to $20^{\circ}$. And the surface energy increased from 45.74 dyne/cm to 68.48 dyne/cm. In case of the $O_2$ plasma treatment, at 300 W of RF power and 4 times treatment, the water contact angle on the PS. Surface was decreased from $91^{\circ}$ to $17^{\circ}$ and the surface energy was increased from 45.74 dyne/cm to 69.73 dyne/cm. The surface energy was increased by polar force not by dispersion force. Improvement of surface properties can be explained by the formation of new hydrophilic groups which is identified as C-O, C=O by XPS analysis. The contact angle of APP treated PS surface kept in air was increased with time elapse, but maintained same value when it was kept in water. We treated the PS surface by APP and deposited Cu as $4,000\;{\AA}$ and $8,000\;{\AA}$ by thermal evaporation. The adhesion between sample and Cu thin film improvement of treated PS surface against untreated sample. could be verifiable by Tape test (ASTM D3359)

• Journal of Adhesion and Interface
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• v.23 no.4
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• pp.122-129
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• 2022

In this study, the hydrophilicity of the metal fiber is improved by introducing an oxygen-containing functional group to the fiber surface after treatment of the metal fiber using the oxygen plasma treatment time as an experimental variable. For the surface modification of metal fibers, changes in surface properties before and after plasma treatment were observed using SEM and x-ray photoelectron spectroscopy (XPS). In order to observe the effect of the plasma treatment time on the surface of the metal fiber, the change in contact angle of the metal fiber with respect to a polar solvent and a non-polar solvent was measured. After calculating the change in surface free energy using the measured contact angle, the contact angle and the surface free energy for metal fibers before and after oxygen plasma treatment were compared, and the correlation with the adhesion work was also considered. The microdroplet specimens were prepared to investigate the effect of surface changes of these metal fibers on the improvement of shear strength at the interface when combined with other materials and the interfacial shear strength was measured, and the correlation with the adhesion work was also identified. Therefore, the oxygen plasma treatment of the metal fiber results in an increase in the physical surface area on the fiber surface and a change in contact angle and surface energy according to the introduction of the oxygen-containing functional group on the surface. This surface hydrophilization resulted in improving the interfacial shear strength with the polymer resin.

• Bulletin of the Korean Chemical Society
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• v.33 no.9
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• pp.2873-2877
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• 2012

Quasi-classical trajectory (QCT) calculations of H+HLi reaction have been carried out on a new potential energy surface of the ground state reported by Prudente et al. [Chem. Phys. Lett. 2009, 474, 18]. The four polarization-dependent differential cross sections have been carried out in the center of mass (CM) frame at various collision energies. The reaction probability for the depletion channel has been studied over a wide collision energy range. It has been found that the collision energy decreases remarkably reaction probability, which shows the expected behavior of the title reaction belonging to an exothermic barrierless reaction. The results are in good agreement with previous RMP results. The P(${\theta}_r$), P(${\phi}_r$) and P(${\theta}_r,\;{\phi}_r$) distributions, the k-k'-j' correlation and the angular distribution of product rotational vectors are presented in the form of polar plots. The average rotational alignment factor <$P_2(j{\prime}{\cdot}k)$> as a function of collision energy is also calculated. The results indicate that the collision energy has a great influence on the polarization of the product rotational angular momentum vector j'.

• Journal of Microbiology and Biotechnology
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• v.15 no.3
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• pp.587-594
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• 2005

The contribution of electrostriction of water molecules to the stabilization of the negatively charged tetrahedral transition state of a lipase-catalyzed reaction was examined by means of kinetic studies involving high-pressure and solvent dielectric constant. A good correlation was observed between the increased catalytic efficiency of lipase and the decreased solvent dielectric constant. When the dielectric constant of solvents was lowered by 5.00 units, the losses of activation energy and free energy of activation were 7.92 kJ/mol and 11.24 kJ/mol, respectively. The activation volume for $k_{cat}$ decreased significantly as the dielectric constant of solvent decreased, indicating that the degree of electrostriction of water molecules around the charged tetrahedral transition state has been enhanced. These observations demonstrate that the increase in the catalytic efficiency of the lipase reaction with decreasing dielectric constant resulted from the stabilization of electrostatic energy for the formation of an oxyanion hole, and that this stabilization was caused by the increase of electrostricted water around the charged tetrahedral transition state. Therefore, we conclude that the control of solvent dielectric constant can stabilize the tetrahedral transition state, thus lowering the activation energy.

• Atmosphere
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• v.16 no.2
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• pp.111-124
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• 2006

This study examines seasonal variability of the surface energy balance at the King Sejong Station, Antarctica, using measurements and estimates of the components related to the balance for the period of 1996 to 2004. Annual average of downward shortwave radiation at the surface is 81 $Wm^{-2}$ which is 37% of the extraterrestrial value, with the monthly maximum of 188 $Wm^{-2}$ in December and the minimum of 8 $Wm^{-2}$ in June. These values are relatively smaller than those at other stations in Antarctica, which can be attributed to higher cloudy weather conditions in Antarctic front zone. Surface albedo varies between ~0.3 in the austral summer season and ~0.6 in the winter season. As a result, the net shortwave radiation ranges from 117 $Wm^{-2}$ down to 3 $Wm^{-2}$ with annual averages of 43 $Wm^{-2}$. Annual average of the downward longwave radiation shows 278 $Wm^{-2}$, ranging from 263 $Wm^{-2}$ in August to 298 $Wm^{-2}$ in January. The downward longwave radiation is verified to be dependent strongly on the air temperature and specific humidity, accounting for 74% and 79% of the total variance in the longwave radiation, respectively. The net longwave radiation varies between 25 $Wm^{-2}$ and 40 $Wm^{-2}$ with the annual averages of 30 $Wm^{-2}$. Accordingly, the annual average energy balance is dominated by radiative warming of a positive net all-wave radiation from September to next March and radiative cooling of a negative net all-wave radiation from April to August. The net all-wave radiative energy gain and loss at the surface is mostly balanced by turbulent flux of sensible and latent heat. The soil heat flux is of negligible importance in the surface energy balance.

• Journal of Astronomy and Space Sciences
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• v.18 no.1
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• pp.1-6
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• 2001

In this paper we investigate the properties of advection-dominated accretion flows (ADAFs) in case that outflows carry away infalling matter with its angular momentum and energy. Positive Bernoulli number in ADAFs allow a fraction of the gas to be expelled in a form of outflows. The ADAFs are also unstable to convection. We present self-similar solutions for advection-dominated accretion flows in the presence of outflows from the accretion flows(ADIOS). The axisymmetric flow is treated in variables integrated over polar sections and the effects of outflows on the accretion flow are parameterized for possible configurations compatible with the one dimensional self-similar ADAF solution. We explicitly derive self-similar solutions of ADAFs in the presence of outflows and show that the strong outflows in the accretion flows result in a flatter density profile, which is similar to that of the convection-dominated accretion flows(CDAFs) in which convection transports the angular momentum inward and the energy outward. There two different versions of the ADAF model should show similar behaviors in X-ray spectrum to some extent. Even though the two models may show similar behaviors, they should be distinguishable due to different physical properties. We suggest that for a central object of which mass is known these two different accretion flow should have different X-ray flux value due to deficient matter in the wind model.