• Title/Summary/Keyword: plasma spray

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Mechanical Behavior of Layered YSZ Thermal Barrier Coatings using Indentation Test (압입시험법에 의한 YSZ 층상 열차폐 코팅재의 기계적 거동)

  • Lee, Dong-Heon;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.396-403
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    • 2011
  • In this study, we investigated the mechanical behaviors of layered thermal barrier coatings by indentations. Various single and double-layered thermal barrier coatings were deposited by air plasma spray process using different type of commercialized YSZ (Yttria stabilized zirconia) starting powders. Indentation stress-strain curve, load-displacement curve and hardness of the single and the double-layered thermal barrier coatings were obtained experimentally and analyzed. The indentation damages at the same loads were compared, and thus, the results depend on the structure of each coating. The result indicates improvement in damage resistances from tailoring of layered structures in the component of gas turbine system is expected.

Ni-BASE ALLOY SYSTEMS AS ALTERNATIVE TO HEXAVALENT CHROMIUM (경질크롬도금 대체용 Ni계 합금도금 기술)

  • Chang, Do-Yon;Lee, Kyu-Hwan;Kwon, Sik-Chol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.10a
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    • pp.11-11
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    • 2003
  • Electroplated hexavalent chromium coatings have been used in many technical applications since it was invented by G.J. Sargent in 1920. Because of the environmental problems and health risks associated with the use of hexavalent chromium, there has been an extensive search for alternative coatings with properties such as corrosion resistance and wear resistance, at a reasonable cost. However there is no single substitute that meets all the desirable performance characteristics of chromium. Advanced techniques, such as alloy plating, electroless plating, trivalent chromium plating, plasma and thermal spray coating, PVD and ion implantation, have been applied for replacing hexavalent chromium plating.

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I-V Properties OLED by CMP Process (CMP 공정을 적용한 유기발광소자의 전압.전류 특성)

  • Choi, Gwon-Woo;Lee, Woo-Sun;Jun, Young-Kil;Jueng, Pan-Gum;Seo, Yong-Jin
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1357-1358
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    • 2006
  • Indium tin oxide (ITO) thin film is a transparent electrode, which is widely applied to solar battery, illuminators, optical switches, liquid crystal displays (LCDs), plasma display panels (PDPs), and organic light emitting displays (OLEDs) due to its easy formation on glass substrates, goof optical transmittance, and good conductivity. ITO thin film is generally fabricated by various methods such as spray, CVD, evaporation, electron gun deposition, direct current electroplating, high frequency sputtering, and reactive DC sputtering. However, some problems such as peaks, bumps, large particles, and pin-holes on the surface of ITO thin film were reported, which caused the destruction of color quality, the reduction of device life time, and short-circuit. Chemical mechanical polishing (CMP) processis one of the suitable solutions which could solve the problems.

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Characterization of Modified Surface Manufactured by PTA(Plasma Transferred Arc) Spray (PTA 용사에 의해 제조된 표면개질부의 특성에 관한 연구)

  • Ji Jung-Hun;Yoo Yeon-Gon;Kim Gwang-Soo
    • Proceedings of the KAIS Fall Conference
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    • 2004.06a
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    • pp.92-95
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    • 2004
  • 플라즈마 트랜스퍼드 아크(PTA) 용사는 플라즈마 아크 용접 장치에 선형의 용접봉을 이용하는 대신 분말 형태의 용접재를 주입하여 주로 마모나 부식에 노출되는 금속의 표면에 적용하여 금속 표면의 내식 내마모 특성을 향상시키는 기술이다. 본 논문에서는 용사전류가 표면개질부에 미치는 기하학적 형상 및 미세조직에 미치는 영향에 대하여 알아보았다. 낮은 전류에서는 접합이 이루어지지 않았고 높은 전류에서는 모재로 희석되어 들어가는 현상을 보였다.

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Effect of coating thickness on contact fatigue and wear behavior of thermal barrier coatings

  • Lee, Dong Heon;Jang, Bin;Kim, Chul;Lee, Kee Sung
    • Journal of Ceramic Processing Research
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    • v.20 no.5
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    • pp.499-504
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    • 2019
  • The effect of coating thickness on the contact fatigue and wear of thermal barrier coatings (TBCs) are investigated in this study. The same bondcoat material thickness (250 ㎛) are used for each sample, which allows the effect of the coating thickness of the topcoat to be investigated. TBCs with different coating thicknesses (200, 400, and 600 ㎛) are prepared by changing processing parameters such as the feeding rate of the feedstock, spraying speed, and spraying distance during APS(air plasma spray) coating. The damage size on the surface are strongly affected by the coating thickness effect. Although the damage size from contact fatigue using a spherical indenter diminish at a TBC of 200 ㎛, a high wear resistance such as a low friction coefficient and little mass change are found at a TBC of 600 ㎛. These results indicate that the coating thickness strongly affects the mechanical behavior in TBCs during gas turbine operation.

Microstructure and plasma resistance of Y2O3 ceramics (Y2O3 세라믹스의 미세구조 및 플라즈마 저항성)

  • Lee, Hyun-Kyu;Lee, Seokshin;Kim, Bi-Ryong;Park, Tae-Eon;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.6
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    • pp.268-273
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    • 2014
  • $Y_2O_3$ ceramic specimens were fabricated from the granular powder, obtained by spray drying process from the slurry. The slurry was prepared by mixing PVA binder, NaOH for Ph control, PEG and $Y_2O_3$ powder. The $Y_2O_3$ specimen was shaped in size of ${\phi}14mm$ and then sintered at $1650^{\circ}C$. The characteristics, microstructure, densities and plasma resistance of the $Y_2O_3$ specimens were investigated with the function of forming pressure and sintering time. $Y_2O_3$ specimens were exposed under the $CHF_3/O_2/Ar$ plasma, the dry etching treatment of specimens was carried out by the physical reaction etching of $Ar^+$ ion beam and the chemical reaction etching of $F^-$ ion decomposed from $CHF_3$. With increasing sintering time, $Y_2O_3$ specimens showed relatively high density and strong resistance in plasma etching test.

Influence of Subsurface Layer on the Indentation Damage Behavior of YSZ Thermal Barrier Coating Layers Deposited by Electron Beam Physical Vapor Deposition (전자 빔 물리적 증착(EB-PVD)법으로 코팅된 YSZ 열차폐층의 압흔손상 거동에 대한 하부층의 영향)

  • Heo, Yong-Suk;Park, Sang-Hyun;Han, In-Sub;Woo, Sang-Kuk;Jung, Yeon-Gil;Paik, Un-Gyu;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.549-555
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    • 2008
  • The thermal barrier coating must withstand erosion when subjected to flowing gas and should also maintain good stability and mechanical properties while it must also protect the turbine component from high temperature, hot corrosion, creep, and oxidation during operation. In this study we investigated the influence of subsurface layer, $Al_2O_3$ or NiCrCoAIY bond coat layer, on the indentation damage behavior of YSZ thermal barrier coating layers deposited by electron beam physical vapor deposition (EB-PVD). The bond coat is deposited using different process such as air plasma spray (APS) or spray of high velocity oxygen fuel (HVOF) and the thickness is varied. Hertzian indentation technique is used to induce micro damages on the coated layer. The stress-strain behaviors are characterized by results of the indentation tests.

Microwave Absorbing Characteristics of Ferrite-silicon carbide surface Films Produced (플라즈마 용사방식에 의해 형성된 페라이트-탄화규소 표면층의 마이크로파 흡수 특성(II))

  • Shin, Dong-Chan;Son, Hyon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.8
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    • pp.1169-1175
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    • 1993
  • Plasma spraying method was used to fabricated the microwave absorbing ferrite-silicon carbide on the aluminum-alloy of the fuselage of an aircraft to protect it from RADAR detection. In this paper 15[rm] instead of 34[rm], the mean size of SIC-powder for ferrite-silicon carbide surface films(I) was used. 50(Kg/h) Instead of 70(Kg/h), the powder feed and 100[mm] Instead of 80(mm), spray distance of spray parameters was used. This M/W absorbers were designed experimentally and fabricated trially, as a result of which the relative frequency bandwidth of 2.8% were obtained under the tolerance limits of the reflection coefficients lower than-10[dB], and the maximum absorption thickness becomes 0.5[mm], which is much thinner than that of the conventional ones.

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Morphological Observation on Tribological Characteristic of Thermal Spray Coated Steel-Bar (용사 코팅된 스틸바의 트라이볼로지적 특성의 형상학적 관찰)

  • Lee, Duk Gyu;Cho, Hee Keun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.5
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    • pp.559-566
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    • 2014
  • Plasma coatings have been conducted to improve the mechanical properties of thermal resistance, wear resistance, corrosion resistance and thermal shock with respect to Great-Bar which is used as a carrier device for ironstone sintering under $700^{\circ}C$. The surface coatings on the upper side of the Great-Bar exposed on extreme environments of high temperature, severe wear, corrosion and thermal shock extended the life time due to the barrier coating layer. $Al_2O_3$, $Cr_2O_3$, WC coatings were applied to Great-Bar and their mechanical and chemical properties are analyzed by several experimental tests such as thermal resistance, wear resistance, corrosion resistance and thermal shock resistance. It shows excellent advantages with respect to wear, thermal shock and corrosion.

Stability, Efficacy, Absorption and Toxicity of a New Nasal Spray Formulation including Salmon Calcitonin

  • Shim, Hyun-Joo;Kim, Mi-Kyung;Bae, En-Joo;Lee, Eung-Doo;Hyun Jo;Kim, Soon-Hae;Kwon, Jong-Won;Kim, Won-Bae
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.137-137
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    • 1998
  • Stability, efficacy, absorption and toxicity of a new nasal spray formulation including salmon calcitonin were studied in the laboratory animals. After the effects of many excipients on the stability of salmon calcitonin were evaluated using HPLC system, we selected taurine. Our experimental composition of salmon calcitonin contains taurine as a stabilizer and HPMC (hydroxypropylmethyl cellulose) as an adhesive polymer. After intranasal administration of salmon calcitonin formulations, Mia$\^$(R)/, Men$\^$(R)/ and experimental composition, 22 IU to rats, the reduction percentages of calcium concentration in plasma (ΔD%) were 16.3%, 12.9% and 20.8%, respectively. After intranasal administration of Mia$\^$(R)/, Men$\^$(R)/ and experimental composition to rats, C$\sub$MAX/ (205${\pm}$161, 244${\pm}$117, and 330${\pm}$202 pg/$m\ell$, respectively) and AUC (41585${\pm}$22070, 41191${\pm}$19125, and 63357${\pm}$43126 pg. min/$m\ell$, respectively) were calculated. The permeation coefficients 10$\^$-7/,cm/sec) of salmon calcitonin in Mia$\^$(R)/, Men$\^$(R)/ and experimental composition using Ussing chamber with rabbit nasal mucosa were 4.7${\pm}$1.5, 0.75${\pm}$0.4 and 5.3${\pm}$1.1, respectively. The experimental composition with taurine and HPMC was proved to be excellent because it improved the stability of salmon calcitonin and inhanced the absorption of salmon calcitonin and was not irritative to the nasal mucosa.

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