• Title/Summary/Keyword: piezoelectric lead zirconate titanate (PZT)

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Stress Induced Gigantic Piezoelectricity of PZT thin films for Actuated Mirror Array

  • Suzuki, Hisao
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.591-596
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    • 2006
  • Lead zirconate titanate(PZT) thin films have been attracting worldwide interests in exploring their potential properties [1-3] or the origins [4-6] of their excellent dielectic, ferroelectric and piezoelectric properties near the morphotropic phase boundary (MPB). PZT thin films are expected to apply to the memory devices, micro electro mechanical systems (MEMS), and display because of their superior ferroelectric, pyroelectric, piezoelectric and electron emission properties. In this study, high- performance piezoelectric PZT thin films for actuated mirror array and optical scanner were developed by controlling the several factors, such as molecular-designed precursor, seeding layer and the residual stress in films, by a chemical solution deposition (CSD).

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Deposition and XPS Study of Pb, Zr, and Ti Films

  • Choi, Sujin;Park, Juyun;Jeong, Eunkang;Kim, Beob Jun;Son, Seo Yoon;Lee, Jeong Min;Lee, Jin Seong;Jo, Hee Jin;Park, Jihun;Kang, Yong-Cheol
    • Journal of Integrative Natural Science
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    • v.7 no.3
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    • pp.183-187
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    • 2014
  • Lead zirconate titanate (PZT) is significant material in electrical and optical devices for their ferroelectric, piezoelectric and dielectric properties. In this research, PZT films were fabricated by reactive RF co-sputtering method using Pb, Zr, and Ti targets. From XPS study, lead, zirconium, and titanium are successfully deposited on Si(100) substrate. Thickness of PZT films was measured with a surface profiler and the thickness was decreased as the oxygen gas ratio increased in the sputter gas.

Dielectric and Piezoelectric Properties on the Piezoceramics PZT by Molten Salt Synthesis (Flux법에 의해 제조된 압전 세라믹(PZT)의 유전 및 압전특성)

  • Lee, S.H.;Park, J.B.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.721-723
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    • 1992
  • The electrical resistivity and piezoelectric properties have been studied for Lead Zirconate-Titanate(PZT) with $Nb_2O_5$ dopant, fabricated from conventional mixed-oxide powders and molten salt synthesis. The resistivity and electromechanical coupling factor(Kp) were increased with increasing Nb contents. The reason for increasing of the electrical resistivity below the Curie Temperature(Tc), It is believed that the p-type electrical conduction in PZT is caused by the lead vacancies. The electromechanical coupling factor(Kr) and piezoelectric constant $d_{33}$ were improved by Nb additives. This behavior can be explained as a compensation effect and $Nb^{5+}$ can serve as a donar and contribute electrons to the conduction process. As a result, the optimized $Nb_2O_5$ dopants on the PZT specimens were 0.75 wt%.

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Phase Transition and Improvement of Output Efficiency of the PZT/PVDF Piezoelectric Device by Adding Carbon Nanotubes (Carbon Nanotube의 첨가에 의한 PZT/PVDF 압전소자의 상전이와 출력 효율 개선)

  • Lim, Youngtaek;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.94-97
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    • 2018
  • Lead zirconate titanate/poly-vinylidene fluoride (PZT/PVDF) piezoelectric devices were fabricated by incorporating carbon nanotubes (CNTs), for use as flexible energy harvesting devices. CNTs were added to maximize the formation of the ${\beta}$ phase of PVDF to enhance the piezoelectricity of the devices. The phase transition of PVDF induced by the addition of CNTs was confirmed by analyzing the X-ray diffraction patterns, scanning electron microscopy images, and atomic force microscopy images. The enhanced output efficiency of the PZT/PVDF piezoelectric devices was confirmed by measuring the output current and voltage of the fabricated devices. The maximum output current and voltage of the PZT/PVDF piezoelectric devices was 200 nA and 350 mV, respectively, upon incorporation of 0.06 wt% CNTs.

Low Temperature Sintering of PZTN by the Liquid Phase Transient Processing (액상천이공정에 의한 PZTN의 저온소결에 관한 연구)

  • Kim, Chan-Yeong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.12
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    • pp.593-598
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    • 2001
  • Transient liquid phase processing was investigated to decrease processing temperatures while maintaining useful piezoelectric properties in the lead zirconate titanate (PZT) system. Niobium oxide$(Nb_2O_5)$ modified crystalline PZT (PZTN) powder was combined with lead silicate $(PS; PbO-SiO_2)$ glass powder and crystalline titania, zirconia, and niobia. Firing above the melting temperature of the lead silicate $(PS; Tm \risingdotseq\; 714^{\circk}C)$ resulted in liquid phase densification of the PZTN followed by dissolution of the titania, zirconia, and niobia into the liquid phase, and crystallization of additional PZTN. The addition of crystalline titania, zirconia, and niobia to react with the lead oxide from the lead silicate phase resulted in an increase in the dielectric and Piezoelectric properties.

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Piezoelectric Composites of PZT/polymer for Ultrasonic Transducer Applications (초음파 변환기 응용을 위한 PZT/고분자 압전복합재료)

  • Kim, Jin-Soo;Kim, Yong-Huck;Kim, Ho-Gi;Lee, Deok-Chool
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.802-805
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    • 1988
  • The objective of the present study was to manufacture the piezoelectric composites of Lead Zirconate Titanate (PZT) - polymer for applications such as ultrasonic medical diagnosis and hydrophone. The PZT rod-polymer composites have been prepared with 4.5 to 57 volume percent PZT using 1.5 mm rod, so the connectivity pattern of the two phase is 1-3 type. The electromechanical coupling factors of radial mode ($k_{p}$) and thickness mode ($k_{t}$) were nearly independent of the volume percent PZT, which were 0.3 and 0.65, respectively. The acoustic impedance of the piezoelectric composites was measured by the resonance technique in the frequency range 50 KHz-1.5 MHz, which was in the range of 3.8 - 60 Mrayl.

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Nondestructive Evaluation and Interfacial Damage Sensing of PVDF embedded Polymer Composites using Micromechanical Techniques and Acoustic Emission (Micromechanical 시험법과 AE를 이용한 PVDF 함침 고분자 복합재료의 계면손상감지능 및 비파괴적 평가 연구)

  • Kong, Jin-Woo;Park, Joung-Man;Kim, Ki-Bok;Yoon, Dong-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.216-219
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    • 2002
  • Conventional piezoelectric lead-zirconate-titanate (PZT) senor has high sensitivity, but it is very brittle. Recently polymer films such as polyvinylidene fluoride (PVDF) have been used use as a sensor. The advantages of PVDF are the flexibility and mechanical toughness. Simple process and possible several shapes are also additional advantages. PVDF sensor can be directly embedded and attached to a structure. In this study, PVDF sensor was embedded in single glass fiber/epoxy composites whereas PZT sensor with AE was attached to single fiber composites (SFC). Piezoelectric sensor responds to interfacial damage of SFC. The signals measured by PVDF sensor were compared to PZT sensor. PZT sensor detected the signals of fiber fracture, matrix crack, interfacial debonding and even sensor delamination, whereas PVDF sensor only detected fiber fracture signals so far, because PZT sensor is much more sensitive than current PVDF sensor. Wave voltage of fiber fracture measured by PVDF sensor was lower than that of PZT sensor, but the results of fast Fourier transform (FFT) analysis were same. Wave velocity using two PZT sensors was also studied to know the internal and surface damage effect of epoxy specimens.

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Analytical Estimation of Power Generation from Dynamic Structure With Piezoelectric Element (압전재료가 부착된 동적 구조물로부터 발생되는 전기력의 해석적인 평가)

  • Oh, Jae-Eung;Yoon, Ji-Hyeon;Sim, Hyoun-Jin;Lee, You-Yub
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.05a
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    • pp.263-263
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    • 2007
  • In the future, self-contained sensors and processing units will need on-board, renewable power supplies to be truly autonomous. One way of supplying such power is through energy harvesting, processes by which ambient forms of energy are converted into electricity. One energy harvesting technique involves converting kinetic energy, in the form of vibrations, into electrical energy through the use of piezoelectric materials. Researchers are currently investigating how piezoelectric materials can be used to harvest power. This study examines the use of auxiliary structures, consisting of a mechanical fixture and a lead zirconate/lead titanate (PZT) piezoelectric element, which can be attached to any boundary conditions vibrating beam of the any boundary conditions. Adjusting various boundary conditions of these structures can maximize the strain induced in the attached PZT element and improve power output.

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Fabrication and Characteristic Analysis of Piezoelectric Micro-Transformer (초소형 마이크로 압전변압기 제작 및 특성 분석)

  • Kim Seong-Kon;Seo Young-Ho;Choi Doo-Sun;Whang Kyung-Hyun
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.469-470
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    • 2006
  • Piezoelectric transformers based on lead zirconate titanate(PZT) have been received considerable interest because of their wide potential applications in transformer, oscillator, resonance sensor, actuator, acoustic transducer, as well as active slider for hard disk drives. However, for the applications which need a small power supply such as thin and flat displays, micro-robot, micro-system, it is especially necessary to integrate the passive components because they typically need more than 2/3 of the space of the conventional circuit. So, we have fabricated the piezoelectric micro-transformer to supply energy for micro-systems using PZT thin films and MEMS technologies.

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Microstructure and Additive Effect of the Piezoelectric ceramics PZT prepared by Molten Salt Synthesis Method (용융염 합성법에 의해 제조된 압전 세라믹(PZT)의 미세구조 및 첨가물의 효과)

  • 이수호;조현철;류주현;사공건
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.5
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    • pp.378-383
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    • 1998
  • Microstructure and additive effect of Lead Zirconate-Titanate(PZT) ceramics prepared by molten salt synthesis method with additives $Nb_2O_5, Fe_2O_3$ and MnO were investigated.The grain PZT ceramics ws decreased with the increase $Nb^{5+} or Fe^{3+}$ while increased with the increase $Mn^{2+}$ addition. The relative resistivity of PZT ceramics was increased with the increase $Mn^{5+}$ addition, while decreased with the increase $Mn^{2+}$ addition. And the dielectric and the piezoelectric constant of PZT ceramics showed 2,100 and 342pC/N at $Mn^{5+}$ addition of 0.75 mol%, respectively.

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