• Title/Summary/Keyword: piezoelectric effect

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Effect of Post-Annealing on the Microstructure and Electrical Properties of PMN-PZT Films Prepared by Aerosol Deposition Process (후열처리 공정이 에어로졸 증착법에 의해 제조된 PMN-PZT 막의 미세구조와 전기적 특성에 미치는 영향)

  • Hahn, Byung-Dong;Ko, Kwang-Ho;Park, Dong-Soo;Choi, Jong-Jin;Yoon, Woon-Ha;Park, Chan;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.106-113
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    • 2006
  • PMN-PZT films with thickness of $5\;{\mu}m$ were deposited on $Pt/Ti/SiO_2/Si$ substrate at room temperature using aerosol deposition process. The films showed fairly dense microstructure without any crack. XRD and TEM analysis revealed that the films consisted of randomly oriented nanocrystalline and amorphous phases. Post-annealing process was employed to induce crystallization and grain growth of the as-deposited films and to improve the electrical properties. The annealed film showed markedly improved electrical properties in comparison with as-deposited film. The film after annealing at $700^{\circ}C$ for 1h exhibited the best electrical properties. Dielectric constant $(\varepsilon_r)$, remanent polarization $(P_r)$ and piezoelectric constant $(d_{33})$ were 1050, $13\;{\mu}C/cm^2$ and 120 pC/N, respectively.

Interfacial Properties and Sensing of Carbon Nanofiber/Tube and Electrospun Nanofiber/Epoxy Composites Using Electrical Resistance Measurement and Micromechanical Technique (전기저항측정 및 미세역학시험법을 이용한 탄소나노섬유/튜브 및 전기방사된 나노섬유/에폭시 복합재료의 계면특성 및 감지능 연구)

  • Jung Jin-Gyu;Kim Sung-Ju;Park Joung-Man
    • Composites Research
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    • v.18 no.4
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    • pp.21-26
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    • 2005
  • Nondestructive damage sensing and load transfer mechanisms of carbon nanotube (CNT) and nanofiber (CNF)/epoxy composites have been investigated by using electro-micromechanical technique. The electrospun PVDF nanofibers were also prepared as a piezoelectric sensor. The electro-micromechanical techniques were applied to evaluate sensing response of carbon nanocomposites by measuring electrical resistance under an uniform cyclic loading. Composites with higher volume content of CNT showed significantly higher tensile properties than neat and low volume$\%$ CNT composites. CNT composites showed humidity sensing within limited temperature range. CNT composites with smaller aspect ratio showed higher apparent modulus due to high volume content in case of shorter aspect ratio. Thermal treated electrospun PVDF nanofiber showed higher mechanical properties than the untreated case due to crystallinity increase, whereas load sensing decreased in heat treated case. Electrospun PVDF nanofiber web also showed sensing effect on humidity and temperature as well as stress transferring. Nanocomposites and electrospun PVDF nanofiber web can be applicable for sensing application.

Effect of sintering atmosphere on the Crystal structure of lead-free Piezoelectric Ceramics (무연계 압전세라믹스의 결정구조에 대한 소결분위기의 영향)

  • Kang, Kyung-Min;Chun, Myuong-Pyo;Cho, Jeong-Ho;Kim, Byung-Ik;Ko, Tae-Gyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.328-328
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    • 2010
  • 압전 세라믹스는 엑츄에이터 및 센서 등의 다양한 응용분야로 인하여 많은 연구가 진행되어왔다. 최근 친환경 무연 압전계인 Bi층상구조 (BNT) 및 알칼리 니오븀산화물계 (KNN)에 대한 연구가 집중되고 있다. 한편, 소형화 및 고성능의 압전소자에 대한 요구 증가로 고가의 내부전극인 Ag, Ag-Pd합금으로 이루어진 적층압전소자에 대한 연구개발이 진행되어 왔다. 본 연구에서는 Ni이나 Cu를 내부전극으로 사용하는 적층압전소자의 개발가능성을 타진하고자 Ni의 산화를 억제할 수 있는 환원분위기 소결시에 압전소재의 상변화 및 내환원성 정도를 조사하였다. 압전소재인 BNT 및 KNN를 공기중에서 합성한 후, 환원분위기의 영향을 조사하고자 샘플을 디스크 형태로 성형하여 $1000{\sim}1200^{\circ}C$에서 2 시간 동안 공기, 중성 (N2) 와 환원 분위기 (3 % H2 - 97 %의 N2) 에서 소결한 후 미세구조와 전기적 특성을 SEM, EDS, XRD, impedance analyzer로 조사였다. 환원분위기에서 소결된 BNT 샘플은 페롭스카이트 상이 관찰되지 않았으며, SEM/EDS 분석결과 시편의 표면에 Bi의 석출이 관찰되었다. KNN의 경우에는 공기중에서 소결 시편뿐만 아니라 환원분위기에서 소결된 시편에서도 페롭스카이트 구조를 보였으며, EDS분석결과 K 및 Na의 휘발이 비교적 적었다.

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Ultrasonic Distance Measurement Method Based on Received Signal Model (수신 신호 모델을 이용한 초음파 거리 측정 방법)

  • Choe, Jin-Hee;Cho, Whang;Choy, Ick
    • The Journal of the Korea institute of electronic communication sciences
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    • v.12 no.1
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    • pp.53-60
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    • 2017
  • Most of present ultrasonic distance measurement technologies are based on the measurement of the TOF (: Time of Flight), the elapsed time during which the ultrasonic wave travels from its transmitter to receiver, to evaluate the distance the wave travels during that time. In this case, high distance measurement accuracy requires an accurate measurement of TOF. In order to acquire an accurate TOF, this paper proposes a method that produces the TOF by using a mathematical model of the received signal obtained from a mathematical model of ultrasonic transducer. The proposed method estimates the arrival time of the received signal retrospectively by comparing its wave form obtained after triggering point with its mathematical model in the sense of least-square. Experimental result shows that the effect of variation of triggering point can be decreased by implementing the proposed method.

Basic Study on P(VDF-TrFE) Smart Sensor for Monitoring Composite Structure Behaviors (복합재료구조물 거동 관찰을 위한 P(VDF-TrFE) 스마트센서의 기초연구)

  • Bae, Ji-Hun;Chang, Seung-Hwan
    • Composites Research
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    • v.28 no.3
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    • pp.75-80
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    • 2015
  • Poly(vinylidene fluoride-trifluoroethylene; P(VDF-TrFE)) is one of the most promising electroactive polymers with numerous application potentials in many fields of industry. Because of its good electro-mechanical properties P(VDF-TrFE) has been used for a number of sensors and actuators and also can be used for monitoring composite structure behaviors as a sensor. Three different ways (Electrical poling, annealing-cooling, and pressing) to enhance ${\beta}$-phase of P(VDF-TrFE) film were carried out. A microscopic analysis was conducted using X-ray diffraction to investigate the effect of such treatments on piezoelectric properties of P(VDF-TrFE) film. From the results, poling, annealing-cooling, and pressing were all effective to enhance ${\beta}$ crystallinity of P(VDF-TrFE) film and the maximum increase rate was 62.80% from 45.29% of the control group.

Improvement of Resonant Characteristics due to the Thermal Annealing Effect in Multi-layer Thin-film SMR Devices (Thermal Annealing 효과에 의한 다층 박막 FBAR 소자의 공진 특성 개선)

  • ;;Mai Linh
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.633-636
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    • 2003
  • In this work, We, for the first time, present the effects of the thermal annealing of the W/SiO$_2$ multi-layer quarter wavelength reflectors on the resonant properties of the ZnO-based SMR devices. In order to improve the resonant properties of the SMR devices, we annealed thermally the reflectors formed on a silicon substrate using a RF magnetron sputtering technique. As a result, the resonant properties of the SMR devices were observed to strongly depend on the annealing conditions applied to the reflectors. The SMR devices with the reflectors annealed at 40$0^{\circ}C$/30min showed excellent resonance properties as compared to those with the reflectors non-annealed (as-deposited). The newly proposed simple thermal annealing process will be very useful to more effectively improve the resonant properties of the future SMR devices with W/SiO$_2$ multi-layer quarter wavelength reflectors.

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Study on Efficiency Droop in a-plane InGaN/GaN Light Emitting Diodes

  • Song, Hoo-Young;Suh, Joo-Young;Kim, Eun-Kyu;Baik, Kwang-Hyeon;Hwang, Sung-Min;Yun, Joo-Sun;Shim, Jong-In
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.145-145
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    • 2011
  • Light-emitting diodes (LEDs) based on III-nitrides compound semiconductors have achieved a high performance device available for display and illumination sector. However, the conventional c-plane oriented LED structures are still showing several problems given by the quantum confined Stark effect (QCSE) due to the effects of strong piezoelectric and spontaneous polarizations. The QCSE results in spatial separation of electron and hole wavefunctions in quantum wells, thereby decreasing the internal quantum efficiency and red-shifting the emission wavelength. Due to demands for improvement of device performance, nonpolar structure has been attracting attentions, since the quantum wells grown on nonpolar templates are free from the QCSE. However, current device performance for nonpolar LEDs is still lower than those for conventional LEDs. In this study, we discuss the potential possibilities of nonpolar LEDs for commercialization. In this study, we characterized current-light output power relation of the a-plane InGaN/GaN LEDs structures with the variation of quantum well structures. On-wafer electroluminescence measurements were performed with short pulse (10 us) and low duty factor (1 %) conditions applied for eliminating thermal effects. The well and barrier widths, and indium compositions in quantum well structures were changed to analyze the efficiency droop phenomenon.

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Preparation and Properties of Poly(vinylidene fluoride) Multilayer Films (Poly(vinylidene fluoride) 다층 필름의 제조 및 특성)

  • Son, Tae-Won;Kim, Jong-Hwan;Choi, Won-Mi;Han, Fei-Fei;Kwon, Oh-Kyeong
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.130-135
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    • 2011
  • Along with the fast development of electronics, the demands of portable electronics and wireless sensors are growing rapidly. The need for self-powering materials capable of powering the electrical devices attached to them is increasing, The piezoelectric effect of polyvinylidene fluoride (PVDF) can be used for this purpose. PVDF has a special crystal structure consisting of a ${\beta}$-phase that can produce piezoelectricity. In this paper, multilayer PVDF films were fabricated to increase the ${\beta}$-phase content. A solution of 10% concentration N;N-dimethylacetamide (DMAc) in PVDF (PVDF/DMAc) was used to fabricate the films via spin coating technique with the following optimum process parameters: a spin rate of 850 rpm, spin time of 60 s, drying temperature of $60^{\circ}C$, and drying time of 30 min, Compared with single-layer PVDF films, the multilayer films exhibited higher ${\beta}$-phase content. The ${\beta}$-phase content of the films increased gradually with increasing number of layers until 4, Maximum ratio of ${\beta}$-phase content was 7.72.

A Pilot Study of Implementing Bender Element to In-situ Civil Engineering Measurement (현장 토목 계측을 위한 벤더 엘리멘트의 적용성 연구)

  • Jung Jae-Woo;Jang In-Sung;Mok Young-Jin
    • Journal of the Korean Geotechnical Society
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    • v.21 no.5
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    • pp.215-223
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    • 2005
  • Piezo-ceramics are special materials which transform energy from mechanical to electrical forms and vice versa. Bender elements are composite materials consisting of thin piezo-ceramics and elastic shims, and are widely used as actuators and transducers in the field of electronics, robotics, autos and mechatronics utilizing the effectiveness of energy transformation capability. In geotechnical engineering, commercial bender elements are used in laboratory as source and receiver in the measurements of soil stiffness. The elements were built by using various metal shims sandwiched between piezo-ceramics and coating over the composite in the research. A pair of elements were buried in a concrete block and used as source and receiver to measure the stiffness of the concrete. The test results were verified by comparing with the resonant column testing results. In a preliminary stage of the development of an in-situ seismic testing equipment using bender elements for soft clay materials, shear waves were generated and measured by burying the elements in the barrel of kaolinite and water mixture. The measured shear wave signals were so distinct for the first-arrival pick that applicability of the elements in the field measurements could be very promising.

Effects of Sodium Excess on Ferroelectric Properties of Bi0.5(Na0.78K0.22)0.5TiO3 Ceramics (Bi0.5(Na0.78K0.22)0.5TiO3 세라믹스의 강유전 특성에 미치는 나트륨 과잉 효과)

  • Park, Jung-Soo;Kim, Seong-Won;Jeong, Young-Hun;Yun, Ji-Sun;Paik, Jong-Hoo;Lee, Sung-Gap;Cho, Jeong-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.764-768
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    • 2016
  • To investigate excess $Na^+$ effect, $Bi_{0.5}(Na_{0.78+x}K_{0.22})_{0.5}TiO_3$ ($0{\leq}x{\leq}0.05$) (BNKT) ceramics were prepared by using a conventional solid-state reaction method. The structure and ferroelectric properties of BNKT ceramics were characterized by XRD (X-ray diffraction) and polarization dependence by external electric field. Also, the temperature dependence of dielectric constant and loss were studied. From these results, it was found that appropriate excess $Na^+$ into BNKT ceramics compensate the volatility and induce dense ceramics. The enhanced piezoelectric coefficient (158 pC/N) and depolarization temperature ($202^{\circ}C$) were obtained for the x=0.01 composition.