• Title/Summary/Keyword: physico-chemistry

Search Result 222, Processing Time 0.028 seconds

Studies on the Water Quality of Ground Water in Seoul Area and Correlation Analysis Among their Contaminants (서울지역 지하수의 오염도와 성분별 相關性 檢討)

  • Ahn, Soo-Mi;Oh, Soo-Kyoung;Park, Sung-Bae
    • Journal of Environmental Health Sciences
    • /
    • v.15 no.1
    • /
    • pp.51-62
    • /
    • 1989
  • This survey was performed to investigate contamination degree and significance in each item of 406 samples of ground water, which was collected in Seoul area from Jan. to Dec. 1988. The results of this study were as follows 1. The unsuitable rate of ground water investigated was 69.7%(32.4% in only bacteria, 23.6% in both bacteria and physico-chemistry and 13.6% in only physico-chemical contamination). 2. The unsuitable rate in each item was the highest(54.2%) in standard plate countland 29.8% in coliform, 12.8% in turbidity, 11.3% in Zn, and 10.8% in Mn. 3. The total mean concentrations in each item were lower than standard except standard plate count, coliform, and Fe. 4. In the analysis of corelation, among items, both total hardness and residual solids were showed very high correlationship (P < 0.01) with other items, and both S.P.C. and coliform showed very highly significant (P < 0.01) with NH$_3$-N.

  • PDF

Possibility of the Nondestructive Quality Evaluation of Apples using Near-infrared Spectroscopy (근적외 분광분석법을 응용한 사과의 비파괴 품질 측정 가능성 조사)

  • Sohn, Mi-Ryeong;Kwon, Young-Kil;Lee, Kyung-Hee;Park, Woo-Churl;Cho, Rae-Kwang
    • Applied Biological Chemistry
    • /
    • v.41 no.2
    • /
    • pp.153-159
    • /
    • 1998
  • A possibility of evaluation of the major internal quality factors-Brix, moisture contents, firmness and acid content in the Korean domestic 'Fuji'apple fruits by near-infrared reflectance spectroscopic (NIRS) methods were investigated. A multiple linear regression(MLR) analysis between the data obtained by physico- chemical analysis method using refractometer, freeze drier, texture analyzer and titrater and NIR spectral data was carried out to make a calibration. The standard error of prediction(SEP) of Brix, moisture, firmness and acid content were $0.50^{\circ}Brix,\;0.64%,\;0.14kg/cm^2$ and 0.07%. It is concluded that NIRS methods can be used to evaluate Brix and moisture contents of in a apple non-destructive and rapid way but the accuracy for determination of firmness and acid content was slightly low.

  • PDF

Searching of the Potent Pig Pheromonal Odorants by Receptor Based Approach (수용체 접근방법에 의한 잠재적인 돼지 페로몬 성 냄새 물질의 탐색)

  • Joo, Sung-Mo;Cho, Yun-Gi;Park, Chang-Sik;Sung, Nack-Do
    • Reproductive and Developmental Biology
    • /
    • v.34 no.3
    • /
    • pp.117-122
    • /
    • 2010
  • To search the potent pig pheromonal odorants through receptor-based approach methods, molecular dockings between 680 Flavomets as substrate molecule and pig odorants binding proteins OBP (1HQP) and PBP (1GM6) as receptor, and QSPR (quantitative structure-property relationship) analyses from physico-chemical parameters of Flavomets and their docking scores (DS) were performed and discussed quantitatively. From the basis on the findings, the optimal value $(MSA)_{opt.}=407.595\;{\AA}^2$ of MSA (molecular surface area; ${\AA}$), and RB (number of rotational bond) had the Flavomets will be able to increase DS. Therefore, it is expected that the stearyl alcohol from DS and H-bond type between substrate and receptor would be shows the character as potent pig pheromonal odorant.

Phosphoric Acid-doped SDF-F/poly(VI-co-MPS)/PTFE Membrane for a High Temperature Proton Exchange Membrane Fuel Cell

  • Lee, Jong-Won;Yi, Cheol-Woo;Kim, Keon
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.6
    • /
    • pp.1902-1906
    • /
    • 2011
  • Sulfonated poly(fluorinated arylene ether)s (SDF-F)/poly[(N-vinylimidazole)-co-(3-methacryloxypropyl-trimethoxysilane)] (poly(VI-co-MPS))/poly(tetrafluoroethylene) (PTFE) is prepared for a high temperature proton exchange membrane fuel cell (PEMFC). The reaction of the membrane with phosphoric acid forms silicate phosphor, as a chemically bound proton carrier, in the membrane. Thus-formed silicate phosphor, nitrogen in the imidazole ring, and physically bound phosphoric acid act as proton carriers in the membrane. The physico-chemical and electrochemical properties of the membrane are investigated by various analytical tools. The phosphoric acid uptake and proton conductivity of the SDF-F/poly(VI-co-MPS)/PTFE membrane are higher than those of SDF-F/PVI/PTFE. The power densities of cells with SDF-F/poly(VI-co-MPS)/PTFE membranes at 0.6 V are 286, 302, and 320 mW $cm^{-2}$ at 150, 170, and 190 $^{\circ}C$, respectively. Overall, the SDFF/poly(VI-co-MPS)/PTFE membrane is one of the candidates for anhydrous HT-PEMFCs with enhanced mechanical strength and improved cell performance.

Bioadsorbents for remediation of heavy metals: Current status and their future prospects

  • Gupta, Vinod Kumar;Nayak, Arunima;Agarwal, Shilpi
    • Environmental Engineering Research
    • /
    • v.20 no.1
    • /
    • pp.1-18
    • /
    • 2015
  • The biosorption process has been established as characteristics of dead biomasses of both cellulosic and microbial origin to bind metal ion pollutants from aqueous suspension. The high effectiveness of this process even at low metal concentration, similarity to ion exchange treatment process, but cheaper and greener alternative to conventional techniques have resulted in a mature biosorption technology. Yet its adoption to large scale industrial wastewaters treatment has still been a distant reality. The purpose of this review is to make in-depth analyses of the various aspects of the biosorption technology, staring from the various biosorbents used till date and the various factors affecting the process. The design of better biosorbents for improving their physico-chemical features as well as enhancing their biosorption characteristics has been discussed. Better economic value of the biosorption technology is related to the repeated reuse of the biosorbent with minimum loss of efficiency. In this context desorption of the metal pollutants as well as regeneration of the biosorbent has been discussed in detail. Various inhibitions including the multi mechanistic role of the biosorption technology has been identified which have played a contributory role to its non-commercialization.

SBA-15 Supported Fe, Ni, Fe-Ni Bimetallic Catalysts for Wet Oxidation of Bisphenol-A

  • Mayani, Suranjana V.;Mayani, Vishal J.;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.12
    • /
    • pp.3535-3541
    • /
    • 2014
  • Bisphenol A is considered as pollutant, because it is toxic and hazardous to living organisms even at very low concentrations. Biological oxidation used for removing this organic from waste water is not suitable and consequently application of catalytic wet oxidation has been considered as one of the best options for treating bisphenol A. We have developed Fe/SBA-15, Ni/SBA-15 and Fe-Ni/SBA-15 as heterogeneous catalysts using the advanced impregnation method for oxidation of bisphenol A in water. The catalysts were characterized with physico-chemical characterization methods such as, powder X-ray diffraction (PXRD), FT-IR measurements, N2 adsorption-desorption isotherm, thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis. This work illustrates activity of the catalysts for heterogeneous catalytic degradation reaction revealed with excellent conversion and recyclability. The degradation products identified were not persistent pollutants. GC-MS analysis identified the products: 2,4-hexadienedioic acid, 2,4-pentadienic acid and isopropanol or acetic acid. The leachability study indicated that the catalysts release very little metals to water. Therefore, the possibility of water contamination through metal leaching was almost negligible.

Removal of chromium from tannery wastewater by electrosorption on carbon prepared from peach stones: effect of applied potential

  • Ziati, Mounir;Khemmari, Fariza;Kecir, Mohamed;Hazourli, Sabir
    • Carbon letters
    • /
    • v.21
    • /
    • pp.81-85
    • /
    • 2017
  • The objective of this study is the removal of chromium from tannery wastewater by electrosorption on carbon prepared from lignocellulosic natural residue "peach stones' thermally treated. The followed steps for obtaining coal in chronological order were: cleaning, drying, crushing and finally its carbonization at $900^{\circ}C$. The characterization of the carbon material resulted in properties comparable to those of many coals industrially manufactured. The study of the dynamic adsorption of chromium on the obtained material resulted in a low removal rate (33.7%) without applied potential. The application of negative potentials of -0.7 V and -1.4 increases the adsorption of chromium up to 90% and 96% respectively. Whereas a positive potential of +1.4V allows desorption of the contaminant of 138%.

Changes of the Physico-Chemical and Microbiological Properties during Composting for Composting of Sewage Sludge (하수슬러지의 퇴비화과정 중 이화학성 및 미생물상 변동)

  • Lee, Hong-Jae;Cho, Ju-Sik;Bahn, Kyeong-Nyeo;Heo, Jong-Soo;Shin, Won-Kyo
    • Korean Journal of Environmental Agriculture
    • /
    • v.17 no.1
    • /
    • pp.16-21
    • /
    • 1998
  • To study the possibility of agricultural utilization of sewage sludge, the changes of the substances physico-chemical and microbiological properties composting periods such as inorganic matter, the form of organic matter and nitrogen and the kinds and the population number of microorganisms were investigated. The results were summarized as follows ; Temperature and $CO_2$ generation, they were the highest in the second day of composting periods and then were gradually fallen. pH value was not changed in first day during composting periods, but in second day was rapidly increased and then it was constant of the range of 8.4∼8.6. The contents of $P_2O,\;K_2O$, CaO and Fe were a little increased during composting periods, while that of ${SO_4}^{2-}$and Mn were big increased with 253${\sim}$331% and 191${\sim}$208% in late composting periods in comparing with early composting periods, respectively. The contents of ether extracted materials, water soluble polysaccharides, hemicellulose and cellulose were decreased but that of resins and lignin were not changed during composting periods. The contents of total and organic nitrogen during composting periods were decreased with 15${\sim}$20% and 22${\sim}$35%, respectively, while that of inorganic nitrogen was decreased with 75${\sim}$116%. The population numbers of microorganism during composting periods was much too changed according to the kinds of microorganism and composting periods.

  • PDF

Studies on Antibiotic Producers of Korean Soil Microbes (IV) -Isolation and Antibiotic Activity of Streptomyces Strain DMC-42- (한국(韓國) 토양균(土壤菌)중 항생물질(抗生物質) 생성균(生成菌)에 관한 연구(硏究) 제 4 보(第4報) -스트렙토마이세스속(屬) 균주(菌株) DMC-42의 분리(分離) 및 그 항균작용(抗菌作用)-)

  • Kim, Hwa-Ki;Kim, Jung-Woo;Kim, Ha-Won;Choi, Eung-Chil;Kim, Byong-Kak
    • The Korean Journal of Mycology
    • /
    • v.13 no.2
    • /
    • pp.89-97
    • /
    • 1985
  • To find antibacterial strains of the soil microorganisms in Korea, they were isolated from the soil samples of different locations and screened for antibacterial activity against several standard microorganisms. An isolate among them had antibacterial activities against gram-positive and gram-negative bacteria. The examination of its morphological, biochemical, cultural and physiological characteristics according to the International Streptomyces Project methods showed that it belongs to the genus Streptomyces. This strain appears to be a novel strain when it was compared with those species of the genus which have been so far reported. The antibiotic metabolite was produced in the submerged culture of the strain. This metabolite was extracted from the culture filtrate and purified by ion-exchange column chromatography. Physico-chemical properties of the antibacterial metabolite were characterized.

  • PDF

Arsenic Movement in the Soils around a Closed Zinc Mine (폐 아연 광산 주변 토양에서 비소의 이동양상)

  • Seo, Young-Jin;Choi, Jyung;Kang, Yun-Ju;Park, Man;Kim, Kwang-Seop;Lee, Young-Han;Komarneni, Sridhar
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.43 no.1
    • /
    • pp.51-59
    • /
    • 2010
  • The sediments and soils around a mine are likely to be exposed to contamination of arsenic (As) through mining operations. In this study, the factors associated with As movement in soils around a closed zinc (Zn) mine were evaluated by the relationship of As distributions to physico-chemical properties of soils. A sequential extraction scheme, based on a soil P fractionation, was used to assess the As distributionsin solid phases. A significant difference in As distributions was found between paddy and upland soils. While As contents of paddy soils increased with soil depth, those of upland soils decreased with soil depth. In upland soils, As showed additional significant relationships to oxides of Si, Al and Fe. Although a major fraction of As in soils was found to be in the NaOH extractable fraction, As exhibited highly significant relationship to the Zn species that apparently originated from the mine. Therefore, As mobility around Zn mine seems to be governed by mass flow of the particulates containing As-associated Zn in paddy soils, whereas retention reactions such as adsorption, complexation, and precipitation seem to predominate in upland soils.