• Title/Summary/Keyword: photosensitive

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Photosensitive Effect of Poly(vinyl cinnamoyl acetate) by New Squarylium Dyes(I) (신규 Squarylium Dyes 증감제에 의한 Poly(vinyl cinnamoyl acetate)의 고감도화(I))

  • 손세모;박진화
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.1-13
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    • 1998
  • Some photopolymer, poly(vinyl cinnamoyl acetate)(PVCiA) was synthesized by esterification of polymer(vinyl alcohol(PVA) with monochloroacetic acid, followed by reaction poly(vinyl monochloroacetate)(PVChA) and potassium cinnamate. When esterification of PVA with monochloroacetic acid was reacted in the dimethyl sulfoxide(DMSO), in the synthesis of PVChA, it is very good yield and the successive cinnamoyl acetoxyl esterification of PVCiA can be successfully synthesized. But PVCiA is low photosensitive polymer if not added photosensitizing dyes. Here, we synthesized photosensitizing dyes. trifluoromethylindol squarylium dye derivatives(TFSQ). Indolization of 3-trifluoromethylphenyl-hydrazine formed 4- and 6-substituted indoles, the rate of 4- and 6-substituted indoles is close to unity. Absorption's coefficient of 1,3-bis(4-trifluoromethyl-1,3,3-trimethylindol) squarylium dye(TFSQ) is 7.57$\times$10\ulcorner, PVCiA added with TFSQ(3%) was highly sensitized six times than not added.

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Research of the TFT-LCD Photosensitive Resist Thickness

  • Zhang, Mi;Xue, Jian She;Wang, Wei;Park, Chun-Bae;Koh, Jai-Wan;Zhang, Zhi-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1269-1271
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    • 2008
  • We find some array mura are caused by S/D bridge or channel open in 4 mask process. The gray tone PR thickness non-uniformity is the main reason of these defects. By the adjustment of exposure and dry etch parameters, S/D bridge and channel open ratio drops by 10.87%.

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The Photosensitive Insulating Materials as a Passivation Layer on a-Si TFT LCDs

  • Lee, Liu-Chung;Liang, Chung-Yu;Pan, Hsin-Hua;Huang, G.Y.;Gan, Feng-Yuan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.695-698
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    • 2006
  • The photosensitive poly-siloxane material used as the passivation layers for the conventional back channel etched (BCE) thin film transistors (TFTs) has been investigated. Through the organic material, the TFT array fabrication process can be reduced and higher aperture ratio can be achieved for higher LCD panel performance. The interface between the organic passivation layer and the back channel of the amorphous active region has been improved by the back channel oxygen treatment and the devices exhibits lower leakage current than the conventional silicon nitride passivation layer of BCE TFTs. The leakage currents between Indium-tin-oxide (ITO) pixels and the TFT devices and its mechanism have also been investigated in this paper.

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Photolithographic Method of Patterning Barrier Ribs for PDP by Green Sheet

  • Park, Lee-Soon;Jang, Dong-Gyu;Hur, Young-June;Lee, Sung-Ho;Kim, Duck-Gon;Kwon, Young-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1225-1228
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    • 2005
  • Barrier ribs in the plasma display panel(PDP) function to maintain the discharge space between the glass plates as well as to prevent optical crosstalk. Patterning of barrier ribs is one of unique processes for making PDP. In this work photosensitive barrier rib pastes were prepared by incorporating binder polymer, solvent, functional monomers photoinitiator, and barrier rib powder of which surface was treated with fumed silica particles. Study on the function of materials for the barrier rib paste were undertaken. After optimization of paste formulation and photolithographic process, it was found that photolithographic patterning of barrier ribs with photosensitive barrier rib green sheet could be used in the fabrication of high resolution PDP.

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Field Emission properties of photosensitive carbon nanotube paste with different inorganic binders

  • Park, Jae-Hong;Moon, Jin-San;Jeong, Jin-Soo;Yoo, Ji-Beom;Park, Chong-Yun;Nam, Joong- Woo;Park, Jong-Hwan;Choe, Deok-Hyeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1451-1454
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    • 2005
  • We report effects of inorganic binder on the emission properties of CNT paste for low cost and high low-cost and large area field emission devices or displays. Two types of photosensitive carbon nanotube (CNT) paste were formulated by using of glass frit and spin on glass (SOG) as an inorganic binder and investigated their emission properties according to inorganic binders and firing conditions.

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A study on the crystallization processing of photosensitive glass by FT-IR and FT-Raman spectroscopy (FT-IR과 FT-Raman 분광계를 이용한 광민감유리의 결정화 과정에 관한 연구)

  • 이명원;강원호
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.284-288
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    • 1997
  • FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.

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Fabricationof small size catridge for electrolyte measurement including flow-channel and microsensors (Flow-channel과 microsensor를 내장한 전해질 측정용 소형 카트리지 제작)

  • 이영철;조병욱;김창수;고광락;손병기
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.4
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    • pp.78-83
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    • 1998
  • A small size cartrideg for FET type electrolyte sensor is designed and faricated with much simplified process by using micromachining tenchiques such as silicon etching andglass bonding. Size of the whole cartideg is 2.4cm*2.5cm, and the dead volume of a micro flow-channel in the cartrideg is only 8.5.mu.l. The photosensitive polymer(THB 30) is used to define a micropool and to encapsulate the sensor surface for standardizationof electrolyte sensors. To miniaturize micro flow-channel conventional reference electrode(Ag/AgCl) a differential amplification is introduced using REFET and quasi reference electrode. Refet was fabricated using photosensitive polymer(OMR 83). The fabricated cartridge with built-in pH-ISFET showed good operational characteristics such as linearity and high sensitivity (55.4mV/pH) in a wide pH range(pH2-pH12).

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Crystallization in Li20-A1203-Si02 Glass induced by 355nm Nd:YAG Laser Irradiation

  • Lee, Yong-Su;Kang, Won-Ho;Song, Sun-Dal
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.04a
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    • pp.112-117
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    • 2000
  • Nd:YAG laser of 355nm wavelength, which amounts to 3.5eV, produced by a harmonic generator was used to create Ag metallic particles as seeds for nucleation in photosensitive glass containing Ag+ and Ce3+. The pulse widths and frequency of the laser were 8ns and 10Hz, respectively. For crystalline growth, heat-treatment following laser irradiation was carried out at $570^{\circ}C$ fur 1h. Then, the LiAlSi3O8. crystal phase appeared in the laser irradiated lithium aluminum silicate glass. We present the effect of laser-induced nucleation compared with spontaneous nucleation by heat treatment for crystallization in the glass.

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VISIBLE LASER POLYMERIZATIONS WITH THE SULFONIUM BORATE STYRYL DYES AS NEW PHOTOINITIATOR SYSTEMS

  • Toba, Yasumasa;Yasuike, Madoka;Usui, Yoshiharu
    • Journal of Photoscience
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    • v.5 no.2
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    • pp.63-67
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    • 1998
  • New photoinitiator systems of dimethylphenacylsulfonium butyltnphenylborate (DMPSB) as a donor-acceptor initiator and styryl dyes have been investigated for free radical polymerization of an acrylate with visible lasers (488, 514 and 647 nm). DMPSB was able to be sensitized by many styryl dyes. When polymerized with pentaerythrithol triacrylate, the sensitivity value of the photosensitive layer containing DMPSB was higher than that of an tetrabutylammonium butyltnphenylborate (TBAB) as an electron donating initiator or a dimethylphenacylsulfonium tetrafiuoroborate (DMPS) as an electron accepting initiator. The sensitivity values of the photosensitive layer containing the photoinitiator systems had a close relation to the free energy changes between the excited singlet styryl dyes and DMPSB.

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Synthesis of the photochromic and electrochromic dyes and their sensible properties (I) - Dyeing application with photochromic moiety to the fiber substrate- (광변색성 및 전기변색성 색소의 합성 및 특성(I) -광변색성 특성의 섬유소재에의 응용-)

  • Son Young-A;Park Young-Min;Kim Byung-Soon;Kim Sung-Hoon
    • Textile Coloration and Finishing
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    • v.18 no.2 s.87
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    • pp.24-30
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    • 2006
  • The photosensitive spiroxazine compound and the electrosensitive viologen compound were prepared to examine their practical application feasibilities and behaviors. These dyes represent corresponding chromism effects related to their own characteristics of the dye molecules. Thus, the prepared dyes were characterized and their absorption spectra were also investigated. Besides, an interest on direct spiroxazine exhaustion to the polyamide substrates and its photochromic effects within the fiber molecules were determined. The photochromic reaction on the substrates was clearly observed and its reversible decoloration behaviors responded.