• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1255-1260
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• 2004

Decomposition of ozone at room temperature was investigated comparatively with commercial monolithic ozone decomposition catalyst (ODC, $MnO_2$) and monolithic photo catalyst ($TiO_2$). The effects of residence time, UV (ultraviolet) light dependence and ozone concentration on the conversion was presented. UV ray was irradiated using BLB (black light blue) lamp ($315{\sim}400$ nm), supplied with a constant intensity in the reactor. The concentration of ozone in the square-shape reactor can be controlled by combining the DBD (dielectric barrier discharge) reactor with an AC high voltage supply system. The catalytic performance, in presence of UV irradiation did not show significant changes for $MnO_2$ catalyst. $TiO_2$ catalyst was the different case, which showed higher decomposition activity in presence of UV irradiation. Deactivation of catalyst detected by real-time ozone monitor for 120 hours with a constant inlet ozone concentration.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2009년도 하계학술발표대회 논문집
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• pp.98-101
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• 2009

Photo-catalyst technology to the decomposition of formaldehyde, and many are capable of VOC. In this research, effects of screw type photo-catalyst device will announce the experimental results.

• 한국대기환경학회지
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• 제21권4호
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• pp.431-438
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• 2005

In order to apply the photocatalytic decomposition of aromatic VOCs, adsorbent prepared from MSWI fly ash was coated by $TiO_2$ solution to endow with photo-catalytic function. The effects of coating number, existence of light source and the type of $TiO_2$ solution used for coating were examined. Adsorbent coated with amorphous $TiO_2$ solution showed higher adsorptivity than adsorbent coated with crystal $TiO_2$ solution. Without light source, breakthrough curve of photo -catalyst absorbent for VOCs removal was similar to that of absorbent made from MSWI fly ash. On the other hand, breakthrough time was enlarged with light source and total removal efficiency of benzene and toluene was also increased. It can be explained as photo-decomposition effect of $TiO_2$ photo-catalyst. Total removal efficiency of benzene and toluene was increased according to the increase of coating number with light source. It was due to the effect of adsorption and photo reaction of photo-catalytic adsorbent. But total removal efficiency of benzene was lower than that of toluene. Because benzene was removed more effectively than toluene by adsorption, but photo - decomposition effect oi toluene was more high than benzene.

• 한국건설순환자원학회논문집
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• 제7권4호
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• pp.423-430
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• 2019

본 연구에서는 콘크리트 보도블록의 표층에 광촉매를 적용하여 광촉매 혼입률 및 블록 표면워싱 유무 등에 따른 휨강도, 흡수율, 메틸렌블루 광촉매 분해 성능 및 방오성능을 평가하였다. 실험결과, 콘크리트 블록 표면층에만 광촉매를 혼입한 블록의 휨강도는 광촉매 무혼입인 기준콘크리트 블록의 휨강도 5.46MPa과 비교하여 광촉매 5% 혼입 일반블록(SNW) 5.32MPa로 나타났으며, 표면워싱블록(SW) 5.26MPa, 광촉매 10%혼입 일반블록(SNW) 5.26MPa, 표면워싱블록(SW) 5.15MPa로 나타나 콘크리트 블록의 표면 워싱 유무 및 광촉매 혼입율이 휨강도에 미치는 영향은 없는 것으로 나타났다. 또한 콘크리트 보도블록의 광촉매 분해성능은 이산화티타늄이 5% 혼합된 시편의 메틸렌블루 제거율은 34.2%, 이산화티타늄이 10% 혼합된 시편의 메틸렌블루 제거율은 37.1%, 세척을 실시한 경우 이산화티타늄이 5% 혼합된 시편의 경우 제거율은 약 37.9%, 10% 혼합된 시편의 메틸렌블루 제거율은 약 37.6%로 나타났다.

• 센서학회지
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• 제16권1호
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• pp.7-10
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• 2007

A thick film catalytic gas sensors which can be operated at $142^{\circ}C$ in presence of ultra violet-light emitting diode has been developed to measure hydrogen concentration in 0-5 % range. The sensing material as a combustion catalyst consists of $TiO_{2}$ (5 wt%) and Pd/Pt (20 wt%) supported on $Al_{2}O_{3}$ powder and the reference material to compensate the heat capacity of it in a bridge circuit was an catalyst free $Al_{2}O_{3}$ powder. Platinum heater and sensor materials were formed on the alumina plate by screen printing method and heat treatment. The effect of UV radiation in the presence of photo catalyst $TiO_{2}$ on the sensor sensitivity, response and recovery time has been investigated. The reduction of operating temperature from $192^{\circ}C$ to $142^{\circ}C$ for hydrogen gas sensing property in presence of UV radiation is attributed to the hydroxy radical and superoxide which was formed at the surface of $TiO_{2}$ under UV radiation.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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• pp.2870-2874
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• 2011

Soil pollution around railroad has been occurred mainly by diesel and lubricant oil, which is difficult to treat due to high carbon number. In this study, we investigated the feasibility of inorganic-inorganic nanohybrid photo-catalyst for the remediation of diesel-contaminated railroad soil. Generally, the $TiO_2$ nanoparticle easily removes organic pollutants due to photo and natural clay of layer structure. Also, montmorillonite (MMT) have an excellent absorption property with organic component. So, we prepared $TiO_2$ pillared MMT nanohybrid photo-catalyst as a chemical oxidant through the integration of theses advantage. As a result, the removal efficiency of diesel was more than 45% at a laboratory-scale test with diesel concentration and the amount of $TiO_2$-MMT. In future, we will improve the removal efficiency of diesel to optimize experimental parameters and apply the field soil The remediation method using photo-catalyst can be used to clean up the railroad soil polluted with high concentration instead of common methods such as soil washing, bioremediation, etc..

• 한국물환경학회지
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• 제18권4호
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• pp.387-394
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• 2002

본 연구는 $TiO_2$ 광촉매 및 응집-여과-중화공정을 거친 아크릴폐수를 UF(tubular)/RO(spiral wound)공정에 적용하여 적용압력과 온도변화에 따른 성능변화를 고찰하였다. 한외여과 관형모듈에서 광촉매 전처리수와 응집-여과-중화 전처리수의 COD, T-N은 온도 및 압력변화에 크게 영향을 받지 않고, 제거효율도 낮은 것으로 확인할 수 있었다. TDS 및 turbidity의 경우 한외여과 관형 모듈에서 광촉매 전처리수가 응집-여과-중화공정의 처리수에 비해 처리효율이 우수함을 확인하였다. T-N, TDS는 역삼투막 공정에서 우수한 제거효율을 나타내었다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제51권12호
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• pp.567-572
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• 2002

In these days, diesel vehicle or power plant emits $NO_X\; and SO_2$ which cause air pollution like acid-rain, ozone layer destroy and optical smoke, therefore there are many kinds of methods considered for removing them such as SCR, catalyst, plasma process, and plasma-catalyst hybrid process. T$TiO_2$ is commonly used as catalyst to remove $NO_X$ gas because it have very excellent chemical characteristic as photo catalyst. In this paper, $NO_X$ sensing characteristic of $TiO_2$ thin film deposited by R.F Magnetron sputtering is investigated. A finger shaped electrode on $Al_2$O$_3$ substrate is designed and $TiO_2$ is deposited on the electrode by the magnetron sputtering deposition system. Chemical composition of the deposited $TiO_2$ thin film is $TiO_{1.9}$ by RBS analysis. When the UV is irradiated on it with flowing air, capacitance of $TiO_2$ thin film increases, however, when NO gas is put into the system with air, it immediately decreases because of photo chemical reaction. and it monotonously decreases with increasing NO concentration.

• 한국수소및신에너지학회논문집
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• 제1권1호
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• pp.9-14
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• 1989

Mixed photocatalyst containing cadmium sulfide and zinc sulfide was prepared on silica gel powder and Nafion film. Photo-irradiation of aqueous mixture containing the photocatalysis generated hydrogen by water cleavage reaction. Use of sodium sulfide as sacrificial reagent help the photo-reaction. Evolution of the hydrogen was measured by gas chromatographic analysis. Composition of the catalyst was determined by atomic absorption spectrophotometer. 0.2 mL of of hydrogen was generated per hour. The maximun catalytic activity was obtained after 8-12 hours later. Hydrogen generation efficiency by the two different catalytic system was compared and showed that the Nafion-based catalyst is more efficient than the silicagel-based catalyst for the photoreaction.

• 상하수도학회지
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• 제18권3호
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• pp.392-400
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• 2004

This research uses the $TiO_2$/UV process to verify the most suitable condition and possibility to dispose dyeing wastewater that contains pigment and a large amount of pollutants. For this, this research has enforced experiments that compare photo adsorption, photolysis, and photo catalyst oxidation reaction, and also evaluated and analyzed the change of pH and $TiO_2$ dosage, irradiation rates of ultraviolet rays and the dosage change and injection method of $H_2O_2$. According to the results of the dyeing wastewater experiment of storehouse catalyst that uses the new form of $TiO_2$, the photo catalyst oxidation reaction proved to be more effective than photo adsorption and photolysis; 35%, 21% in the case of $TCOD_{cr}$ and 39%, 28% in the case of chromaticity. Taking into consideration the reaction time, amount of photo catalyst reaction and irradiation amount of ultraviolet rays, the decomposition efficiency of pH change proved to be most effective at pH 4. On the whole, the acidity area proved to be effective in dyeing water exclusion than neutral and alkalinity areas. Having evaluated the influence of $TiO_2$ dosage, not only does the decomposition efficiency continuously improve as the $TiO_2$ dosage increases but the shielding effect does not occur also when the $TiO_2$ is at a fixed state. The influence of ultraviolet irradiation amount concluded in the result that as the ultraviolet irradiation amount increases the decomposition efficiency continually increased, but in the case of chromaticity when the irradiation amount was higher than 37.8mW/cm2 the removal efficiency is slowed remarkably. The influence of $H_2O_2$ dosage evaluation reached the results that although the decomposition efficiency increases with the increase of $H_2O_2$ dosage, when above 150mg (total dosage: 1200mg) $H_2O_2$ consumes OH radical itself and reduces the decomposition efficiency. Also in the case of the $H_2O_2$ injection method rather than injecting in the whole amount of $H_2O_2$ (1200mg) needed at the beginning all at once, injecting divided quantities of $H_2O_2$ whenever the electric current density falls below 10mgfl reduces the wases of OH radical due to an excess of $H_2O_2$ and in tum heightens the decomposition efficiency.