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http://dx.doi.org/10.5369/JSST.2007.16.1.007

Catalytic combustion type hydrogen gas sensor using TiO2 and UV LED  

Hong, Dae-Ung (Department of Electrical and Electronic Engineering, Yonsei University)
Han, Chi-Hwan (Photo- & Electro-Materials Research Center, Korea Institute of Energy Research)
Han, Sang-Do (Photo- & Electro-Materials Research Center, Korea Institute of Energy Research)
Gwak, Ji-Hye (Photo- & Electro-Materials Research Center, Korea Institute of Energy Research)
Lee, Sang-Yeol (Department of Electrical and Electronic Engineering, Yonsei University)
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Abstract
A thick film catalytic gas sensors which can be operated at $142^{\circ}C$ in presence of ultra violet-light emitting diode has been developed to measure hydrogen concentration in 0-5 % range. The sensing material as a combustion catalyst consists of $TiO_{2}$ (5 wt%) and Pd/Pt (20 wt%) supported on $Al_{2}O_{3}$ powder and the reference material to compensate the heat capacity of it in a bridge circuit was an catalyst free $Al_{2}O_{3}$ powder. Platinum heater and sensor materials were formed on the alumina plate by screen printing method and heat treatment. The effect of UV radiation in the presence of photo catalyst $TiO_{2}$ on the sensor sensitivity, response and recovery time has been investigated. The reduction of operating temperature from $192^{\circ}C$ to $142^{\circ}C$ for hydrogen gas sensing property in presence of UV radiation is attributed to the hydroxy radical and superoxide which was formed at the surface of $TiO_{2}$ under UV radiation.
Keywords
$H_{2}$ gas sensor; catalytic sensor; UV radiation$TiO_{2}$ photo-catalyst;
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1 C.-H. Han, S.-D. Han, and J.-D. Kim, 'Micro-hydrogen gas sensor using $SnO_2$ coated F-doped $SnO_2$', 한국센서학회 종합학술대회 논문집, 제16권, 제1호, pp. 158-161, 대전, 한국, 2005
2 D. U. Hong, c.-H. Han, I.-J. Kim, S.-D. Han, and B.-S. Lee, 'Catalytic combustible hydrogen sensor using crystalline F-doped $SnO_2$', 한국센서학회 종합학술대회 논문집, 제16권, 제1호, pp. 292-293, 대전, 한국, 2005
3 S. J. Gentry and T. A. Jones, 'The role of catalysts in solid-state gas sensors', Sens, Actuators, vol. 10, pp. 141-163, 1986   DOI   ScienceOn
4 M. G. Jones and T. G. Nevell, 'The detection of hydrogen using catalytic flammable gas sensors', Sens. Actuators, vol. 16, pp. 215-224, 1989   DOI   ScienceOn
5 V. R. Katti, A. K. Dehnath, S. C. Gadkari, S. K. Gupta, and V. C. Sahni, 'Passivated thick film catalytic type H2 sensor operating at low temperature', Sens. Actuators B, vol. 84, pp. 219-225, 2002   DOI   ScienceOn
6 J. Saura, 'Gas-sensing properties of $SnO_2$ pyrolytic films subjected to ultra violet radiation', Sens. Actuators B, vol. 17, pp. 211-214, 1994   DOI   ScienceOn
7 P. Camagni, G. Faglia, P. Galinetto, C. Perego, G. Samoggia, and G. Sberveglieri, 'Photo sensitivity activation of $SnO_2$ thin film gas sensors at room temperature', Sens. Actuators B, vol. 31, pp. 99-103, 1996   DOI   ScienceOn
8 E. Comini,. A crestal!i, G. Faglia, and G. Sberveglieri, Sens. Actuators B, vol. 65, pp. 260-263, 2000   DOI   ScienceOn
9 S. Shukla, R. Agrawal, H. J. Cho, and S. Seal, 'Effect of UV radiation exposure on room temperaturehydrogen sensitivity of nano crystalline doped tin oxide sensor incorporatedinto microelectro mechanical system device', J. Applied Physics, vol. 97, 054307, 2005   DOI   ScienceOn
10 G. K. Mor, M. A. Carvalho, O. K. Varghege, M. V. Pishko, and C. A. Grimes, 'A room temperature $TiO_2$-nanotube hydrogen sensor able to self clean photo activity from environmental contamination', J. Mater. Res., vol. 19, pp. 628-634, 2004   DOI   ScienceOn
11 J. J. Carr, 'Sensors & Curcuit, PTR Prentice Hall Englewood Cliffs', New Jersey 07632, p. 75, 1993
12 P. T. Moseley and B. C. Tofrield, 'Solid state gas sensors', lOP Publishing Ltd. Adam Hilger, Bristal, U. K. 1987
13 D. C. Young, G. A. Mill, and R. Wall, 'Feasibility of renewable energy storage using hydrogen in remote communities in Bhutan', International J. of Hydrogen Energy, 2006, in press
14 V. A. Goltsov and T. N. Veziroglu, 'A step on the road to hydrogen civilization', International J. of Hydrogen Energy, vol. 27, pp.719-723, 2004
15 J. G Firth, A. Jones, and T. A. Jones, 'Principle of the detection of flammable atmospheres by catalytic devices', Combust. Flame., vol. 21, pp. 303-311, 1973
16 M. A. DeLuchi, 'Hydrogen vehicles: An evaluation of fuel storage, performance, safety, environmental impacts and costs', International J. of Hydrogen Energy, vol. 14, pp. 81-130, 1989   DOI   ScienceOn
17 S. H. Browne, D. R. Neill, and P. K. Takahashi, 'The Hawaii hydrogen from renewable energy program', International J. of Hydrogen Energy, vol. 13, pp. 483-488, 1989