• Title/Summary/Keyword: phase transitions

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Photoluminescence Property of Lu2Si2O7:Ce3+ Powder for Scintillator

  • Kim, Kyung-Nam;Cao, Guozhong
    • Korean Journal of Materials Research
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    • v.26 no.4
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    • pp.212-215
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    • 2016
  • In this paper, cerium doped lutetium pyrosilicate (LPS) powders with cerium content (0.05 and 0.07 mol%) were prepared by sol-gel process. The formation of lutetium pyrosilicate (LPS) phase was confirmed by XRD analysis for the powders heated at $1,200^{\circ}C$; in these powders, a single phase of $Lu_2Si_2O_7$ (LPS) was observed. Cerium doped lutetium pyrosilicate (LPS) powder was agglomerated and constituted of small spherical particles with diameters of about 300 nm. The photoluminescence spectra of the $Lu_2Si_2O_7:Ce^{3+}$ powders showed the characteristic of excitation and there was an emission spectrum for $Ce^{3+}$ in the host of $Lu_2Si_2O_7$. The emission spectrum shows a broad band in the range of 350-525 nm; the broad wavelength on the right side of the spectra should be ascribed to the same 5d-4f transitions of $Ce^{3+}$, as in the case of cerium doped $Lu_2Si_2O_7$ single crystals.

Application of CRAMPS for a Phase Transition in H+-ion irradiated TlH2PO4

  • Kim, Se-Hun;Han, J.H.;Lee, Cheol-Eui;Lee, Kwang-Sei;Kim, Chang-Sam;Dalal, N.S.;Han, Doug-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.14 no.2
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    • pp.134-143
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    • 2010
  • We studied the hydrogen-bonded $TlH_2PO_4$ (TDP) ferroelectrics treated with the proton-beam bombardment. The TDP material was irradiated with 1-MeV proton beam at a dose of $10^{15}/cm^2$. In order to analyze the hydrogen environment in TDP, we carried out the $^1H$ high resolution nuclear magnetic resonance (NMR) - i.e., Combined Rotation And Multiple Pulse Spectroscopy (CRAMPS) measurement. The isotropic chemical shift of hydrogen indicates its displacive property is related to the $PO_4$ lattice deformation which occurs throughout the antiferroelectric-, the ferroelastic- and the paraelastic-phase transitions. The temperature dependence of $\sigma_{iso}$ reveals the electronic charge redistribution is induced by the proton-beam irradiation and the elastic property.

Structure and Electric Properties of PZT Ceramics Substituted by La and Nd (La와 Nd가 치환된 PZT 세라믹의 구조 및 전기적 성질)

  • Jung, Soo-Cheol;Park, Hyu-Bum;Kim, Jeong;Kim, Keon;Kim, Si-Joong
    • Journal of the Korean Ceramic Society
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    • v.31 no.2
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    • pp.155-160
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    • 1994
  • PZT ceramics substituted by La3+ and Nd3+ were fabricated according to the formula: [Pb1-x(La or Nd)x][Zr0.58Ti0.42]1-x/4$\square$x/4O3(x=0.00, 0.02, 0.05, 0.08, 0.15, 0.20). The crystal structure and microstructure were investigated by XRD and SEM. It was observed that the phase transitions among rhombohedral, tetragonal, and cubic symmetry occured as the substitutional quantity increased. Dielectric constant, dissipation factor and piezoelectric coefficient (d33), of each sample were measured. The dielectric properties were changed as the substitutional quanity of rare earth ion increased. These changes could be explained by crystal structure and compositional fluctuaction. Its d33 was higher at tetragonal region near to phase boundry between rhombohedral and tetragonal, which was explained by reorientation of domain wall.

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InGaAs/InAlAs Quantum Cascade Lasers Grown by using Metal-organic Vapor-phase Epitaxy

  • Kim, Dong Hak;Jeong, Hae Yong;Choi, Young Su;Park, Deoksoo;Jeon, Young-Jin;Jun, Dong-Hwan
    • Applied Science and Convergence Technology
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    • v.26 no.5
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    • pp.139-142
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    • 2017
  • In this paper, InP-based InGaAs/InAlAs quantum cascade lasers(QCLs) providing nearly zero emission wavelength mismatch between the measured emission wavelength and the designed transition wavelength of QCLs is presented. The zero emission wavelength mismatch of QCLs influenced by both the accurate compositions and thicknesses of the low-pressure metal-organic vapor-phase epitaxy(MOVPE) grown InGaAs and InAlAs layers throughout the core and the abrupt composition transitions between InGaAs and InAlAs layers. The abrupt interfaces between InGaAs and InAlAs layers have been achieved throughout the core structure by means of controlling individually purged vent/run valves of a closed coupled showerhead reactor. In addition, maintaining substrate temperature constant during InGaAs/InAlAs core growth was a partial factor of uniformity improvement of QCLs. These approaches for reducing the possible discrepancies between the designed and MOVPE grown epitaxial structures could lead to improvement of QCL performance.

Structural and Dielectric Properties of $Pb(Mg_{1/3}Nb_{2/3})O_3$ Ceramics Substituted by Nd, La, K and Na (Nd, La, K, Na이 치환된 $Pb(Mg_{1/3}Nb_{2/3})O_3$ 세라믹의 구조 및 유전 성질에 관한 연구)

  • Kweon, Sook-Hwa;Park, Hyu-Bum;Kim, Jeong;Hong, Young-Sik;Kim, Si-Joong
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.839-845
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    • 1995
  • The structural and dielectric properties of Pb(Mg1/3Nb2/3)O3 ceramics substituted by Nd3+, La3+, K+ and Na+ were studied over 0~50 at.% substituent content. The 1 : 1 ordering behavior of Mg2+ and Nb5+ ions in the B site sublattice was observed in Nd3+-and La3+-modified compounds. The degree of ordering was increased with Nd3+, La3+ content in the compounds. But K+-or Na+-modified compounds did not exhibit the ordering behavior. This was explained by charge and size effect of A and B site cations and oxygen vacancies. As the mole fractions of substituent increased, the maximum values of dielectric constants were rapidly decreased and the phase transitions were broadened. Phase transition temperature was correlated with the covalency of A-O and B-O bonding.

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Magnetic Properties of Polycrystalline ErFe2O4 (ErFe2O4 다결정체 시료의 자기적 특성 연구)

  • Kim, J.;Lee, B.W.
    • Journal of the Korean Magnetics Society
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    • v.18 no.6
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    • pp.217-220
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    • 2008
  • We have investigated the magnetic properties of $ErFe_2O_4$. Stoichiometric polycrystalline sample of $ErFe_2O_4$ was prepared by solid-state reaction method in a stream of CO/$CO_2$ gas. The X-ray power diffraction pattern shows that the diffraction peaks are indexed with respect to the rhombohedral structure with a space group of R3m. The temperature dependent magnetization for $ErFe_2O_4$ shows two-step phase transitions at about 220 and 250 K. The transition at 250 K is an antiferromagnetic transition and that at 220 K is a structural transition.

Thermoelectric Properties of Co1-xNixSb3 Prepared by Encapsulated Induction Melting (밀폐유도용해로 제조한 Co1-xNixSb3의 열전특성)

  • Kim, Mi-Jung;Choi, Hyun-Mo;Ur, Soon-Chul;Kim, Il-Ho
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.377-381
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    • 2006
  • Skutterudite $CoSb_3$ doped with nickel was prepared by encapsulated induction melting, and its doping effects on thermoelectric properties were investigated. Single phase ${\delta}-CoSb_3$ was successfully obtained by encapsulated induction melting and subsequent heat treatment at 773 K for 24 h. Nickel atoms acted as electron donors by substituting cobalt atoms. Thermoelectric properties were remarkably improved by appropriate heat treatment and doping, and they were closely related to phase transitions and dopant activation. The maximum ZT(dimensionless figure of merit) was achieved as 0.2 at 600 K for the $Co_{0.93}Ni_{0.07}Sb_3$ specimen.

Design of A Compact Single-Balanced Mixer for UWB Applications

  • Mohyuddin, Wahab;Kim, In Bok;Choi, Hyun Chul;Kim, Kang Wook
    • Journal of electromagnetic engineering and science
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    • v.17 no.2
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    • pp.65-70
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    • 2017
  • The design and implementation aspects of a new single-balanced mixer for ultra-wideband (UWB) applications are presented in this study. The proposed mixer utilizes a miniaturized UWB ring coupler as a balun, consisting of a pair of in-phase and inverted-phase transitional structures. The well-balanced UWB performance of the ring coupler, aside from the optimized diode matching, results in improved conversion loss and inter-port isolations for a wide bandwidth. The size of the implemented single-balanced diode mixer is reduced to about 60% of the area of the conventional single-balanced ring diode mixer. The measured results of the proposed mixer exhibit an average conversion loss of 7.5 dB (minimum 6.7 dB) and a port-to-port isolation of greater than 18 dB over a UWB frequency range of 3.1-10.6 GHz. The measured results agree well with the simulated results.

Structural and Dielectric Properties of $(1-x)Pb(Fe_{1/2}Nb_{1/2})O_3-xPbTiO_3$ Prepared by Precalcination Method (전하소법으로 합성한 $(1-x)Pb(Fe_{1/2}Nb_{1/2})O_3-xPbTiO_3$의 구조와 유전성질에 대한 연구)

  • Hong, Young-Sik;Park, Hyu-Bum;Kim, Jeong;Kim, Keon;Kim, Si-Joong
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.891-896
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    • 1993
  • Pb(Fe1/2Nb1/2)O3 and (1-x)Pb(Fe1/2Nb1/2)O3-xPbTiO3 ceramics were prepared by the precalcination method. Their structural and dielectric properties were investigated. The amount of perovsikte phase was increased by the precalcination and the dielectric properties of ceramics were improved. Additions of PbTiO3 were found to increase the tetragonality (c/a) of crystal lattice and Tc. In the middle region of (1-x)Pb(Fe1/2Nb1/2)O3-xPbTiO3, duffuse phase transitions (DPT) were observed.

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Hybrid Control and Protection Scheme for Inverter Dominated Microgrids

  • Xu, Xiaotong;Wen, Huiqing;Jiang, Lin;Hu, Yihua
    • Journal of Power Electronics
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    • v.17 no.3
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    • pp.744-755
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    • 2017
  • With the high penetration of various sustainable energy sources, the control and protection of Microgrids has become a challenging problem considering the inherent current limitation feature of inverter-based Distributed Generators (DGs) and the bidirectional power flow in Microgrids. In this paper, a hybrid control and protection scheme is proposed, which combines the traditional inverse-time overcurrent protection with the biased differential protection for different feeders with different kinds of loads. It naturally accommodates various control strategies such as P-Q control and V-f control. The parameter settings of the protection scheme are analyzed and calculated through a fast Fourier transform algorithm, and the stability of the control strategy is discussed by building a small signal model in MATLAB. Different operation modes such as the grid-connected mode, the islanding mode, and the transitions between these two modes are ensured. A Microgrid model is established in PSCAD and the analysis results show that a Microgrid system can be effectively protected against different faults such as the single phase to ground and the three phase faults in both the grid-connected and islanded operation modes.